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Nonsmooth Equilibrium
1 · Prerequisites
- Binary Operations, Monoids, Groups and Subgroups
- Compactness in Metric Spaces
- Completeness, Completion, and Uniform Continuity
- Construction of the Natural Numbers
- Construction of the Real Numbers via Cauchy Sequences
- Construction of the Real Numbers via Dedekind Cuts
- Continuity, IVT, EVT, and Uniform Continuity
- Convex and Semicontinuous Functions on Rⁿ
- Countability and Uncountability
- Filters and Ultrafilters
- Finite Counting, Factorials and Binomial Coefficients
- Foundations of the Real Numbers for Analysis
- Limits of Real Functions
- limsup, liminf, and Subsequential Limits
- Linear Independence, Bases and Dimension
- Linear Transformations, Rank-Nullity and Quotient Spaces
- Metric Spaces
- Mixed Partials, Taylor Formulae, and Extrema
- Monotone Functions, Discontinuities, and Continuity Sets
- Monotone Sequences, Bolzano-Weierstrass, and Cauchy Completeness
- Order, Zorn's Lemma, and the Axiom of Choice
- Ordered Composition
- Properties of the Integral and the Working FTC
- Relations, Functions, and Quotients
- Rings, Subrings, Integral Domains and Fields
- Rⁿ as a Normed Space; Vector-Valued Functions
- Roots, Rational Powers, and Classical Inequalities
- Sequences and Limits
- Suprema and Infima
- The Derivative and the Mean Value Theorems
- The Inverse and Implicit Function Theorems
- The Inverse Function Theorem Completed
- The Riemann Integral: Definition and Integrability
- The Total Derivative in ℝᵐ → ℝⁿ
- The ZFC Axioms and the Basic Set Constructions
- Topology of ℝ
- Vector Spaces, Linear Subspaces, Span and Direct Sums
2 · Summary
This page develops finite-dimensional convex analysis and local equilibrium mathematics. It defines proper extended-real convex functions, lower semicontinuity, Fenchel conjugates and subgradients; proves epigraph characterizations, strict separation, Fenchel equality, and biconjugation; and gives an explicit coercive-tilt attainment result. The separation and biconjugation arguments include the vertical-separator case, including points outside the effective domain.
The finite-mixture result is restricted to a finite list of data: its minimum is attained on a simplex, its envelope is proper, closed and convex, and occupied points satisfy one supporting-affine equality. A conditional corollary transfers this conclusion to an additive compound representation only under the exact batch-3 interface and an affine coordinate assignment. The required page td-math-ordered-composition and its current additive-representation proof are present, with owner Step 1 proof-readiness recorded. This supplies the authored prerequisite context; both suppliers remain draft and independent review is pending. The corollary is conditional on the exact representation hypotheses, not an assertion of physical adoption or prior review acceptance. The scalar lever rule records its endpoint and uniqueness cases.
The remaining results keep smooth and nonsmooth claims separate. The concavity lemma proves supporting bounds along admitted segments, global stationary maxima on the stated affine slices, and local Hessian semidefiniteness without assuming convexity of an entire state domain. The constrained-curvature test assumes a continuous second directional form and stationarity on an affine feasible slice. The stoichiometric lemma proves the tangent cone for finite linear species-balance inequalities and states the directional optimality condition. The local implicit-rank theorem yields a graph only at a nonsingular derivative minor; the phase-dimension count is conditional on that rank and on interior composition coordinates. These are mathematical deductions and make no empirical claim about an actual material or equilibrium.
3 · Logical flowchart
4 · Definitions, postulates, theorems and proofs
Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space
Definition
Fix an integer . Write with its usual order and extended addition; in a convex combination set and for . A function is proper when it never takes the value and its effective domain
is nonempty. It is convex when
It is lower semicontinuous when each weak sublevel set is closed in the Euclidean topology, for every . Its epigraph is
On this page “closed proper convex” means proper, convex, and lower semicontinuous in these conventions. The pairing of is the Euclidean inner product of The Euclidean inner product on .
