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Positive logarithmic contact model as a consistency witness

Physical scope

A calculated mathematical model showing compatibility of the stated accessibility and contact assumptions for positive-coordinate systems; it is not an experiment or evidence that real materials obey the assumptions.

Example

Take finitely many tagged simple types i, each with positive dimensionless coordinates u>0,v>0, where u=E/(1 J) for internal energy E measured in joules and v is the numerical work coordinate in its declared fixed unit. Choose dimensionless constants ci,ri>0, positive dimensionless reference values u⋆,i,v⋆,i>0, and dimensionless offsets bi∈R, and define

si(u,v)=cilog⁡uu⋆,i+rilog⁡vv⋆,i+bi.

For a scaled tag ti, set its coefficients to tci,tri,tbi and its reference coordinates to tu⋆,i,tv⋆,i, so sti(tu,tv)=t si(u,v). For every finite compound of declared primitive, scaled, or recursively joined tags, assign the sum of the constituent state entropies and declare A≺B exactly when this sum for A is no greater than this sum for B, on equal-formal-mass pairs. For a thermal join of i,j, define the joined entropy at (u,vi,vj) as the maximum of si(ui,vi)+sj(uj,vj) over ui,uj>0 with ui+uj=u. Use the same entropy comparison for the separated-pair and joined encodings, which have the same formal composition: the pair accesses the join exactly when its entropy is at most the joined entropy, and the join accesses the pair exactly when the reverse inequality holds. Thus contact equilibrium is equivalent to equality with the maximum. For a positive scaled copy tΔij of a join, scale all coordinates by t and set stΔij(tZ):=tsΔij(Z); this is consistent with the maximum because scaling (ui,uj) by t bijects the splits of u with the splits of tu. For nested joins, use the same maximum construction recursively, with the same positive-scaling rule.

To realize every stated comparison, explicitly declare a formal channel for each ordered pair of endpoint types T,T′ of equal formal mass, including pairs with different primitive compositions. Let XT,XT′ be their domains, let HT:XT→R be the entropy specified above, and let ET:XT→R J be the energy map (sum over separated factors, or the single summed energy for a join). The configuration space is the disjoint union ZT,T′=({0}×XT)∪({1}×XT′), with initial and final equilibrium subsets the two summands and endpoint maps (0,a)↦a, (1,b)↦b. Fix singleton protocol and outer-boundary record sets {∗} and the transfer-record set RT,T′=XT×XT′. For endpoints (a,b) the one-second record is Pa,b=([0,1],a,b,za,b,∗,∗,(a,b)), where za,b(0)=(0,a) and za,b(t)=(1,b) for 0<t≤1; no path regularity is asserted. Let its transfer record (a,b) supply HPa,bin(t)=HPa,bout(t)=0 for every t∈[0,1], with numerical values in joules. These nonnegative, nondecreasing maps start at zero and specify no thermal transfer across the selected outer boundary. Deleting the fixed outer-boundary field gives a bijection from these seven-field records to the six-field records of Tagged scaled systems and separated products, preserving endpoints, controls, transfers and admission; for one-factor channels use these same records as the single-system model. Permutation and reassociation transport the endpoint tuples and the path labels together; their inverse transports give record bijections, preserving entropy sums, total energy and the zero thermal histories. Assign Q(a,b)=0 J from these histories and Won(a,b)=ET′(b)−ET(a). Admit exactly these records with HT(a)≤HT′(b); their declared balance is ΔE=Q+Won and equal formal mass. Accessibility is existence of one of these admitted records. Thus the entropy order, including the cross-composition comparisons, has explicit witnesses, rather than being inferred from equal mass. Primitive composition here is a formal label, not a mole vector; no chemical or material conservation model, actual apparatus, or realization of these discontinuous paths is asserted. The empty type has its sole state, energy zero and entropy zero, and has its identity record.

This formal model explicitly declares each equilibrium endpoint domain to be the stated positive numerical orthant, with endpoint coordinate map the identity and accessibility the entropy-sum relation above. Its fixed unit map assigns E=u(1 J) and each work coordinate Wa=vawa for a fixed positive unit wa; this bookkeeping supplies no material realization. Each primitive tag has a fixed formal composition, while the joined endpoint space is the positive orthant in summed energy and retained work coordinates with the summed composition. A scaled copy transports these coordinates and that composition and retains its distinct tag, exactly as in the declared join interface. This provides a nondegenerate consistency witness for the order, geometric, contact, T5, and C1 assumptions on this positive-coordinate family. It supplies no measured parameter values or empirical claim.

