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Nonsmooth Equilibrium

1 · Prerequisites

2 · Summary

This page develops finite-dimensional convex analysis and local equilibrium mathematics. It defines proper extended-real convex functions, lower semicontinuity, Fenchel conjugates and subgradients; proves epigraph characterizations, strict separation, Fenchel equality, and biconjugation; and gives an explicit coercive-tilt attainment result. The separation and biconjugation arguments include the vertical-separator case, including points outside the effective domain.

The finite-mixture result is restricted to a finite list of data: its minimum is attained on a simplex, its envelope is proper, closed and convex, and occupied points satisfy one supporting-affine equality. A conditional corollary transfers this conclusion to an additive compound representation only under the exact batch-3 interface and an affine coordinate assignment. The required page td-math-ordered-composition and its current additive-representation proof are present, with owner Step 1 proof-readiness recorded. This supplies the authored prerequisite context; both suppliers remain draft and independent review is pending. The corollary is conditional on the exact representation hypotheses, not an assertion of physical adoption or prior review acceptance. The scalar lever rule records its endpoint and uniqueness cases.

The remaining results keep smooth and nonsmooth claims separate. The concavity lemma proves supporting bounds along admitted segments, global stationary maxima on the stated affine slices, and local Hessian semidefiniteness without assuming convexity of an entire state domain. The constrained-curvature test assumes a continuous second directional form and stationarity on an affine feasible slice. The stoichiometric lemma proves the tangent cone for finite linear species-balance inequalities and states the directional optimality condition. The local implicit-rank theorem yields a graph only at a nonsingular derivative minor; the phase-dimension count is conditional on that rank and on interior composition coordinates. These are mathematical deductions and make no empirical claim about an actual material or equilibrium.

3 · Logical flowchart

4 · Definitions, postulates, theorems and proofs

DefinitionDefinition: Literature-sourcedProof: Not applicableverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space

Definition

Fix an integer d≥1. Write R‾=R∪{+∞} with its usual order and extended addition; in a convex combination set 0⋅(+∞)=0 and λ⋅(+∞)=+∞ for λ>0. A function f:Rd→R‾ is proper when it never takes the value −∞ and its effective domain

dom⁡f:={x∈Rd:f(x)<+∞}

is nonempty. It is convex when

f((1−t)x+ty)≤(1−t)f(x)+tf(y)(x,y∈Rd, t∈[0,1]).

It is lower semicontinuous when each weak sublevel set {x:f(x)≤a} is closed in the Euclidean topology, for every a∈R. Its epigraph is

epi⁡f:={(x,r)∈Rd×R:f(x)≤r}.

On this page “closed proper convex” means proper, convex, and lower semicontinuous in these conventions. The pairing of p,x∈Rd is the Euclidean inner product ⟨p,x⟩ of The Euclidean inner product ⟨x,y⟩=∑k<nxkyk on Rn.

DefinitionDefinition: Literature-sourcedProof: Not applicableverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

Fenchel conjugate, biconjugate, and subdifferential

Definition

Let f:Rd→R‾ be proper in the sense of Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space. Its Fenchel conjugate is f∗:Rd→R‾,

f∗(p):=sup⁡x∈dom⁡f(⟨p,x⟩−f(x)).

The supremum is taken in R‾; its defining set is nonempty and consists of real numbers, so f∗(p)∈R∪{+∞}. The biconjugate is an extended-real expression that may also take −∞ when its defining supremum is over the empty set:

f∗∗(x):=sup⁡{p∈Rd:f∗(p)<+∞}(⟨p,x⟩−f∗(p)),

with the convention sup⁡∅=−∞. For x∈dom⁡f, the subdifferential is

∂f(x):={p∈Rd:f(y)≥f(x)+⟨p,y−x⟩ for every y∈Rd};

set ∂f(x)=∅ for x∉dom⁡f. A vector in ∂f(x) is a subgradient at x. All pairings use The Euclidean inner product ⟨x,y⟩=∑k<nxkyk on Rn.

LemmaStatement: Literature-sourcedProof: AI-adaptedverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

Extended-real convexity and lower semicontinuity are characterized by the epigraph

Statement

Let d≥1 and let f:Rd→R‾ use the conventions of Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space. Then f is convex if and only if epi⁡f is a convex subset of Rd+1, and f is lower semicontinuous if and only if epi⁡f is closed.

Facts & Assumptions

Given: d≥1, the extended-real conventions and epigraph of the Statement, and the Euclidean topology.

[F1]

Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space: convexity is the extended chord inequality; lower semicontinuity means that every weak sublevel set is closed.

[F2]

The metric topology: a set is open when every one of its points has a ball around it inside the set; closed means open complement: a set is open when every point has a positive-radius metric ball contained in the set; it is closed exactly when its complement is open. Here the metrics are Euclidean.

Proof

technique · direct
1.1givenF1algebra

Suppose f is convex and take (x,r),(y,s)∈epi⁡f. For t∈[0,1], the chord inequality gives f((1−t)x+ty)≤(1−t)f(x)+tf(y)≤(1−t)r+ts, so (1−t)(x,r)+t(y,s)∈epi⁡f. Thus the epigraph is convex.

1.2F1algebra

Conversely, if the epigraph is convex and f(x),f(y) are finite, then (x,f(x)) and (y,f(y)) lie in it; their convex combination lies in it and gives the chord inequality. If either value is +∞ and its coefficient is positive, the right side is +∞ and the inequality is automatic; at t=0 or t=1 it is equality.

