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Conditional admissibility of the specified non-Newtonian branches

Physical scope

Given selected stated law and balances, derive objective nonnegative mechanical dissipation; conformation entropy requires explicit isothermal Helmholtz realization/thermostat.

Statement

Work in the smooth incompressible branch of the adopted nonrelativistic continuum model. Let T>0, let J⊆R be an open interval containing [0,T], let Ω⊆R3 be open, and let u∈C2(J×Ω;R3) be the Eulerian velocity induced by a C2 material motion with orientation-preserving C2 diffeomorphic time slices, and satisfy div⁡u=0. At a spatial point let L=∇u, D=(L+LT)/2, tr⁡D=0, and use the Frobenius contraction S:T=tr⁡(STT) with norm ∣S∣=(S:S)1/2. Let M3(R) denote the real 3×3 matrices, and define Sym0(3)={S∈M3(R):S=ST,tr⁡S=0} and Sym+(3)={C∈M3(R):C=CT,zTCz>0 for every z≠0}. A constitutive response is objective when under every rigid observer change x∗=Q(t)x+c(t), with Q∈C2([0,T],SO(3)) and c∈C2([0,T],R3), its second-order tensor value at corresponding events transforms as S∗=QSQT. For the generalized Newtonian branch, let γ˙=(2D:D)1/2, let η:[0,∞)→[0,∞) be finite and continuous, and set τ=2η(γ˙)D. Define I3 as the 3×3 identity matrix; in SI units, L,D,γ˙ have units s−1, η,ηs,μp have units Pa s, and τ,τy,G have units Pa. For the Bingham branch, let μp≥0 in Pa s and τy≥0 in Pa, and set B(D)={2μpD+τyD/∣D∣} for D≠0 and B(0)={S∈Sym0(3):∣S∣≤τy}. For the conformation branch, take a C1 trajectory x:[0,T]→Ω with x′(t)=u(t,x(t)). Set L(t)=∇u(t,x(t)), D(t)=(L(t)+L(t)T)/2, and let the dimensionless C∈C1([0,T];M3(R)) be symmetric, so C(t)=C(t)T for all t, and satisfy

C′=LC+CLT−(C−I3)/λ,C(0)=C0∈Sym+(3),

where G>0 is a modulus in Pa, λ>0 is a relaxation time in seconds, and ηs≥0 is a solvent viscosity in Pa s. Define τp=G(C−I3), τs=2ηsD, and w(C)=G2(tr⁡C−log⁡det⁡C−3) in J m−3. Then the generalized Newtonian and Bingham branches have objective stress responses and nonnegative instantaneous mechanical power τ:D≥0 for every allowed stress. On every forward time t∈[0,T], the conformation solution remains positive definite, its constitutive response is objective, and

(τs+τp):D−ddtw(C)=2ηsD:D+G2λ(tr⁡C+tr⁡C−1−6)≥0.

Thus the selected smooth branches have nonnegative mechanical or stored-energy dissipation under their stated model hypotheses. This is a conditional deduction, not a claim of empirical material applicability or existence of a fluid partial-differential-equation solution.

For an entropy-production interpretation of the conformation inequality, additionally adopt the following separate isothermal realization along the trajectory. Fix T0>0 in K and let ev,sv∈C1([0,T];R) be internal-energy and entropy densities per current volume, in J m−3 and J K−1m−3, respectively. Let h∈C0([0,T];R) be the signed heat-removal rate per current volume, in W m−3, positive for heat passed to an ideal external thermostat at the same temperature T0. Assume this is the only heat exchange, carrying entropy out at rate h/T0, and adopt the energy balance ev′=(τs+τp):D−h and the Helmholtz free-energy identification w(C)=ev−T0sv. Define the internal entropy-production density by πs:=sv′+h/T0, in W K−1m−3. Derivatives at the time endpoints are one-sided. Then

T0πs=(τs+τp):D−ddtw(C)≥0.

These additional thermodynamic assumptions are not inferred from the continuum balances or the stored-energy identity alone.

Statement references

Facts & Assumptions

Given: The adopted smooth continuum branch and the three constitutive cases in the Statement.