Fenchel conjugate, biconjugate, and subdifferential
Definition
Let be proper in the sense of Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space. Its Fenchel conjugate is ,
The supremum is taken in ; its defining set is nonempty and consists of real numbers, so . The biconjugate is an extended-real expression that may also take when its defining supremum is over the empty set:
with the convention . For , the subdifferential is
set for . A vector in is a subgradient at . All pairings use The Euclidean inner product on .
Extended-real convexity and lower semicontinuity are characterized by the epigraph
Statement
Let and let use the conventions of Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space. Then is convex if and only if is a convex subset of , and is lower semicontinuous if and only if is closed.
Facts & Assumptions
Given: , the extended-real conventions and epigraph of the Statement, and the Euclidean topology.
Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space: convexity is the extended chord inequality; lower semicontinuity means that every weak sublevel set is closed.
The metric topology: a set is open when every one of its points has a ball around it inside the set; closed means open complement: a set is open when every point has a positive-radius metric ball contained in the set; it is closed exactly when its complement is open. Here the metrics are Euclidean.
Proof
Suppose is convex and take . For , the chord inequality gives , so . Thus the epigraph is convex.
Conversely, if the epigraph is convex and are finite, then and lie in it; their convex combination lies in it and gives the chord inequality. If either value is and its coefficient is positive, the right side is and the inequality is automatic; at or it is equality.
Suppose is closed and fix . For write for the Euclidean metric. The slice map satisfies . If , then ; closedness gives such that the -ball of radius around misses . Whenever , the distance identity puts in that ball, so . Thus the complement of is open, and this weak sublevel set is closed.
Conversely suppose every weak sublevel set is closed and let , so . Choose a finite real with when is finite, and choose when . The set is an open neighborhood of , as it is the complement of a closed weak sublevel set. Choose with and with . If , then and , so . The epigraph's complement therefore contains a ball around each of its points and is open, so the epigraph is closed.
Strictly separate a point from a nonempty closed convex Euclidean set
Statement
Let , let be nonempty, closed, and convex, and let . Then there are a nonzero and a real such that
Thus an affine hyperplane strictly separates the point from the entire set.
Facts & Assumptions
Given: The Euclidean inner product and norm, a nonempty closed convex , and .
The Euclidean inner product on : and the squared norm expands bilinearly.
Cauchy-Schwarz with its equality case, the triangle inequality for , the parallelogram law and polarisation: the Euclidean norm satisfies the triangle inequality, so is continuous by the reverse triangle inequality.
A continuous real-valued function on a nonempty compact metric space is bounded and attains a greatest and a least value: a continuous real-valued function on a nonempty compact metric space attains its minimum.
Proof
Choose and set . The set is nonempty and bounded; it is closed because is closed and the distance map is continuous by [L1]. Hence [L2] makes it compact, and the continuous function attains a minimum at some by [L3].
This is nearest to in all of : every satisfies . Put ; since , .
Fix and put . For , [F2] gives , so minimality of and [F1] imply . If , then ; setting contradicts this inequality whether the minimum is or the quotient. Hence .
Therefore for every , while . Taking proves strict separation.
Fenchel inequality and its equality condition
Statement
Let be proper, let , and let . Then . Equality holds exactly when , equivalently when attains the supremum defining ; in that case the supremum is finite.
Facts & Assumptions
Given: The Fenchel conjugate and subdifferential from Fenchel conjugate, biconjugate, and subdifferential.
Fenchel conjugate, biconjugate, and subdifferential: is the supremum of over , and means for every .
Proof
Since , the value is one of the values over which is the supremum; the stated inequality follows.
Equality means every satisfies , which rearranges to the subgradient inequality; for that inequality is automatic because . Conversely the subgradient inequalities make the value at a finite upper bound attained there, so .
Finite-dimensional Fenchel-Moreau biconjugation
Statement
Let and let be closed, proper, and convex in the sense of Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space. With the Fenchel conjugate and biconjugate of Fenchel conjugate, biconjugate, and subdifferential, one has
Facts & Assumptions
Given: The closed proper convex function and conjugates in the Statement.
Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space: proper means and ; convexity is the extended chord inequality; lower semicontinuity means closed weak sublevel sets.
Extended-real convexity and lower semicontinuity are characterized by the epigraph: under [F1], is nonempty, closed, and convex.
Strictly separate a point from a nonempty closed convex Euclidean set: a point outside a nonempty closed convex subset of has a strict linear separator.
Fenchel conjugate, biconjugate, and subdifferential: and are the stated extended suprema over the effective domain and finite conjugate domain.
Every complete ordered field is Archimedean: the canonical natural numbers are cofinal in ; for every there is a positive integer with .
Proof
For any with and any with , the defining supremum gives , hence ; taking the supremum over yields . If , the same upper bound is automatic.
Fix and a real . Apply [F3] to and the nonempty closed convex set , and negate the resulting separator to write for all . Upward closure forces . If , the inequality at would give , impossible. Thus .
Now fix and . Apply [F3] to and negate the separator to obtain for all . If , then for every , so with one has and .
Substituting for every gives the affine minorant . With , [F4] gives , hence . Since this holds for every , on .
In the case of step 1.3, the separator gives for every . Choose and a finite . Apply [F3] to and , reversing the separator orientation to obtain for every . Upward closure gives , and contradicts the inequality at , so . Set and ; substituting gives the affine minorant on , so [F4] gives . For each positive integer , define . Since on , this is still a minorant; [F4] gives and hence , where by step 1.3. For any prescribed , apply [L1] to to choose a positive integer with ; multiplying by gives . Hence exceeds every real bound, so .
The upper bound from step 1.1 and the lower bounds from steps 2.1 and 2.2 cover respectively finite and infinite values of , proving equality everywhere.
A coercive Fenchel tilt attains its minimum and conjugate supremum
Statement
Let be an integer, let be closed, proper, and convex, and let . Define . Assume is coercive, meaning that for every there is such that implies . Then has a finite global minimum at some . The supremum defining is finite and attained at , and . No uniqueness is asserted.
Facts & Assumptions
Given: The function conventions of Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space, the Fenchel definitions of Fenchel conjugate, biconjugate, and subdifferential, and the coercivity condition in the Statement.
Extended-real convexity and lower semicontinuity are characterized by the epigraph: the epigraph is closed if and only if every weak sublevel set is closed, equivalently if and only if the function is lower semicontinuous.
The Euclidean inner product on makes the shear linear, and Every Euclidean linear map has a unique matrix and satisfies for some supplies such that for all .
A metric space is compact if and only if every family of closed subsets with the finite intersection property has nonempty intersection: a family of closed subsets of a compact metric space with the finite intersection property has nonempty intersection.
Every nonempty set bounded below has an infimum and Greatest lower bound (infimum): every nonempty real set bounded below has an infimum; Epsilon characterisation of the infimum gives a point below for every .
Every nonempty finite set of reals has a maximum and a minimum: every nonempty finite set of real numbers has a maximum.
Fenchel inequality and its equality condition: equality in Fenchel's inequality at a finite point is equivalent to the subgradient inequality.
Proof
Since is proper, choose and put . By coercivity, first choose a radius such that whenever , then enlarge it to ; the same implication holds for this . Let ; it is nonempty, closed, bounded, and therefore compact by [L3].
The epigraph of is , because exactly when . By [L1], is closed. Fix ; openness of the complement of gives such that the Euclidean ball of radius around misses . Set . If , [L2] gives , so also lies outside . Thus the complement of is open and is closed. By [L1], is lower semicontinuous.
For each real , is relatively open in , since its complement is the weak sublevel . These sets cover because for every (properness excludes and the tilt is finite). Compactness gives a finite subcover, and [L6] supplies a largest real index among its finitely many indices. Since the are nested, , so every finite value of on is greater than .
Let . It is nonempty because and , and it is a real set bounded below by by step 2.1. It therefore has a real infimum . For every , [L5] gives with ; choosing with shows is nonempty. It is closed in by [L1]. Any nonempty finite subfamily has nonempty intersection, because the member with least positive is contained in all the others; the empty subfamily has intersection .