1.3F1F2construct

Suppose epi⁡f is closed and fix a∈R. For n=d,d+1 write dn(u,v)=(∑j=1n(uj−vj)2)1/2 for the Euclidean metric. The slice map ia(x)=(x,a) satisfies dd+1(ia(x),ia(y))=dd(x,y). If f(x)>a, then (x,a)∉epi⁡f; closedness gives ε>0 such that the dd+1-ball of radius ε around (x,a) misses epi⁡f. Whenever dd(x,y)<ε, the distance identity puts (y,a) in that ball, so f(y)>a. Thus the complement of {y:f(y)≤a} is open, and this weak sublevel set is closed.

2.1givenF1F2construct∎

Conversely suppose every weak sublevel set is closed and let (x,r)∉epi⁡f, so r<f(x). Choose a finite real a with r<a<f(x) when f(x) is finite, and choose a=r+1 when f(x)=+∞. The set N={y:f(y)>a} is an open neighborhood of x, as it is the complement of a closed weak sublevel set. Choose δ>0 with Bd(x,δ)⊆N and η>0 with r+η<a. If dd+1((x,r),(y,s))<min⁡(δ,η), then y∈N and s<r+η<a<f(y), so (y,s)∉epi⁡f. The epigraph's complement therefore contains a ball around each of its points and is open, so the epigraph is closed.

LemmaStatement: Literature-sourcedProof: AI-adaptedverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

Strictly separate a point from a nonempty closed convex Euclidean set

Statement

Let n≥1, let E⊆Rn be nonempty, closed, and convex, and let z∉E. Then there are a nonzero u∈Rn and a real c such that

⟨u,e⟩≤c<⟨u,z⟩(e∈E).

Thus an affine hyperplane strictly separates the point from the entire set.

Facts & Assumptions

Given: The Euclidean inner product and norm, a nonempty closed convex E⊆Rn, and z∉E.

[F1]

The Euclidean inner product ⟨x,y⟩=∑k<nxkyk on Rn: ∥x∥22=⟨x,x⟩ and the squared norm expands bilinearly.

[F2]

A convex subset of Rm contains every line segment between two of its points: for e0,e1∈E and t∈[0,1], (1−t)e0+te1∈E.

[L1]

Cauchy-Schwarz ∣⟨x,y⟩∣≤∥x∥2∥y∥2 with its equality case, the triangle inequality for ∥⋅∥2, the parallelogram law and polarisation: the Euclidean norm satisfies the triangle inequality, so e↦∥z−e∥2 is continuous by the reverse triangle inequality.

[L3]

A continuous real-valued function on a nonempty compact metric space is bounded and attains a greatest and a least value: a continuous real-valued function on a nonempty compact metric space attains its minimum.

Proof

technique · direct
1.1givenL1L2L3choose

Choose e0∈E and set R=∥z−e0∥2+1. The set K=E∩{e:∥z−e∥2≤R} is nonempty and bounded; it is closed because E is closed and the distance map is continuous by [L1]. Hence [L2] makes it compact, and the continuous function e↦∥z−e∥22 attains a minimum at some e∗∈K by [L3].

2.1step 1.1givenalgebra

This e∗ is nearest to z in all of E: every e∈E∖K satisfies ∥z−e∥2>R>∥z−e0∥2≥∥z−e∗∥2. Put u=z−e∗; since z∉E, u≠0.

3.1F1F2step 2.1algebra

Fix e∈E and put v=e−e∗. For 0<t≤1, [F2] gives e∗+tv∈E, so minimality of e∗ and [F1] imply 2t⟨u,v⟩≤t2∥v∥22. If ⟨u,v⟩>0, then v≠0; setting t=min⁡{1,⟨u,v⟩/∥v∥22} contradicts this inequality whether the minimum is 1 or the quotient. Hence ⟨u,v⟩≤0.

4.1F1step 3.1algebra∎

Therefore ⟨u,e⟩≤⟨u,e∗⟩ for every e∈E, while ⟨u,z⟩=⟨u,e∗⟩+∥u∥22>⟨u,e∗⟩. Taking c=⟨u,e∗⟩ proves strict separation.

LemmaStatement: Literature-sourcedProof: AI-adaptedverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

Fenchel inequality and its equality condition

Statement

Let f:Rd→R‾ be proper, let x∈dom⁡f, and let p∈Rd. Then f∗(p)≥⟨p,x⟩−f(x). Equality holds exactly when p∈∂f(x), equivalently when x attains the supremum defining f∗(p); in that case the supremum is finite.

Facts & Assumptions

Given: The Fenchel conjugate and subdifferential from Fenchel conjugate, biconjugate, and subdifferential.

[F1]

Fenchel conjugate, biconjugate, and subdifferential: f∗(p) is the supremum of ⟨p,y⟩−f(y) over y∈dom⁡f, and p∈∂f(x) means f(y)≥f(x)+⟨p,y−x⟩ for every y.

Proof

technique · direct
1.1F1given

Since x∈dom⁡f, the value ⟨p,x⟩−f(x) is one of the values over which f∗(p) is the supremum; the stated inequality follows.

2.1F1algebra∎

Equality means every y∈dom⁡f satisfies ⟨p,y⟩−f(y)≤⟨p,x⟩−f(x), which rearranges to the subgradient inequality; for y∉dom⁡f that inequality is automatic because f(y)=+∞. Conversely the subgradient inequalities make the value at x a finite upper bound attained there, so f∗(p)=⟨p,x⟩−f(x).

TheoremStatement: Literature-sourcedProof: AI-adaptedverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

Finite-dimensional Fenchel-Moreau biconjugation

Statement

Let d≥1 and let f:Rd→R‾ be closed, proper, and convex in the sense of Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space. With the Fenchel conjugate and biconjugate of Fenchel conjugate, biconjugate, and subdifferential, one has

f∗∗(x)=f(x)(x∈Rd).

Facts & Assumptions

Given: The closed proper convex function and conjugates in the Statement.

