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Regular rank form of the finite-component phase dimension count
Statement
Let be the number of components and the number of phases. Use common positive real coordinates , expressed in fixed units if they are given a physical interpretation, and, for each phase , an interior composition vector
with the convention and . The final component fraction is . The ambient coordinate domain is open in , where . For each phase and component , let be a real-valued coordinate function; these are mathematical maps and no thermodynamic potential or physical realization is assumed.
For , define the coexistence equations
At a solution , assume some derivative minor of is invertible. Then the local solution set is a graph of dimension
For there are no coexistence equations and the coordinate domain itself has dimension . In a specified reactive variant with , let be linearly independent dimensionless stoichiometric vectors and add the affinity equations . If the combined equation map has an invertible derivative minor at a solution and , its local zero set has dimension
These are conditional local dimensions under the displayed nonsingular-minor assumptions. No dimension formula follows at singular solutions, on composition boundaries, or from equation counting alone; no empirical or general physical phase rule is asserted.
Facts & Assumptions
Given: The finite integers, open coordinate domain, chemical-potential coordinate functions, coexistence equations, and nonsingular-minor assumptions in the Statement.
Continuously differentiable maps, local inverses, and local diffeomorphisms: means total differentiability with continuous derivative-matrix entries.
Local graph form at a nonsingular derivative minor: for an open , a map , , and a zero with an invertible derivative minor, the local zero set is a graph over coordinates when , and an isolated point when .
Sums and scalar multiples of totally differentiable maps are totally differentiable with the expected derivatives: if are totally differentiable at and , then and are totally differentiable there, with and . Repeated application gives the derivative of every finite linear combination; continuity of its derivative entries must also be checked to establish regularity.
Proof
For each phase let select , and write . The same coordinate selection on increments is linear and satisfies . Substituting into the first-order expansion of gives derivative and remainder , with zero remainder when . Its derivative entries are selected entries of or zero; they are continuous because does not increase distances and the original entries are continuous. For , has scalar components, each a difference of these lifted maps. By [L2] their derivative rows are ; the entries are continuous since the increment of each difference is bounded by the sum of the two entry increments. The finitely many scalar remainders assemble to a vector remainder , since its norm is at most times their largest absolute value. Thus is by [F1]. The assumed minor entails , so [L1] gives local graph dimension , including an isolated point if .
If , no phase-equality equations are indexed because there is no . The local solution set is all of the open domain , which has coordinates.
In the reactive variant put if . The lifted maps constructed in step 1.1 are for every . By [L2], . For each derivative entry, its increment is bounded by the finite sum of times the corresponding continuous entry increments, which tends to zero. Thus the affinity derivative entries are continuous. As in step 1.1, the finitely many scalar remainders assemble to a vector remainder , so the combined map is by [F1] and has scalar equations. Since , its stated minor lets [L1] give graph dimension , with an isolated point if . Linear independence of the identifies distinct reaction directions, while the nonsingular derivative minor remains a separate assumption.