Applying [L4] to the family gives . The bound makes finite, so and . If , choose ; then would give , a contradiction. Thus .
For , step 1.1 gives , because implies . Thus is a global minimizer over , and its value is finite.
On , , and outside this domain . The global minimum is attained at , so the supremum in the definition of is finite, equals , and is attained at . Therefore ; [L7] yields .
Finite-mixture convex envelope and its supporting-face condition
Statement
Let and be integers, let , and let . Put
Thus is the finite convex hull of the listed points, defined here as their convex combinations.
For let and define
set for . Then every minimum is attained; is proper, lower semicontinuous, and convex; and it is pointwise greatest among convex functions satisfying for every . Consequently . If and is any minimizing mixture for , then every with satisfies
Thus all occupied data points lie on one supporting affine hyperplane. The assertion is finite-dimensional and makes no claim about infinite families.
Facts & Assumptions
Given: The finite data in the Statement, the extended-real conventions of Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space, and the conjugate and subgradient definitions of Fenchel conjugate, biconjugate, and subdifferential.
The set is nonempty, closed, and bounded: it contains each coordinate vector; it is the intersection of the closed coordinate half-spaces with the closed affine set ; and every coordinate satisfies , so . Hence Heine-Borel in : with the Euclidean metric a subset of is compact if and only if it is closed and bounded, and the proof by bisection uses no choice principle; the same holds on the real line makes it compact. The map is linear and continuous by [L1], so is closed and bounded, hence compact. The objective is also linear and continuous by [L1].
A continuous image of a compact metric space is compact (The image of a compact metric space under a continuous map is compact, and so is the image of any compact subset).
A continuous real function on a nonempty compact metric space attains its minimum (A continuous real-valued function on a nonempty compact metric space is bounded and attains a greatest and a least value).
The epigraph characterizations of extended convexity and lower semicontinuity are Extended-real convexity and lower semicontinuity are characterized by the epigraph.
A convex subset of contains every line segment between two of its points: a convex set contains every segment between two of its points.
A closed proper convex function equals its biconjugate (Finite-dimensional Fenchel-Moreau biconjugation).
Equality in Fenchel's inequality is equivalent to the subgradient relation (Fenchel inequality and its equality condition).
Every Euclidean linear map has a unique matrix and satisfies for some : every linear map between finite-dimensional Euclidean spaces is continuous.
Proof
The set contains each coordinate vector. The coordinate maps, the sum map , and are continuous by [L1]. For any continuous map into a Euclidean space and any closed set , the complement of is open: if , a ball about misses , and continuity gives a ball about mapped inside that ball. Thus is closed. Coordinate half-lines and singletons are closed, since a point outside either has a positive-distance ball missing it; a finite intersection of closed sets is closed because its complement is a finite union of open sets. These facts show that is closed and that is closed. Since on , both sets are bounded and hence compact by [F1]. For , the definition of makes nonempty. The linear objective is continuous by [L1] and attains its minimum on by [F3].
Let and . The affine map defining is continuous by [L1], so is compact by [F2]. The set is convex because convex combinations of points in remain in (nonnegativity and the unit-sum equation are preserved) and the defining map is affine; is closed and convex. If , a minimizing gives and , so . Conversely if with , then . Thus .
The coordinate vector with and all other weights zero shows . Let be convex with . For any weights , prove by induction on the number of positive weights: for it is equality; for , choose an index with , put , and apply the induction hypothesis to the normalized remaining weights. Convexity then gives . All terms on the right are finite because and the codomain excludes . For and any , this gives ; taking the minimum yields . For , . Thus is the greatest convex minorant of the data.
The set is convex: for , , and , by [F5]. To see it is closed, fix and write . The distance from to the ray is : if the closest ray point has height , and if it has height . This formula is continuous in because , and it is positive for every since . Compactness of and [F3] give a minimum ; every point of is at distance at least from , so the ball of radius about misses .