[F1]

Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space: proper means dom⁡f≠∅ and f>−∞; convexity is the extended chord inequality; lower semicontinuity means closed weak sublevel sets.

[F2]

Extended-real convexity and lower semicontinuity are characterized by the epigraph: under [F1], epi⁡f is nonempty, closed, and convex.

[F3]

Strictly separate a point from a nonempty closed convex Euclidean set: a point outside a nonempty closed convex subset of Rd+1 has a strict linear separator.

[F4]

Fenchel conjugate, biconjugate, and subdifferential: f∗(p) and f∗∗(x) are the stated extended suprema over the effective domain and finite conjugate domain.

[L1]

Every complete ordered field is Archimedean: the canonical natural numbers are cofinal in R; for every q∈R there is a positive integer k with q<k.

Proof

technique · direct
1.1F4givenalgebra

For any x with f(x)<+∞ and any p with f∗(p)<+∞, the defining supremum gives f∗(p)≥⟨p,x⟩−f(x), hence ⟨p,x⟩−f∗(p)≤f(x); taking the supremum over p yields f∗∗(x)≤f(x). If f(x)=+∞, the same upper bound is automatic.

1.2F2F3givenalgebra

Fix x∈dom⁡f and a real t<f(x). Apply [F3] to (x,t) and the nonempty closed convex set epi⁡f, and negate the resulting separator to write ⟨a,y⟩+bs≥c>⟨a,x⟩+bt for all (y,s)∈epi⁡f. Upward closure forces b≥0. If b=0, the inequality at (x,f(x))∈epi⁡f would give ⟨a,x⟩≥c>⟨a,x⟩, impossible. Thus b>0.

1.3F2F3F4algebra

Now fix x∉dom⁡f and t∈R. Apply [F3] to (x,t) and negate the separator to obtain ⟨a,y⟩+bs≥c>⟨a,x⟩+bt for all (y,s)∈epi⁡f. If b>0, then f(y)≥−⟨a/b,y⟩+c/b for every y∈dom⁡f, so with p=−a/b one has f∗(p)≤−c/b<+∞ and f∗∗(x)≥⟨p,x⟩−f∗(p)≥(c−⟨a,x⟩)/b>t.

2.1F4step 1.2algebra

Substituting (y,f(y)) for every y∈dom⁡f gives the affine minorant ℓ(y)=−⟨a/b,y⟩+c/b≤f(y). With p=−a/b, [F4] gives f∗(p)≤−c/b, hence f∗∗(x)≥⟨p,x⟩−f∗(p)≥ℓ(x)>t. Since this holds for every t<f(x), f∗∗(x)≥f(x) on dom⁡f.

2.2F1F2F3F4L1step 1.3choosealgebra

In the b=0 case of step 1.3, the separator gives ⟨a,y⟩≥c>⟨a,x⟩ for every y∈dom⁡f. Choose y0∈dom⁡f and a finite t0<f(y0). Apply [F3] to (y0,t0) and epi⁡f, reversing the separator orientation to obtain ⟨a0,y⟩+b0s≥c0>⟨a0,y0⟩+b0t0 for every (y,s)∈epi⁡f. Upward closure gives b0≥0, and b0=0 contradicts the inequality at (y0,f(y0)), so b0>0. Set p0=−a0/b0 and r0=c0/b0; substituting (y,f(y)) gives the affine minorant ℓ0(y)=⟨p0,y⟩+r0≤f(y) on dom⁡f, so [F4] gives f∗(p0)≤−r0. For each positive integer k, define ℓk(y)=ℓ0(y)+k(c−⟨a,y⟩)=⟨p0−ka,y⟩+(r0+kc). Since c−⟨a,y⟩≤0 on dom⁡f, this is still a minorant; [F4] gives f∗(p0−ka)≤−(r0+kc)<+∞ and hence f∗∗(x)≥ℓk(x)=ℓ0(x)+kδ, where δ:=c−⟨a,x⟩>0 by step 1.3. For any prescribed B∈R, apply [L1] to q=(B−ℓ0(x))/δ to choose a positive integer k with q<k; multiplying by δ>0 gives ℓ0(x)+kδ>B. Hence f∗∗(x) exceeds every real bound, so f∗∗(x)=+∞=f(x).

3.1step 1.1step 2.1step 2.2∎

The upper bound from step 1.1 and the lower bounds from steps 2.1 and 2.2 cover respectively finite and infinite values of f(x), proving equality everywhere.

TheoremStatement: Literature-sourcedProof: AI-adaptedverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

A coercive Fenchel tilt attains its minimum and conjugate supremum

Statement

Let d≥1 be an integer, let f:Rd→R‾ be closed, proper, and convex, and let p∈Rd. Define g(x)=f(x)−⟨p,x⟩. Assume g is coercive, meaning that for every M∈R there is R>0 such that ∥x∥2≥R implies g(x)>M. Then g has a finite global minimum at some x∗∈dom⁡f. The supremum defining f∗(p) is finite and attained at x∗, and p∈∂f(x∗). No uniqueness is asserted.

Facts & Assumptions

Given: The function conventions of Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space, the Fenchel definitions of Fenchel conjugate, biconjugate, and subdifferential, and the coercivity condition in the Statement.

[L1]

Extended-real convexity and lower semicontinuity are characterized by the epigraph: the epigraph is closed if and only if every weak sublevel set is closed, equivalently if and only if the function is lower semicontinuous.

[L2]

The Euclidean inner product ⟨x,y⟩=∑k<nxkyk on Rn makes the shear T(x,r)=(x,r+⟨p,x⟩) linear, and Every Euclidean linear map has a unique matrix and satisfies ∥Lh∥2≤K∥h∥2 for some K≥0 supplies K≥0 such that ∥Tz−Tz′∥2≤K∥z−z′∥2 for all z,z′∈Rd+1.