Facts & Assumptions

Given: Positive coordinates; fixed ci,ri>0, reference values and constants; tagged scaling as stated; accessibility on separated, joined, and mixed contact encodings is the stated total-entropy comparison; join entropy is the constrained maximum.

[F1]

Thermal joins and thermal equivalence: a join retains component work coordinates and sums the energy coordinate.

[F2]

Accessibility axioms A1–A6: A1–A6 are the order conditions to be checked for the example relation.

[F3]

Simple-system geometric axioms: A7 and S1–S3 are the geometric conditions to be checked.

[F4]

Thermal-contact axioms T1–T4: T1–T4 are the contact conditions to be checked.

[F5]

Universal thermal-equilibrium range T5 and Equilibrium-join coherence C1: T5 and C1 are separate conditions to be checked.

[F6]

The two-point convexity inequality for the exponential function: for a,b∈R and t∈[0,1], exp⁡((1−t)a+tb)≤(1−t)exp⁡(a)+texp⁡(b); for 0<t<1, equality holds exactly when a=b.

[F7]
[F8]

Real powers for positive bases, with the zero-base positive-exponent convention and Continuity and derivatives of positive-base real powers: for K>0 and α∈R, vα is differentiable for v>0 with derivative αvα−1.

Verification

Given: [F1]–[F5] and the construction in the Example.

1.1F3F6F7algebra

For a,b>0, apply [F6] to log⁡a,log⁡b, then use [F7] and monotonicity of log⁡, to obtain log⁡((1−t)a+tb)≥(1−t)log⁡a+tlog⁡b for 0≤t≤1. Apply this inequality to the energy ratios u/u⋆,i and to the work ratios v/v⋆,i; multiplying by ci,ri>0 and adding bi proves concavity of si. This verifies the convex-combination accessibility condition. Since log⁡ is strictly increasing, raising u at fixed v gives a strict successor, proving S1.

1.2F3F8F9algebra

The boundary equation si(u′,v′)=si(ux,vx) rearranges to u′=g(v′)=K(v′)−α, where K=uxvxα>0 and α=ri/ci>0. By [F8], g′=−αK(v′)−α−1 and g′′=α(α+1)K(v′)−α−2>0. Thus g′ is increasing by [F9]. For v′≠vx, the mean value theorem on the interval between them and the monotonicity of g′ give g(v′)≥g(vx)+g′(vx)(v′−vx): when v′<vx, both the derivative comparison and the sign of v′−vx reverse. Hence the forward sector u′≥g(v′) lies above the tangent support u′−ux+(riux/(civx))(v′−vx)=0. A vertical line cannot support this sector because its work coordinate varies on both sides at an interior boundary point. If a nonvertical line with slope parameter q supports there, its inequality on graph points gives g(v′)−g(vx)+q(v′−vx)≥0 for both signs of v′−vx; dividing by that difference and taking limits forces q=−g′(vx). This proves uniqueness and gives Pi=riux/(civx). On any closed rectangle with u,u~≤u1 and v,v~≥v0>0, ∣u/v−u~/v~∣≤∣u−u~∣/v0+u1∣v−v~∣/v02, so the slope is locally Lipschitz. The graph over v′>0 is arcwise connected, proving S3.

1.3F1F4F6F7givenalgebra

Put C=ci+cj. For any split ui+uj=u, [F6] with weights ci/C,cj/C, followed by [F7], gives ciClog⁡uici+cjClog⁡ujcj≤log⁡uC, with equality exactly when ui/ci=uj/cj. Since ui+uj=u, that equality forces the unique split ui=ciu/C, uj=cju/C. Multiply by C and add the constants cilog⁡(ci/u⋆,i)+cjlog⁡(cj/u⋆,j)+bi+bj+rilog⁡(vi/v⋆,i)+rjlog⁡(vj/v⋆,j); the resulting inequality is exactly the pair entropy bounded by its value at that split. By the declared total-entropy comparison, this proves T1 and shows that the maximizing split is reversible with the join, establishing the join-splitting clause of T2. For the equal-state scaled split, tagged extensivity gives sti(tu,tv)=tsi(u,v) and s(1−t)i((1−t)u,(1−t)v)=(1−t)si(u,v), so the pair is reversible with x by the example order. The maximizing-split criterion also applies to the two scaled types: their energy coefficients are tci,(1−t)ci, and their energy-to-coefficient ratios both equal u/ci. Their join is therefore reversible with the pair, which is precisely the scaled-join clause of T2. The binary join entropy is Clog⁡u+rilog⁡vi+rjlog⁡vj+Cij for a constant Cij; its energy-to-coefficient ratio is u/C=ui/ci=uj/cj at the maximizing split.