By [F4] and step 3.1, is convex and lower semicontinuous. It is proper because is nonempty, each value on is finite by step 1.1, and it is outside . Therefore [F6] gives .
Let and let attain the minimum defining . By [F7], . Also implies . Since is a weighted average of terms bounded above by , each term with equals that bound, proving the supporting-hyperplane formula.
Conditional finite-mixture envelope for an additive ordered representation
Statement
Assume the strict-reference representation conclusion of the draft supplier Additive extensive representation of compound comparison for its nonempty state set and stated comparison hypotheses. Let and be integers, and take a finite list of distinct states . Let and set for . Let be the unit-state compound defined in Tagged scalable compounds; it is a mass-one point mass by Compound mass is well-defined and additive. For , put and set . Suppose a map satisfies for every . For each , define the value to be if no has coordinate . Then the minimum represented value among those finite mixtures, with that empty-feasible-set convention, is exactly the finite-mixture envelope of Finite-mixture convex envelope and its supporting-face condition, with all its attainment, convexity, lower-semicontinuity, biconjugation, and supporting-face conclusions. This is the complete conditional transfer under the representation conclusion and affine coordinate assignment; the supplier definition and mass-one fact are provided locally.
Facts & Assumptions
Given: A finite family of states and coordinate data as in the Statement.
Additive extensive representation of compound comparison: under its strict-reference hypotheses the normalized assigns each compound the finite additive value and represents all equal-mass comparisons. Its normalized reference values are and . The supplier remains draft; this use records no independent proof acceptance.
Conditional premise: assume the strict-reference representation conclusion [L1] for the chosen state set and its listed comparison hypotheses.
The coordinate assignment is affine on the finite mixtures of the fixed states, exactly as specified in the Statement.
Tagged scalable compounds defines when and otherwise, nonnegative pointwise scaling with , and finite pointwise composition. Compound mass is well-defined and additive proves , finite mass additivity and homogeneity for every nonnegative scalar, and exactly for the empty compound.
Finite-mixture convex envelope and its supporting-face condition: for finite data the minimized weighted value is the proper closed convex envelope with the stated dual and support properties.
Proof
By [A1] and [L1], each is finite. For any , [L2] gives . If , its term is the empty compound and contributes zero; equivalently omit such terms, leaving only positive coefficients and never applying a positive-scaling comparison axiom at zero. The representation assigns the value . By [A3], its coordinate is . Since the states are distinct, the coefficient of in is exactly , so this parametrization is injective. Hence mixtures in this fixed family with coordinate correspond exactly to from [L3].
The minimum of over those mixtures is therefore by [L3], with when is empty. Every further conclusion in the Statement follows by applying the corresponding conclusion of [L3] to the same finite data. The point-mass and zero-coefficient cases are supplied by [L2]; the transfer remains conditional on [A1] and [A3] and records no independent acceptance of the draft representation.
The two-point lever rule on a scalar interval
Statement
Let with . A fraction satisfies exactly when and
This fraction is unique. At it is , and at it is ; no admissible fraction gives a value outside the endpoint interval.
Facts & Assumptions
Given: Ordered real numbers , an interval point , and a mixing fraction .
Complete ordered field (least-upper-bound property): is an ordered field, so division by the positive number is valid and preserves inequalities.
Proof
From one obtains . Since and , this gives and forces .
Conversely, if , the quotient lies in and substitution gives . The same forced quotient proves uniqueness and yields the two endpoint values.
Concave supporting bound, affine maxima, and Hessian sign
Statement
Let , , be open, and let be differentiable. For , suppose the whole segment lies in and its concavity inequality holds:
Then the supporting bound is . In particular this bound holds for every in any convex subset of on which is concave. No global convexity of is assumed.
Let be linear, , and . Suppose , for every , and for every the segment lies in and has the displayed concavity inequality. Then is a global maximum of on . If is convex and is strictly concave, meaning the inequality is strict for distinct endpoints and , the maximum is unique.
For the curvature clause, suppose and fix . If, for every , all sufficiently small satisfy and
then the Hessian bilinear form satisfies for every . This condition holds whenever is concave on a neighborhood of . Thus a function concave on an open convex region has negative-semidefinite Hessian there. Concavity alone does not assert strict curvature.
