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Finite energy-resolved GKSL thermal model

Definition

Let d≥1 and let H=Cd with its standard complex inner product. Let H=H∗ on H be a Hamiltonian matrix with entries in joules, let ℏ>0 have units joule-seconds, and let S1,…,Sm be a finite family of dimensionless Hermitian matrices, where m≥0. Write the finite spectral decomposition H=∑E∈spec⁡(H)EPE, where PE are pairwise orthogonal spectral projections and ∑EPE=Id. The Bohr-frequency set is

ΩH:={(E′−E)/ℏ:E,E′∈spec⁡(H)}⊂R,

whose frequencies have units seconds−1. For each ω∈ΩH and 1≤a≤m, define the dimensionless energy-resolved coupling

Sa(ω):=∑E,E′∈spec⁡(H)E′−E=ℏωPESaPE′.

Let β∈R have units joules−1. For each ω∈ΩH, choose a finite rate matrix Γ(ω)=(γab(ω))a,b=1m, with entries in seconds−1, that is positive semidefinite in the explicit sense that Γ(ω)=Γ(ω)∗ and v∗Γ(ω)v≥0 for every v∈Cm, and require the thermal balance relation

γab(−ω)=e−βℏωγba(ω).

Let HLS=HLS∗ be a Hermitian matrix with units joules satisfying [HLS,H]=0. For dimensionless X∈Md(C), the finite energy-resolved generator is the linear map

L(X)=−iℏ[H+HLS,X]+∑ω∈ΩH∑a,b=1mγab(ω)(Sb(ω)XSa(ω)∗−12{Sa(ω)∗Sb(ω),X}),

where [A,B]=AB−BA, {A,B}=AB+BA, and A∗ is the conjugate transpose. The finite sums define a linear map with units seconds−1. This is an adopted finite effective model specification; the definition asserts no microscopic weak-coupling convergence or physical applicability.

Facts & Assumptions

Given: d, H, ℏ, the finite Hermitian family (Sa), real inverse-energy parameter β, finite positive rate matrices Γ(ω) obeying the displayed balance relation, and commuting Hermitian HLS, all with the types and units specified in the Definition.

[F1]

Finite matrix spectral and state calculus: a finite Hermitian matrix has finitely many real eigenvalues and pairwise orthogonal spectral projections summing to the identity; finite spectral functions are basis-independent.

Proof

1.1givenF1algebra

By [F1], spec⁡(H) is finite and the projections PE are well-defined, pairwise orthogonal, and sum to Id. Therefore ΩH is finite and symmetric, and each Sa(ω) is a finite sum of endomorphisms of H; when m=0 or a frequency block is empty, the corresponding sum is the zero matrix.

2.1givenstep 1.1algebra∎

Every term in the displayed formula is a product and finite sum of matrices on H, so L is a complex-linear endomorphism of Md(C). The Hamiltonian coefficient has units joules/(joule-seconds) = seconds−1; each dissipative term has units γab=s−1 times dimensionless matrices. Thus the formula is a well-defined finite linear map with the stated units.

Remarks

The sign convention makes Sa(ω) lower the system energy by ℏω when ω>0: it maps the E′ eigenspace to the E eigenspace with E′−E=ℏω. The rate-matrix transpose in the thermal balance relation is tied to the displayed placement of Sb(ω) and Sa(ω)∗ in the generator. No bath limit is part of this mathematical definition.

Depends on

Dependency tree · 2 levels

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