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Finite unitary dynamics and Gibbs KMS identity

Statement

Let H be a finite-dimensional complex Hilbert space and let H=H∗ be a Hamiltonian on H with energy unit J; let ℏ>0 have unit J s. For real t measured in seconds, U(t)=e−itH/ℏ is unitary and U(t+s)=U(t)U(s). For a trace-one density ρ on H, the Schrödinger state U(t)ρU(t)∗ and the Heisenberg observable αt(A)=U(t)∗AU(t) have the same trace expectation. Fix kB>0 in J/K for the entropy convention; then the von Neumann entropy is unchanged. If d=dim⁡H≥1, β>0 has unit J−1, and σβ=e−βH/Zβ with Zβ=Tr⁡e−βH, then it is stationary and satisfies the finite Gibbs KMS strip identity FA,B(t+iβℏ)=Tr⁡(σβαt(B)A),FA,B(z)=Tr⁡(σβAαz(B)), where αz(B)=eizH/ℏBe−izH/ℏ, with complexified time z measured in seconds. The function is entire and bounded on 0≤Im⁡z≤βℏ seconds. No infinite-volume KMS existence or approach to equilibrium follows.

Facts & Assumptions

Given: A finite-dimensional complex Hilbert space, a Hermitian H, ℏ>0, real time t in seconds, β>0 in J−1 and a nonzero space for the normalized Gibbs clause, bounded matrices A,B, a density matrix ρ, and kB>0 for the entropy clause.

[F1]

Finite matrix spectral and state calculus: Hermitian matrices have real spectral decompositions, basis-independent spectral calculus, and the stated density trace pairing.

Proof

1.1givenF1algebra

On a zero-dimensional Hilbert space the unique endomorphism is I=0, and its exponential is I, so the unitary and group identities hold directly. There is no trace-one density there; the remaining density and normalized-Gibbs clauses have no instance. On a nonzero space, diagonalize H by [F1], with eigenvalues Ej. Then U(t) has eigenvalues e−itEj/ℏ of modulus one, so it is unitary. In the same eigenbasis, multiplying scalar exponentials gives U(t+s)=U(t)U(s). The finite exponential series differentiates termwise and yields iℏU′(t)=HU(t).

1.2givenF1algebra

In the eigenbasis of H, every matrix entry of eizH/ℏBe−izH/ℏ is a constant times eiz(Ej−Ek)/ℏ, an entire scalar function. Thus FA,B is entire. For z=t+iy, 0≤y≤βℏ, the real-time factors are unitary and the imaginary-time factors have norm at most eβ∥H∥ each. The trace against a density is bounded by operator norm, so ∣FA,B(z)∣≤∥A∥∥B∥e2β∥H∥ throughout the closed strip.

2.1step 1.1F1algebra

For finite matrices C,D, the coordinate trace gives Tr⁡(CD)=∑i,jCijDji=Tr⁡(DC) by interchanging the two finite indices. This cyclicity gives Tr⁡(UρU∗A)=Tr⁡(ρU∗AU). Unitary conjugation preserves positivity, trace, and eigenvalues; therefore it preserves the finite entropy S(ρ)=−kB∑jf(pj), where pj are the density eigenvalues, f(x)=xlog⁡x for x>0, and f(0)=0. Thus Tr⁡(ρlog⁡ρ) denotes Tr⁡f(ρ), including singular densities; no value of log⁡0 is used. Since σβ is a function of H, it commutes with U(t), hence is stationary.

3.1step 1.2step 2.1F1algebra∎

At z=t+iβℏ, αz(B)=e−βHαt(B)eβH. Hence FA,B(t+iβℏ)=Zβ−1Tr⁡(e−βHAe−βHαt(B)eβH)=Zβ−1Tr⁡(Ae−βHαt(B))=Tr⁡(σβαt(B)A), where the first equality uses the definition, the second uses finite trace cyclicity, and the third uses it again. The strip boundary identity follows.

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