Facts & Assumptions
Given: The open domain, differentiability, and the stated admissible segments and concavity inequalities; affine constraints and stationarity for the maximum clause; strict concavity or regularity only for their respective further clauses.
A convex subset of contains every line segment between two of its points: every segment between points of a convex set stays in that set.
The total (Fréchet) derivative as the linear first-order approximation with remainder: at each point of differentiability.
If all partial derivatives exist on a neighbourhood and are continuous at a point, then the map is totally differentiable there with Jacobian derivative, The chain rule for total derivatives: and Euclidean maps and diffeomorphisms: continuous first and second coordinate partials give total derivatives of and its vector of first partials; thus a function restricted to the line is , with second derivative .
The mean value theorem, as the case of Cauchy's: for continuous on with and differentiable on there is with : a real function continuous on a closed interval and differentiable inside it has an interior derivative equal to its endpoint secant slope.
Proof
For an admissible pair and , the given concavity inequality yields . By [F2] the right side tends to as , proving the supporting bound. The convex-region specialization follows from [F1] and the concavity inequality on that region; it does not require any other segment of to be admissible.
For , linearity gives , so stationarity yields . The assumed segment from to permits step 1.1, hence , proving global maximality. If is convex and two distinct points maximize , their midpoint lies in by [F1], while strict concavity would give a strictly larger midpoint value. Thus the maximum is unique under the further hypothesis.
Under the and local midpoint hypotheses, fix and put near zero. By [F3], . Define . Differentiability of gives ; [F4] on the interval between and gives , since . Therefore . Its numerator is nonpositive by hypothesis, so . Concavity on a neighborhood implies that midpoint hypothesis on every sufficiently short centered segment; this proves all Hessian claims without strengthening the domain assumptions.
Second-order curvature tests on an affine feasible slice
Statement
Let and be integers, let be open and convex, let be linear, let , and let satisfy . Put . Assume is differentiable and has second directional derivatives represented by a continuous matrix field: there is a continuous map with symmetric values, and for every and ,
Assume stationarity for every . If for some , then is not a local minimum of on . If for every nonzero , then is a strict local minimum on that feasible slice. If , the latter conclusion holds because is the only feasible point.
Facts & Assumptions
Given: The open convex domain, linear constraint, differentiable function, continuous symmetric matrix field, directional second-derivative identity, and stationarity in the Statement.
A convex subset of contains every line segment between two of its points: the segment between two points of a convex set stays in that set.
The Euclidean inner product on : the Euclidean norm is .
A continuous real-valued function on a nonempty compact metric space is bounded and attains a greatest and a least value: a continuous real function on a nonempty compact set attains its minimum.
The mean value theorem, as the case of Cauchy's: for continuous on with and differentiable on there is with : if a real function is continuous on a closed interval and differentiable inside it, some interior derivative equals its endpoint secant slope.
Proof
If , then has only its zero vector, , and . There is no negative-curvature direction and is the only feasible point, so the strict-minimum conclusion holds. In the remaining argument suppose . Suppose and . Set for near . Openness of permits this definition; stationarity gives . The identity in the Statement gives wherever defined, and continuity of the entries of makes this negative for every sufficiently small .
Suppose and for each nonzero . The unit sphere is nonempty, closed by [L2] and continuity of the norm, and bounded; [L3] makes it compact. The quadratic polynomial is continuous, so [L4] gives .
Choose such a small . Applying [L5] to on gives for some , hence ; the same argument applies to every positive endpoint up to . Applying [L5] to on gives for some . Since , is feasible, so is not a local minimum.
By continuity of the finitely many entries of , choose so that implies for every unit vector : expand the difference as a finite sum of entry differences times , each with . If is feasible and , put . Then , and convexity of keeps in for . For , stationarity gives , while homogeneity of the quadratic form gives .
For any , [L5] applied to on yields for some , so . Applying [L5] to on gives for some . Thus every distinct feasible with has . If , implies , so is the only feasible point.