[L4]

A metric space is compact if and only if every family of closed subsets with the finite intersection property has nonempty intersection: a family of closed subsets of a compact metric space with the finite intersection property has nonempty intersection.

[L5]

Every nonempty set bounded below has an infimum and Greatest lower bound (infimum): every nonempty real set bounded below has an infimum; Epsilon characterisation of the infimum gives a point below m+ε for every ε>0.

[L6]

Every nonempty finite set of reals has a maximum and a minimum: every nonempty finite set of real numbers has a maximum.

[L7]

Fenchel inequality and its equality condition: equality in Fenchel's inequality at a finite point is equivalent to the subgradient inequality.

Proof

technique · direct
1.1givenL3choose

Since f is proper, choose x0∈dom⁡f and put c=g(x0)∈R. By coercivity, first choose a radius R0>0 such that g(x)>c+1 whenever ∥x∥2≥R0, then enlarge it to R>max⁡{R0,∥x0∥2}; the same implication holds for this R. Let K={x:∥x∥2≤R}; it is nonempty, closed, bounded, and therefore compact by [L3].

1.2L1L2givenalgebra

The epigraph of g is T−1(epi⁡f), because g(x)≤r exactly when f(x)≤r+⟨p,x⟩. By [L1], epi⁡f is closed. Fix z∉T−1(epi⁡f); openness of the complement of epi⁡f gives ε>0 such that the Euclidean ball of radius ε around Tz misses epi⁡f. Set ρ=ε/(K+1)>0. If ∥z′−z∥2<ρ, [L2] gives ∥Tz′−Tz∥2≤K∥z′−z∥2<ε, so Tz′ also lies outside epi⁡f. Thus the complement of T−1(epi⁡f) is open and epi⁡g is closed. By [L1], g is lower semicontinuous.

2.1L1L3L6givenstep 1.1algebra

For each real r>0, Ur={x∈K:g(x)>−r} is relatively open in K, since its complement is the weak sublevel K∩{g≤−r}. These sets cover K because g(x)∈R∪{+∞} for every x (properness excludes −∞ and the tilt is finite). Compactness gives a finite subcover, and [L6] supplies a largest real index r∗ among its finitely many indices. Since the Ur are nested, Ur∗=K, so every finite value of g on K is greater than −r∗.

3.1L1L4L5step 1.1step 2.1choose

Let S:={g(x):x∈K, g(x)<+∞}. It is nonempty because x0∈K and g(x0)=c, and it is a real set bounded below by −r∗ by step 2.1. It therefore has a real infimum m. For every ε>0, [L5] gives s∈S with s<m+ε; choosing x∈K with g(x)=s shows Fε:=K∩{x:g(x)≤m+ε} is nonempty. It is closed in K by [L1]. Any nonempty finite subfamily has nonempty intersection, because the member with least positive ε is contained in all the others; the empty subfamily has intersection K≠∅.

4.1L4step 3.1algebrachoose

Applying [L4] to the family (Fε)ε>0 gives x∗∈⋂ε>0Fε. The bound g(x∗)≤m+1 makes g(x∗) finite, so g(x∗)∈S and m≤g(x∗). If g(x∗)>m, choose ε=(g(x∗)−m)/2>0; then x∗∈Fε would give g(x∗)≤m+ε<g(x∗), a contradiction. Thus g(x∗)=m.

5.1step 1.1step 4.1algebra

For x∉K, step 1.1 gives g(x)>c+1≥m+1, because x0∈K implies m≤c. Thus x∗ is a global minimizer over Rd, and its value m is finite.

6.1givenL7step 5.1algebra∎

On dom⁡f, −g(x)=⟨p,x⟩−f(x), and outside this domain g(x)=+∞. The global minimum m is attained at x∗∈dom⁡f, so the supremum in the definition of f∗(p) is finite, equals −m, and is attained at x∗. Therefore f∗(p)=⟨p,x∗⟩−f(x∗); [L7] yields p∈∂f(x∗).

TheoremStatement: Literature-sourcedProof: AI-adaptedverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

Finite-mixture convex envelope and its supporting-face condition

Statement

Let m≥1 and d≥1 be integers, let q1,…,qm∈Rd, and let a1,…,am∈R. Put

Δm={θ∈Rm:θi≥0, ∑i=1mθi=1},P:={∑i=1mθiqi:θ∈Δm}.

Thus P is the finite convex hull of the listed points, defined here as their convex combinations.

For x∈P let Θx={θ∈Δm:∑iθiqi=x} and define

fmix(x)=min⁡θ∈Θx∑i=1mθiai;

set fmix(x)=+∞ for x∉P. Then every minimum is attained; fmix is proper, lower semicontinuous, and convex; and it is pointwise greatest among convex functions h:Rd→R‾ satisfying h(qi)≤ai for every i. Consequently fmix=fmix∗∗. If p∈∂fmix(x) and θ is any minimizing mixture for x, then every i with θi>0 satisfies

ai=⟨p,qi⟩−fmix∗(p).

Thus all occupied data points (qi,ai) lie on one supporting affine hyperplane. The assertion is finite-dimensional and makes no claim about infinite families.

Facts & Assumptions

Given: The finite data in the Statement, the extended-real conventions of Proper, convex, and lower-semicontinuous extended-real functions on Euclidean space, and the conjugate and subgradient definitions of Fenchel conjugate, biconjugate, and subdifferential.

