How statement and proof provenance work
The first chip identifies the source of the statement or construction; the second identifies the source of its local proof or verification.
- Literature-sourced: the exact statement appears in a cited source; only wording and notation differ.
- AI-adapted: a semantically identical restatement of literature-sourced material, modulo indexing, notation, and boundary cases adopted by the library.
- AI-generated: a genuinely novel statement formulated by AI, with no source for the claim itself.
These labels describe origin, not correctness: citations and verification chips remain separate evidence.
Detection-limit assumptions and left-censored readings
Example
Consider the heteroscedastic response law for , with and . The blank variance is , but the standard deviation increases with concentration when . For , write . The critical level is . A finite detection limit for false-negative target exists exactly when , and then For , the coefficient-of-variation criterion has a finite quantification limit exactly when , and then When a reporting procedure records only the category , its likelihood contribution at concentration is the probability not a density value at .
Facts & Assumptions
Given: AC; the heteroscedastic family and parameter restrictions in the Example; and the positive-decision rule is .
AC is required by the standard normal probability-law construction. The Axiom of Choice Standard normal and normal laws
The standard normal CDF is strictly increasing, has no atoms, and its quantiles obey for every . The standard normal CDF has unique symmetric quantiles
A normal response with mean and scale has expectation and variance . Location-scale normal laws have their stated mean and variance
is the law of for standard normal . Standard normal and normal laws
A real random variable's CDF is . Cumulative distribution function of a real random variable
The exact critical level and the false-negative target are defined relative to the specified blank and signal laws. Critical, detection, and quantification levels
For a probability measure, . Basic identities for a probability measure
Verification
Given: The response model, positive-decision rule, and targets in the Example.
At , the model is , so [F3] represents in law. Set ; by [F1], [F3], and complement identity [F6], . Also [F1] gives , hence and . Since , strict increase gives , and [F5] makes this an exact critical level.
By [F2], for . If , the inequality is equivalent to , giving the displayed least value. If , then for every finite , so no finite quantification limit exists.
For , the scale is . By [F3], . Since , strict increase in [F1] makes this equal to exactly when Rearranging gives , whose right-hand side is positive. If , the unique solution is the positive displayed . If , the equation would equate zero to a positive number; if , its only algebraic solution is negative. Thus a nonnegative detection limit exists exactly under the stated condition.
If the recorded observation is the category , its probability under the stated law is the CDF at , namely the displayed by [F4]. The affine normal law has no atom at by [F1] and [F3], while the CDF gives the probability of the reported half-line. Substituting as an observed point is therefore not the likelihood of this censored report.
Source notes
Eurachem §5.3.2 explains that blank correction changes the standard deviation used for LOD/LOQ; §5.3.5 discusses changing blanks across days. The heteroscedastic law and censoring rule here are explicit model assumptions. Their consequences are derived above rather than imported as universal measurement claims.
Depends on
- Critical, detection, and quantification levels
- The standard normal CDF has unique symmetric quantiles
- Location-scale normal laws have their stated mean and variance
- Standard normal and normal laws
- Cumulative distribution function of a real random variable
- Basic identities for a probability measure
- The Axiom of Choice
Used by
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Dependency tree · two levels
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Sources
- H. Cantwell (ed.), Eurachem Guide: The Fitness for Purpose of Analytical Methods, 3rd ed. (2025), §§5.3.1–5.3.5 and Annex B (standard reference, not scraped)