The feasible tangent cone for nonnegative stoichiometric amounts
Statement
Let , let be a stoichiometric matrix (column gives the signed species-amount change per unit extent of reaction ), and let be initial species amounts. Extents are measured in one fixed amount unit, so has species amounts in that same unit; is dimensionless. The feasible extent set is the polyhedron
At , let be the active species set. Define the Bouligand tangent cone to consist of all for which there are with and such that . Then
If is open with , and is differentiable with a local minimum at relative to , then for every . Conversely, if is convex and is convex and differentiable on , this directional inequality for every implies for every . Suppose is open, , is totally differentiable at , and near . For each , let have coordinate in position and in every other position; define . Then
The tangent-cone and optimality claims are mathematical deductions. They do not assert that a particular physical system obeys this model or is at equilibrium.
Facts & Assumptions
Given: The finite stoichiometric matrix, initial amounts, feasible extent set, Euclidean convergence, and differentiability/convexity hypotheses in the Statement.
The total (Fréchet) derivative as the linear first-order approximation with remainder: differentiability at gives as .
A convex subset of contains every line segment between two of its points: convexity of and the affine inequalities defining keep every segment between feasible points in .
The chain rule for total derivatives: : the derivative of a composition is the composition of its total derivatives.
Convex and strictly convex functions on Euclidean convex sets: a real-valued function is convex when for points in its convex domain and .
Every Euclidean linear map has a unique matrix and satisfies for some : a finite-dimensional linear map is bounded and therefore continuous.
Proof
Suppose , and choose sequences from its definition. For each active , feasibility gives , hence . Since [F5] makes the finite matrix map continuous, implies , so . This proves one inclusion.
Conversely suppose for all . For each inactive , put . If , restrict ; if , no restriction is needed. There are finitely many species, so choose a common no larger than all positive bounds (or if there are none). For , ; for inactive , the choice of gives for . Thus throughout that interval. Taking and any positive tending to zero proves .
By steps 1.1–1.2, every tangent has a feasible ray for all sufficiently small . Openness of keeps the initial part of this ray in . At a relative local minimum, for all sufficiently small ; differentiability [F1] makes its limit . Hence .
Now assume is convex and convex and differentiable. For any , put . For active , , so step 1.2 makes a tangent direction; the segment also lies in by [F2]. Let . [F4] gives for ; as , the left side tends to by [F1]. If every tangent derivative is nonnegative, then .
The affine map has derivative . By [F3], . Since and is linear, this equals , as claimed.
Local graph form at a nonsingular derivative minor
Statement
Let , let be open, and let be in the sense of Continuously differentiable maps, local inverses, and local diffeomorphisms. Suppose and some minor of the derivative matrix is invertible. This nonsingular-minor hypothesis is the explicit full-row-rank condition used here. If , then after permuting coordinates , there are open neighborhoods of and of and a unique map such that
Its derivative is
Thus the local zero set is a graph over free coordinates. If , the zero is locally isolated, so the local graph dimension is zero. Here “local graph dimension ” means a local graph parameterized by an open subset of , with a singleton counted as dimension zero.
Facts & Assumptions
Given: The open domain, map, zero, dimensions, and invertible derivative minor in the Statement.
Continuously differentiable maps, local inverses, and local diffeomorphisms: a map is when it is totally differentiable everywhere and the entries of its derivative matrix are continuous.
Invertible Euclidean linear maps: a square linear map is invertible when it has a two-sided linear inverse.
The Euclidean implicit function theorem with derivative formula: for an open set and a map with , , , and invertible second-block derivative , there are open neighborhoods and a unique map with exactly when on . After shrinking these neighborhoods, is invertible and .
The Euclidean inverse function theorem: a map between open subsets of with invertible derivative at a point is a local bijection with a inverse.
Every Euclidean linear map has a unique matrix and satisfies for some : linear maps between Euclidean spaces have coordinate matrices and are bounded, hence continuous; a coordinate permutation is an invertible linear map.
