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A constant potential has no canonical Gibbs probability on the line

Example

On R, take V(q)=0, any fixed mass m>0, friction γ>0, and inverse temperature β>0. The configurational partition integral diverges, so the canonical Gibbs expression does not define a probability. The momentum factor is normalizable but cannot repair the infinite configurational factor.

Facts & Assumptions

Given: V(q)=0 for every q∈R, m>0, γ>0, β>0, and the canonical normalizer in Underdamped Langevin equation and canonical Gibbs density.

[F1]

Underdamped Langevin equation and canonical Gibbs density: a canonical Gibbs probability requires a finite positive normalizing integral Z=∫e−βH(q,p)dq dp.

[A1]

The Axiom of Choice: AC is inherited from the model-definition interface [F1]; the finite-rectangle lower bound uses no further choice.

Verification

Given: V(q)=0 for every q∈R, m>0, γ>0, β>0, and the canonical normalizer in Underdamped Langevin equation and canonical Gibbs density.

[F1] Underdamped Langevin equation and canonical Gibbs density: a canonical Gibbs probability requires a finite positive normalizing integral Z=∫e−βH(q,p)dq dp.

[A1] The Axiom of Choice: AC is inherited from the model-definition interface [F1]; the finite-rectangle lower bound uses no further choice.

Given: The data in the Example.

1.1givenalgebra

For every R>0, ∫−RRe−βV(q)dq=∫−RR1 dq=2R. These integrals are unbounded as R→∞, so ∫Re−βV(q)dq=∞.

2.1A1F1givenalgebra∎

On the finite rectangle [−R,R]×[−1,1] the phase-space integrand is at least e−β/(2m), so its integral is at least 4Re−β/(2m). These lower bounds diverge as R→∞, hence the full normalizer Z is infinite and the expression cannot be normalized to a probability.

Depends on

Used by

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Dependency tree · two levels

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Sources