[F1]

The set Δm is nonempty, closed, and bounded: it contains each coordinate vector; it is the intersection of the closed coordinate half-spaces {θi≥0} with the closed affine set {∑iθi=1}; and every coordinate satisfies 0≤θi≤1, so ∥θ∥22=∑iθi2≤m. Hence Heine-Borel in Rn: with the Euclidean metric a subset of Rn is compact if and only if it is closed and bounded, and the proof by bisection uses no choice principle; the same holds on the real line makes it compact. The map Q(θ)=∑iθiqi is linear and continuous by [L1], so Θx=Δm∩Q−1({x}) is closed and bounded, hence compact. The objective θ↦∑iθiai is also linear and continuous by [L1].

[F3]

A continuous real function on a nonempty compact metric space attains its minimum (A continuous real-valued function on a nonempty compact metric space is bounded and attains a greatest and a least value).

[F4]

The epigraph characterizations of extended convexity and lower semicontinuity are Extended-real convexity and lower semicontinuity are characterized by the epigraph.

[F5]

A convex subset of Rm contains every line segment between two of its points: a convex set contains every segment between two of its points.

[F6]

A closed proper convex function equals its biconjugate (Finite-dimensional Fenchel-Moreau biconjugation).

[F7]

Equality in Fenchel's inequality is equivalent to the subgradient relation (Fenchel inequality and its equality condition).

Proof

technique · direct
1.1F1F3L1givenconstruct

The set Δm contains each coordinate vector. The coordinate maps, the sum map θ↦∑iθi, and Q are continuous by [L1]. For any continuous map T into a Euclidean space and any closed set K, the complement of T−1(K) is open: if T(z)∉K, a ball about T(z) misses K, and continuity gives a ball about z mapped inside that ball. Thus T−1(K) is closed. Coordinate half-lines [0,∞) and singletons are closed, since a point outside either has a positive-distance ball missing it; a finite intersection of closed sets is closed because its complement is a finite union of open sets. These facts show that Δm is closed and that Θx=Δm∩Q−1({x}) is closed. Since 0≤θi≤1 on Δm, both sets are bounded and hence compact by [F1]. For x∈P, the definition of P makes Θx nonempty. The linear objective is continuous by [L1] and attains its minimum on Θx by [F3].

2.1F1F2L1step 1.1construct

Let C={∑iθi(qi,ai):θ∈Δm}⊂Rd+1 and V={(0,s):s≥0}. The affine map defining C is continuous by [L1], so C is compact by [F2]. The set C is convex because convex combinations of points in Δm remain in Δm (nonnegativity and the unit-sum equation are preserved) and the defining map is affine; V is closed and convex. If (x,r)∈epi⁡fmix, a minimizing θ∈Θx gives (x,fmix(x))∈C and r−fmix(x)≥0, so (x,r)∈C+V. Conversely if (x,r)=∑iθi(qi,ai)+(0,s) with s≥0, then fmix(x)≤∑iθiai≤r. Thus epi⁡fmix=C+V.

2.2F4givenstep 1.1algebrainduction

The coordinate vector with θi=1 and all other weights zero shows fmix(qi)≤ai. Let h:Rd→R‾ be convex with h(qi)≤ai. For any weights θ∈Δm, prove h(∑iθiqi)≤∑iθih(qi) by induction on the number N of positive weights: for N=1 it is equality; for N>1, choose an index j with 0<θj<1, put y=(1−θj)−1∑i≠jθiqi, and apply the induction hypothesis to the normalized remaining weights. Convexity then gives h(∑iθiqi)≤θjh(qj)+(1−θj)h(y)≤∑iθih(qi). All terms on the right are finite because h(qi)≤ai and the codomain excludes −∞. For x∈P and any θ∈Θx, this gives h(x)≤∑iθiai; taking the minimum yields h(x)≤fmix(x). For x∉P, h(x)≤+∞=fmix(x). Thus fmix is the greatest convex minorant of the data.

3.1F1F2F3F5step 2.1algebra

The set C+V is convex: for c1,c2∈C, v1,v2∈V, and t∈[0,1], (1−t)(c1+v1)+t(c2+v2)=((1−t)c1+tc2)+((1−t)v1+tv2)∈C+V by [F5]. To see it is closed, fix z=(x,r)∉C+V and write c=(u,a)∈C. The distance from z to the ray c+V is ρz(c)=∥x−u∥22+max⁡{a−r,0}2: if r≥a the closest ray point has height r, and if r<a it has height a. This formula is continuous in c because max⁡{w,0}=(w+∣w∣)/2, and it is positive for every c∈C since z∉c+V. Compactness of C and [F3] give a minimum δ>0; every point of C+V is at distance at least δ from z, so the ball of radius δ/2 about z misses C+V.

4.1F4F6step 1.1step 3.1

By [F4] and step 3.1, fmix is convex and lower semicontinuous. It is proper because P is nonempty, each value on P is finite by step 1.1, and it is +∞ outside P. Therefore [F6] gives fmix=fmix∗∗.

5.1F7step 1.1step 2.2algebra∎

Let p∈∂fmix(x) and let θ attain the minimum defining fmix(x). By [F7], fmix∗(p)=⟨p,x⟩−fmix(x). Also fmix(qi)≤ai implies ⟨p,qi⟩−ai≤⟨p,qi⟩−fmix(qi)≤fmix∗(p). Since ⟨p,x⟩−fmix(x)=∑iθi(⟨p,qi⟩−ai) is a weighted average of terms bounded above by fmix∗(p), each term with θi>0 equals that bound, proving the supporting-hyperplane formula.

