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Stoichiometric number and mass changes for finite coagulation and fragmentation events

Statement

In the finite discrete model of Finite discrete coagulation and fragmentation with a mass reservoir, an in-range coagulation event changes the retained number by −1 and retained mass by 0. An overflow event changes retained number by −2, retained mass by −(mi+mj), and reservoir mass by mi+mj. A fragmentation event of species i changes number by ∑k<ibi(k)−1 and mass by 0.

Facts & Assumptions

Given: The event definitions, stoichiometric increments, and daughter normalization in Finite discrete coagulation and fragmentation with a mass reservoir.

[F1]

Finite discrete coagulation and fragmentation with a mass reservoir: an in-range aggregation event has increment ei+j−ei−ej; overflow removes both parents and adds their mass to the reservoir; fragmentation has increment −ei+∑k<ibi(k)ek with ∑k<ikbi(k)=i.

Proof

1.1givenF1algebra

For i+j≤N, summing the coordinates of ei+j−ei−ej gives 1−1−1=−1, and pairing it with the mass vector (mk) gives (i+j)a−ia−ja=0.

1.2givenF1algebra

For i+j>N, the two parent removals give number change −2 and retained-mass change −(mi+mj); the reservoir increment is exactly mi+mj, so augmented mass change is zero.

2.1givenF1algebra∎

Fragmentation changes number by −1+∑k<ibi(k). Its mass change is −ia+∑k<ikabi(k)=a(−i+i)=0 by the daughter normalization.

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