2.1F2givenstep 1.1algebra

By the declared total-entropy comparison, every finite product has a real-valued order. Reflexivity and transitivity follow from the real order; adding the same spectator adds the same number to both sides; positive scaling multiplies the sums by a positive coefficient; and reversible splitting preserves the extensive sum. If A+ϵnZ0≺B+ϵnZ1, then s(A)−s(B)≤ϵn(s(Z1)−s(Z0)). Taking n→∞ yields s(A)≤s(B) and hence A≺B. This verifies the six adopted order conditions.

2.2F3F8F9givenstep 1.1step 1.2step 1.3algebra

For a single system the entropy has the displayed logarithmic form. If a nested join has energy coefficient C and is joined with a system of coefficient c>0, the maximum calculation of step 1.3 gives the unique maximizing split at equal energy-to-coefficient ratios; substitution adds c to the energy coefficient and adds the new work term. Induction over the finite joins therefore gives coefficient C=∑kck and entropy Clog⁡u+∑krklog⁡vk+C0 for the positive work coordinates v=(v1,…,vm). Its boundary is u=g(v)=K∏kvk−αk with αk=rk/C>0. Direct differentiation gives, for any vector h, D2g(v)[h,h]=g(v)[(∑kαkhkvk)2+∑kαk(hkvk)2]≥0. Thus along each segment in the positive work orthant, the derivative of g is nondecreasing by [F9], and the mean value theorem gives g(v′)≥g(v)+∇g(v)⋅(v′−v). The forward sector u≥g(v) lies above this tangent support; uniqueness follows by applying the support inequality to graph points in each direction h and −h, which forces the support functional to equal ∇g(v). Its finite slope components are Pk=rku/(Cvk); on rectangles bounded away from all coordinate axes, the quotient estimate from step 1.2 applies to each component and proves local Lipschitz regularity. The positive orthant and its graph are arcwise connected. Increasing u gives S1, and the coordinatewise concavity argument of step 1.1 gives the convex-combination accessibility condition. Hence each join satisfies the same simple-system geometry.

3.1F4givenstep 1.3step 2.2algebra

Applying the two-weight maximum calculation of steps 1.3 and 2.2 to any two primitive or recursively joined types A,B shows that x=(uA,vA) and y=(uB,vB) are thermally equivalent exactly when uA/CA=uB/CB, where CA,CB>0 are their energy coefficients. Equality of ratios is transitive, proving T3. For any such simple type with coefficient C and at least one work coordinate vk, fix a state x=(u,v) and choose 0<vk−<vk<vk+, keeping u and all other coordinates fixed. The entropy formula of step 2.2 strictly increases with vk, so x−≺≺x≺≺x+. Both outer states have the same ratio u/C and hence are thermally equivalent. This proves T4 for primitive and recursively joined simple types.

4.1F5givenstep 1.3step 2.2algebra∎

Let A,B be any primitive or recursively joined simple types, with energy coefficients CA,CB>0. Given x=(uA,vA) and any allowed work-coordinate vector vB, choose uB=CBuA/CA. The two-weight maximum calculation in steps 1.3 and 2.2 makes x thermally equivalent to y=(uB,vB), proving T5. For any equilibrated pair x,y, the same calculation gives uA/CA=uB/CB. Their joined state has energy coefficient CA+CB and energy uA+uB, so its ratio equals the common ratio; the two-weight maximum criterion therefore makes that joined state thermally equivalent to x, and likewise to y. This proves C1 for every admitted join.

Remarks

The coefficients are chosen mathematical parameters. Their existence checks compatibility of the postulates but does not report measurements, determine SI entropy units, or prove the assumptions for a real substance.

Depends on

Dependency tree · 2 levels

Sources