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Conditional finite-mixture envelope for an additive ordered representation

Statement

Assume the strict-reference representation conclusion of the draft supplier Additive extensive representation of compound comparison for its nonempty state set X and stated comparison hypotheses. Let d≥1 and m≥1 be integers, and take a finite list of distinct states s1,…,sm∈X. Let q1,…,qm∈Rd and set ai:=S(si) for 1≤i≤m. Let es be the unit-state compound defined in Tagged scalable compounds; it is a mass-one point mass by Compound mass is well-defined and additive. For θ∈Δm, put Mθ=∑iθiesi and set V(θ):=∑iθiS(si). Suppose a map χ:{Mθ:θ∈Δm}→Rd satisfies χ(Mθ)=∑iθiqi for every θ∈Δm. For each x∈Rd, define the value to be +∞ if no θ∈Δm has coordinate x. Then the minimum represented value among those finite mixtures, with that empty-feasible-set convention, is exactly the finite-mixture envelope fmix(x) of Finite-mixture convex envelope and its supporting-face condition, with all its attainment, convexity, lower-semicontinuity, biconjugation, and supporting-face conclusions. This is the complete conditional transfer under the representation conclusion and affine coordinate assignment; the supplier definition and mass-one fact are provided locally.

Facts & Assumptions

Given: A finite family of states and coordinate data as in the Statement.

[L1]

Additive extensive representation of compound comparison: under its strict-reference hypotheses the normalized S:X→R assigns each compound ∑iaiexi the finite additive value ∑iaiS(xi) and represents all equal-mass comparisons. Its normalized reference values are 0 and 1. The supplier remains draft; this use records no independent proof acceptance.

[A1]

Conditional premise: assume the strict-reference representation conclusion [L1] for the chosen state set and its listed comparison hypotheses.

[A3]

The coordinate assignment χ is affine on the finite mixtures of the fixed states, exactly as specified in the Statement.

[L2]

Tagged scalable compounds defines es(x)=1 when x=s and 0 otherwise, nonnegative pointwise scaling with 0es=0, and finite pointwise composition. Compound mass is well-defined and additive proves m(es)=1, finite mass additivity and homogeneity for every nonnegative scalar, and m(C)=0 exactly for the empty compound.

[L3]

Finite-mixture convex envelope and its supporting-face condition: for finite data (qi,ai) the minimized weighted value is the proper closed convex envelope with the stated dual and support properties.

Proof

technique · direct
1.1A1A3L1L2L3algebra

By [A1] and [L1], each ai=S(si) is finite. For any θ∈Δm, [L2] gives m(Mθ)=∑iθim(esi)=∑iθi=1. If θi=0, its term is the empty compound and contributes zero; equivalently omit such terms, leaving only positive coefficients and never applying a positive-scaling comparison axiom at zero. The representation assigns Mθ the value V(θ)=∑iθiai. By [A3], its coordinate is ∑iθiqi. Since the states are distinct, the coefficient of si in Mθ is exactly θi, so this parametrization is injective. Hence mixtures in this fixed family with coordinate x correspond exactly to θ∈Θx from [L3].

2.1A1A3L3step 1.1∎

The minimum of V(θ) over those mixtures is therefore min⁡θ∈Θx∑iθiai=fmix(x) by [L3], with +∞ when Θx is empty. Every further conclusion in the Statement follows by applying the corresponding conclusion of [L3] to the same finite data. The point-mass and zero-coefficient cases are supplied by [L2]; the transfer remains conditional on [A1] and [A3] and records no independent acceptance of the draft representation.

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The two-point lever rule on a scalar interval

Statement

Let va,vb∈R with va<vb. A fraction λ∈[0,1] satisfies v=(1−λ)va+λvb exactly when v∈[va,vb] and

λ=v−vavb−va.

This fraction is unique. At v=va it is 0, and at v=vb it is 1; no admissible fraction gives a value outside the endpoint interval.

Facts & Assumptions

Given: Ordered real numbers va<vb, an interval point v∈R, and a mixing fraction λ∈[0,1].

[F1]

Complete ordered field (least-upper-bound property): R is an ordered field, so division by the positive number vb−va is valid and preserves inequalities.

[F2]

Intervals of R: the nine order-convex forms, nondegeneracy, and length: [0,1]={λ∈R:0≤λ≤1}.

Proof

technique · direct
1.1F1F2givenalgebra

From v=(1−λ)va+λvb one obtains v−va=λ(vb−va). Since vb−va>0 and 0≤λ≤1, this gives va≤v≤vb and forces λ=(v−va)/(vb−va).

2.1F1F2step 1.1algebra∎

Conversely, if va≤v≤vb, the quotient λ=(v−va)/(vb−va) lies in [0,1] and substitution gives v=(1−λ)va+λvb. The same forced quotient proves uniqueness and yields the two endpoint values.

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Concave supporting bound, affine maxima, and Hessian sign

Statement

Let U⊆Rd, d≥1, be open, and let f:U→R be differentiable. For x,y∈U, suppose the whole segment [x,y] lies in U and its concavity inequality holds:

f(x+t(y−x))≥(1−t)f(x)+tf(y)(0≤t≤1).

Then the supporting bound is f(y)≤f(x)+Df(x)(y−x). In particular this bound holds for every x,y in any convex subset of U on which f is concave. No global convexity of U is assumed.

Let A:Rd→Rk be linear, b∈Rk, and F=U∩{x:Ax=b}. Suppose x∗∈F, Df(x∗)h=0 for every h∈ker⁡A, and for every y∈F the segment [x∗,y] lies in U and has the displayed concavity inequality. Then x∗ is a global maximum of f on F. If F is convex and f∣F is strictly concave, meaning the inequality is strict for distinct endpoints and 0<t<1, the maximum is unique.

For the curvature clause, suppose f∈C2(U) and fix x∈U. If, for every h∈Rd, all sufficiently small ∣t∣ satisfy x±th∈U and

f(x+th)+f(x−th)≤2f(x),

then the Hessian bilinear form D2f(x)=D(Df)(x) satisfies D2f(x)[h,h]≤0 for every h. This condition holds whenever f is concave on a neighborhood of x. Thus a C2 function concave on an open convex region has negative-semidefinite Hessian there. Concavity alone does not assert strict curvature.