The chain rule for total derivatives: : composing a map with a linear coordinate permutation preserves total differentiability and the derivative formula; [L3] and The metric topology: a set is open when every one of its points has a ball around it inside the set; closed means open complement make that permutation a homeomorphism, so it preserves open domains.
Proof
First suppose . Choose the coordinate permutation that puts the columns of the stated invertible minor into the second block , and write the remaining coordinates as . Composing with the inverse permutation preserves openness and the property by [F1], [L3], and [L4]; its second-block derivative at is exactly the chosen invertible minor in the sense of [F2]. Since and , [L1] applies and gives the neighborhoods, unique graph , equivalence, and displayed derivative formula.
The graph map is one-to-one because its first coordinate is , and its inverse on the graph is coordinate projection. Its parameter domain is open in , so this is the claimed local graph dimension.
Now suppose . The selected minor is the whole square derivative matrix , so it is invertible by [F2]. Apply [L2] on neighborhoods of and of . Injectivity of and imply for exactly when . Thus the local zero set is a singleton and has the stated zero-dimensional graph form.
Regular rank form of the finite-component phase dimension count
Statement
Let be the number of components and the number of phases. Use common positive real coordinates , expressed in fixed units if they are given a physical interpretation, and, for each phase , an interior composition vector
with the convention and . The final component fraction is . The ambient coordinate domain is open in , where . For each phase and component , let be a real-valued coordinate function; these are mathematical maps and no thermodynamic potential or physical realization is assumed.
For , define the coexistence equations
At a solution , assume some derivative minor of is invertible. Then the local solution set is a graph of dimension
For there are no coexistence equations and the coordinate domain itself has dimension . In a specified reactive variant with , let be linearly independent dimensionless stoichiometric vectors and add the affinity equations . If the combined equation map has an invertible derivative minor at a solution and , its local zero set has dimension
These are conditional local dimensions under the displayed nonsingular-minor assumptions. No dimension formula follows at singular solutions, on composition boundaries, or from equation counting alone; no empirical or general physical phase rule is asserted.
Facts & Assumptions
Given: The finite integers, open coordinate domain, chemical-potential coordinate functions, coexistence equations, and nonsingular-minor assumptions in the Statement.
Continuously differentiable maps, local inverses, and local diffeomorphisms: means total differentiability with continuous derivative-matrix entries.
Local graph form at a nonsingular derivative minor: for an open , a map , , and a zero with an invertible derivative minor, the local zero set is a graph over coordinates when , and an isolated point when .
Sums and scalar multiples of totally differentiable maps are totally differentiable with the expected derivatives: if are totally differentiable at and , then and are totally differentiable there, with and . Repeated application gives the derivative of every finite linear combination; continuity of its derivative entries must also be checked to establish regularity.
Proof
For each phase let select , and write . The same coordinate selection on increments is linear and satisfies . Substituting into the first-order expansion of gives derivative and remainder , with zero remainder when . Its derivative entries are selected entries of or zero; they are continuous because does not increase distances and the original entries are continuous. For , has scalar components, each a difference of these lifted maps. By [L2] their derivative rows are ; the entries are continuous since the increment of each difference is bounded by the sum of the two entry increments. The finitely many scalar remainders assemble to a vector remainder , since its norm is at most times their largest absolute value. Thus is by [F1]. The assumed minor entails , so [L1] gives local graph dimension , including an isolated point if .
If , no phase-equality equations are indexed because there is no . The local solution set is all of the open domain , which has coordinates.
In the reactive variant put if . The lifted maps constructed in step 1.1 are for every . By [L2], . For each derivative entry, its increment is bounded by the finite sum of times the corresponding continuous entry increments, which tends to zero. Thus the affinity derivative entries are continuous. As in step 1.1, the finitely many scalar remainders assemble to a vector remainder , so the combined map is by [F1] and has scalar equations. Since , its stated minor lets [L1] give graph dimension , with an isolated point if . Linear independence of the identifies distinct reaction directions, while the nonsingular derivative minor remains a separate assumption.
5 · Examples, experiments and counterexamples
None yet.
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