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Degenerate thermometers can fail product comparison
An abstract positive-energy thermometer model showing failure of T4 and the comparison hypothesis for products; it is not a measured thermometer or a claim about ordinary thermodynamic bodies.
Statement refuted
Let be an internal-energy value measured in joules, and use the dimensionless numerical coordinate , so , as in SI quantities and unit conventions. The one-system order relation on the degenerate thermometer state space , together with the thermal equilibration operation described below, need not satisfy T4 or the comparison hypothesis on products. Consequently, a monotone entropy on the single-system space need not represent product accessibility.
Facts & Assumptions
Given: A state is a positive dimensionless energy coordinate as defined in the Statement. For one copy, accessibility is . Thermal equilibrium of scaled copies holds exactly when their normalized coordinates . For two unit copies starting at , put , let
and define the product forward sector as , where is the set of all finite convex combinations with , , and . describes componentwise energy increase and thermal equilibration followed by energy increase, as in Lieb–Yngvason §IV.C. To respect the permutation identification in [F1], a two-copy state here is the class of under swapping its coordinates. Define exactly when some representative of belongs to , where are the displayed sets for the initial representative . This explicitly declares the permutation-compatible version of the source construction; its independence of the initial representative is checked below.
To realize these relations by formal process records, use for one copy and for two ordered copies. In the latter case admit endpoint pairs exactly when under the displayed sector relation; in the former admit exactly . For either domain, put , take identity endpoint maps, a singleton control set, transfer-record set , and a fixed outer boundary. For each admitted pair use exactly the one-second record , where for and . Its transfer record supplies for every , with numerical values in joules, so . Define for one copy and for two, and assign . The same one-copy construction applies to a scaled copy using its actual energy coordinate . Permuting initial and final representatives transports their endpoint labels and the corresponding path labels; the inverse permutations give record bijections preserving boundary, thermal histories, total energies and admission by the representative invariance checked in step 1.1 below. Quotienting therefore gives exactly the stated class relation while retaining both factors up to permutation. These are formal records without auxiliaries, path regularity, core-class membership or material realization asserted; their zero histories are explicit data, not an inference from zero net heat.
Tagged scaled systems and separated products: product states are tagged scaled copies and product comparison is the declared relation, not coordinate addition.
Thermal-contact axioms T1–T4: T4 requires a thermal-equilibrium class crossing strictly below and above every state.
Order, continuity, range, and the product, quotient, and reciprocal laws for the natural logarithm: the real natural logarithm is strictly increasing on positive reals, has , and satisfies .
SI quantities and unit conventions: energy is measured in joules, and numerical energy coordinates are divided by their displayed units before they are used as Euclidean coordinates.
Counterexample
Given: [F1]–[F4] and the product sector specified above.
Let . Then and , since the mean is unchanged; linearity of also gives . Thus the declared relation is independent of the representative of ; target representatives are already quantified over, and reflexivity follows from . Consider the distinct classes and . From , every point of has coordinate sum at least , and every point of has both coordinates at least , hence sum at least . Finite convex combinations preserve this sum bound. Every representative of has sum , so .
In the one-system space, strict accessibility is exactly strict increase of , while thermal equilibrium is equality of normalized energies. If , then , so and the two cannot be thermally equivalent. Thus T4 fails.
From , both and consist of points whose two coordinates are at least ; finite convex combinations preserve both inequalities. Every representative of has a coordinate equal to . Therefore . Together with step 1.1, this proves incomparability of distinct product states and failure of the comparison hypothesis.
By [F4], is dimensionless, so the single-system function is well-defined; it is strictly increasing and represents . If its additive sum represented product accessibility, the states and would have equal summed entropy , forcing accessibility both ways. Step 1.1 and step 2.1 show neither direction holds. Therefore this single-system entropy does not represent the product relation. Since the example fails T4 by step 1.2, it does not satisfy the hypotheses of a product-comparison result that includes T4.
Remarks
The example concerns the formal order model and shows why a product theorem must retain T4 or provide another adequate thermal partner. Lieb–Yngvason’s subsequent Theorem 4.9 treats entropy construction without T4 only when the degenerate type is joined to a system satisfying the appropriate contact conditions.
Depends on
Dependency tree · 2 levels
Sources
- Lieb and Yngvason, The Physics and Mathematics of the Second Law of Thermodynamics, §IV.C, pp. 59–60
- André Thess, The Lieb–Yngvason Machine: A didactical tool for the definition of entropy in classical thermodynamics, §2
- Goddard, The second law of thermodynamics as variation on a theme of Carathéodory, §3