Facts & Assumptions

Given: The open domain, differentiability, and the stated admissible segments and concavity inequalities; affine constraints and stationarity for the maximum clause; strict concavity or C2 regularity only for their respective further clauses.

[F1]

A convex subset of Rm contains every line segment between two of its points: every segment between points of a convex set stays in that set.

[F2]

The total (Fréchet) derivative Df(a) as the linear first-order approximation with o(∥h∥2) remainder: f(x+h)=f(x)+Df(x)h+o(∥h∥) at each point of differentiability.

[F3]

If all partial derivatives exist on a neighbourhood and are continuous at a point, then the map is totally differentiable there with Jacobian derivative, The chain rule for total derivatives: D(g∘f)(a)=Dg(f(a))∘Df(a) and Ck Euclidean maps and diffeomorphisms: continuous first and second coordinate partials give total derivatives of f and its vector of first partials; thus a C2 function restricted to the line t↦x+th is C2, with second derivative D2f(x+th)[h,h].

Proof

1.1givenF1F2algebra

For an admissible pair x,y and 0<t<1, the given concavity inequality yields f(y)−f(x)≤(f(x+t(y−x))−f(x))/t. By [F2] the right side tends to Df(x)(y−x) as t↓0, proving the supporting bound. The convex-region specialization follows from [F1] and the concavity inequality on that region; it does not require any other segment of U to be admissible.

2.1givenF1step 1.1algebra

For y∈F, linearity gives A(y−x∗)=0, so stationarity yields Df(x∗)(y−x∗)=0. The assumed segment from x∗ to y permits step 1.1, hence f(y)≤f(x∗), proving global maximality. If F is convex and two distinct points maximize f, their midpoint lies in F by [F1], while strict concavity would give a strictly larger midpoint value. Thus the maximum is unique under the further hypothesis.

3.1givenF1F3F4algebra∎

Under the C2 and local midpoint hypotheses, fix h and put g(t)=f(x+th) near zero. By [F3], g′′(0)=D2f(x)[h,h]. Define R(t)=g(t)−g(0)−g′(0)t−12g′′(0)t2. Differentiability of g′ gives R′(s)=o(∣s∣); [F4] on the interval between 0 and t gives R(t)=tR′(ξt)=o(t2), since ∣ξt∣≤∣t∣. Therefore (g(t)+g(−t)−2g(0))/t2→g′′(0). Its numerator is nonpositive by hypothesis, so D2f(x)[h,h]≤0. Concavity on a neighborhood implies that midpoint hypothesis on every sufficiently short centered segment; this proves all Hessian claims without strengthening the domain assumptions.

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Second-order curvature tests on an affine feasible slice

Statement

Let d≥0 and k≥0 be integers, let U⊆Rd be open and convex, let A:Rd→Rk be linear, let b∈Rk, and let x∗∈U satisfy Ax∗=b. Put T=ker⁡A. Assume f:U→R is differentiable and has second directional derivatives represented by a continuous matrix field: there is a continuous map H:U→Rd×d with symmetric values, and for every x∈U and h∈Rd,

d2dt2f(x+th)∣t=0=Qx(h):=hTH(x)h.

Assume stationarity Df(x∗)h=0 for every h∈T. If Qx∗(h0)<0 for some h0∈T, then x∗ is not a local minimum of f on {x∈U:Ax=b}. If Qx∗(h)>0 for every nonzero h∈T, then x∗ is a strict local minimum on that feasible slice. If T={0}, the latter conclusion holds because x∗ is the only feasible point.

Facts & Assumptions

Given: The open convex domain, linear constraint, differentiable function, continuous symmetric matrix field, directional second-derivative identity, and stationarity in the Statement.

[F1]

A convex subset of Rm contains every line segment between two of its points: the segment between two points of a convex set stays in that set.

[L1]

The Euclidean inner product ⟨x,y⟩=∑k<nxkyk on Rn: the Euclidean norm is ∥h∥2=⟨h,h⟩.

Proof

technique · direct
1.1givenL1algebra

If d=0, then R0 has only its zero vector, U={x∗}, and T={0}. There is no negative-curvature direction and x∗ is the only feasible point, so the strict-minimum conclusion holds. In the remaining argument suppose d≥1. Suppose h0∈T and Qx∗(h0)<0. Set ϕ(t)=f(x∗+th0) for t near 0. Openness of U permits this definition; stationarity gives ϕ′(0)=0. The identity in the Statement gives ϕ′′(t)=Qx∗+th0(h0) wherever defined, and continuity of the entries of H makes this negative for every sufficiently small t≥0.

1.2L1L2L3L4given

Suppose T≠{0} and Qx∗(h)>0 for each nonzero h∈T. The unit sphere ST={h∈T:∥h∥2=1} is nonempty, closed by [L2] and continuity of the norm, and bounded; [L3] makes it compact. The quadratic polynomial h↦hTH(x∗)h is continuous, so [L4] gives λ=min⁡h∈STQx∗(h)>0.

2.1L5step 1.1algebra

Choose such a small t>0. Applying [L5] to ϕ′ on [0,t] gives ϕ′(t)−ϕ′(0)=tϕ′′(s)<0 for some s∈(0,t), hence ϕ′(t)<0; the same argument applies to every positive endpoint up to t. Applying [L5] to ϕ on [0,t] gives ϕ(t)−ϕ(0)=tϕ′(r)<0 for some r∈(0,t). Since h0∈ker⁡A, x∗+th0 is feasible, so x∗ is not a local minimum.