[F1]

Restricted non-Newtonian constitutive examples: a material motion is a C2 map with orientation-preserving C2 diffeomorphic time slices, its Eulerian velocity is u(t,χ(t,a))=∂tχ(t,a), and SO(3)={Q:QTQ=I3,det⁡Q=1}; under a rigid observer change with Q(t)∈SO(3), objective tensor responses transform as S∗=QSQT.

[F2]

Restricted non-Newtonian constitutive examples: the generalized Newtonian branch defines γ˙=(2D:D)1/2 and τ=2η(γ˙)D with finite continuous η:[0,∞)→[0,∞).

[F3]

Restricted non-Newtonian constitutive examples: the selected parameter τy is the Frobenius radius of the Bingham stress ball at rest, and the graph is set-valued there.

[F4]

Restricted non-Newtonian constitutive examples: the conformation branch adopts the displayed upper-convected equation, polymer and solvent stresses, and stored-energy density w(C) on a smooth incompressible trajectory.

[F5]

Objective generalized-Newtonian dissipation: for the incompressible generalized Newtonian law with finite continuous η:[0,∞)→[0,∞), τ:D≥0; under the stated C2 rigid observer change the rate and stress transform by orthogonal conjugation.

[F6]

Bingham yield graph and convex monotonicity: the trace-free Bingham graph is the subdifferential of Φ(D)=μp∣D∣2+τy∣D∣; its values are monotone, every value satisfies τ:D≥0, and B(QDQT)=QB(D)QT.

[F7]

Objective conformation positivity and stored-energy dissipation: for the stated smooth forward trajectory, continuous matrix field L, positive-definite initial C0, G,λ>0, and ηs≥0, the solution remains positive definite and satisfies the exact displayed stored-energy dissipation identity.

[F8]

Objective conformation positivity and stored-energy dissipation: under the stated rigid observer change, the conformation equation is covariant, the conformation and both stresses transform by orthogonal conjugation, and the stored-energy density is invariant.

[A1]

For the optional isothermal realization only, adopt the Statement's T0>0, densities ev,sv, heat-removal rate h, energy balance ev′=(τs+τp):D−h, Helmholtz identification w(C)=ev−T0sv, and entropy-exchange convention πs=sv′+h/T0. These are additional physical assumptions and a definition, not consequences of [F1]–[F8].

Proof

1.1F1F2F5algebra

In the generalized Newtonian branch, γ˙2=2D:D and η(γ˙)≥0 by [F2], so τ:D=2η(γ˙)D:D=η(γ˙)γ˙2≥0. Under a rigid observer change, [F5] gives D∗=QDQT and τ∗=QτQT; orthogonal conjugation preserves the Frobenius product, hence γ˙∗=γ˙. By the definition in [F1], the response is objective.

1.2F3F5F6algebra

In the Bingham branch, when D≠0, each allowed stress is τ=2μpD+τyD/∣D∣, so τ:D=2μp∣D∣2+τy∣D∣≥0. When D=0, every allowed stress has τ:D=0; the graph value there is nonempty since it contains 0, and for D≠0 the graph value is a singleton. The kinematic identity D∗=QDQT in [F5] and the graph equivariance in [F6] give B(D∗)=QB(D)QT, so the graph response is objective, including at zero rate.

1.3F4F7F8algebra

For the conformation branch, [F7] supplies positive definiteness and the exact identity in the Statement under its forward-time and regularity hypotheses; [F8] supplies objectivity. Set A=C−I3. Since C is positive definite, it is invertible and C−1 is positive definite: for each nonzero z, zTC−1z=(C−1z)TC(C−1z)>0. Matrix multiplication gives AC−1A=C+C−1−2I3, so tr⁡C+tr⁡C−1−6=tr⁡(ATC−1A)=∑j=13ajTC−1aj≥0, where aj are the columns of A. Since ηs≥0, the displayed stored-energy dissipation is nonnegative.

2.1givenA1step 1.1step 1.2step 1.3algebra∎

Steps 1.1–1.3 establish the conditional nonnegative mechanical or stored-energy dissipation and objectivity. Under the additional assumptions [A1], constancy of T0 gives ddtw(C)=ev′−T0sv′=(τs+τp):D−h−T0sv′. Rearrangement yields (τs+τp):D−ddtw(C)=T0(sv′+h/T0)=T0πs≥0 by step 1.3. Since T0>0, πs≥0; no entropy conclusion is used or asserted without [A1].

Depends on

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