2.2F1L1step 1.2givenalgebra

By continuity of the finitely many entries of H, choose δ>0 so that ∥x−x∗∥2<δ implies ∣Qx(h)−Qx∗(h)∣<λ/2 for every unit vector h: expand the difference as a finite sum of entry differences times hihj, each with ∣hihj∣≤1. If y≠x∗ is feasible and ∥y−x∗∥2<δ, put v=y−x∗. Then v∈T, and convexity of U keeps x∗+tv in U for 0≤t≤1. For ϕ(t)=f(x∗+tv), stationarity gives ϕ′(0)=0, while homogeneity of the quadratic form gives ϕ′′(t)=Qx∗+tv(v)≥(λ/2)∥v∥22>0.

3.1L5step 2.2algebra∎

For any t∈(0,1], [L5] applied to ϕ′ on [0,t] yields ϕ′(t)−ϕ′(0)=tϕ′′(s)>0 for some s∈(0,t), so ϕ′(t)>0. Applying [L5] to ϕ on [0,1] gives ϕ(1)−ϕ(0)=ϕ′(r)>0 for some r∈(0,1). Thus every distinct feasible y with ∥y−x∗∥2<δ has f(y)>f(x∗). If T={0}, Ay=Ax∗ implies y−x∗∈T={0}, so x∗ is the only feasible point.

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The feasible tangent cone for nonnegative stoichiometric amounts

Statement

Let s,r≥1, let ν∈Rs×r be a stoichiometric matrix (column k gives the signed species-amount change per unit extent of reaction k), and let n0∈[0,∞)s be initial species amounts. Extents ξ∈Rr are measured in one fixed amount unit, so n(ξ)=n0+νξ has species amounts in that same unit; ν is dimensionless. The feasible extent set is the polyhedron

F={ξ∈Rr:n0+νξ∈[0,∞)s}.

At ξ∗∈F, let J={j:nj0+(νξ∗)j=0} be the active species set. Define the Bouligand tangent cone TF(ξ∗) to consist of all h∈Rr for which there are tk>0 with tk→0 and hk→h such that ξ∗+tkhk∈F. Then

TF(ξ∗)={h∈Rr:(νh)j≥0 for every j∈J}.

If U⊆Rr is open with ξ∗∈U, and f:U→R is differentiable with a local minimum at ξ∗ relative to F∩U, then Df(ξ∗)h≥0 for every h∈TF(ξ∗). Conversely, if U is convex and f is convex and differentiable on U, this directional inequality for every h∈TF(ξ∗) implies f(ξ)≥f(ξ∗) for every ξ∈F∩U. Suppose V⊆Rs is open, n∗:=n0+νξ∗∈V, Φ:V→R is totally differentiable at n∗, and f(ξ)=Φ(n0+νξ) near ξ∗. For each j, let ej∈Rs have coordinate 1 in position j and 0 in every other position; define μj:=DΦ(n∗)ej. Then

Df(ξ∗)h=∑j=1sμj(νh)j=(νTμ)⋅h.

The tangent-cone and optimality claims are mathematical deductions. They do not assert that a particular physical system obeys this model or is at equilibrium.

Facts & Assumptions

Given: The finite stoichiometric matrix, initial amounts, feasible extent set, Euclidean convergence, and differentiability/convexity hypotheses in the Statement.

[F1]

The total (Fréchet) derivative Df(a) as the linear first-order approximation with o(∥h∥2) remainder: differentiability at ξ∗ gives f(ξ∗+w)=f(ξ∗)+Df(ξ∗)w+o(∥w∥2) as w→0.

[F2]

A convex subset of Rm contains every line segment between two of its points: convexity of U and the affine inequalities defining F keep every segment between feasible points in F∩U.

[F3]

The chain rule for total derivatives: D(g∘f)(a)=Dg(f(a))∘Df(a): the derivative of a composition is the composition of its total derivatives.

[F4]

Convex and strictly convex functions on Euclidean convex sets: a real-valued function is convex when f((1−t)x+ty)≤(1−t)f(x)+tf(y) for points in its convex domain and t∈[0,1].

Proof

technique · direct
1.1F5givenalgebra

Suppose h∈TF(ξ∗), and choose sequences tk,hk from its definition. For each active j∈J, feasibility gives 0+tk(νhk)j≥0, hence (νhk)j≥0. Since [F5] makes the finite matrix map continuous, hk→h implies νhk→νh, so (νh)j≥0. This proves one inclusion.

1.2givenchoosealgebra

Conversely suppose (νh)j≥0 for all j∈J. For each inactive j, put bj=nj0+(νξ∗)j>0. If (νh)j<0, restrict 0≤t≤bj/[−(νh)j]; if (νh)j≥0, no restriction is needed. There are finitely many species, so choose a common ϵ>0 no larger than all positive bounds (or ϵ=1 if there are none). For j∈J, nj0+(ν(ξ∗+th))j=t(νh)j≥0; for inactive j, the choice of ϵ gives bj+t(νh)j≥0 for 0≤t≤ϵ. Thus ξ∗+th∈F throughout that interval. Taking hk=h and any positive tk≤ϵ tending to zero proves h∈TF(ξ∗).

2.1F1step 1.1step 1.2given

By steps 1.1–1.2, every tangent h has a feasible ray ξ∗+th for all sufficiently small t≥0. Openness of U keeps the initial part of this ray in U. At a relative local minimum, [f(ξ∗+th)−f(ξ∗)]/t≥0 for all sufficiently small t>0; differentiability [F1] makes its limit Df(ξ∗)h. Hence Df(ξ∗)h≥0.

2.2F1F2F4step 1.2givenalgebra

Now assume U is convex and f convex and differentiable. For any ξ∈F∩U, put h=ξ−ξ∗. For active j, (νh)j=nj(ξ)−nj(ξ∗)=nj(ξ)≥0, so step 1.2 makes h a tangent direction; the segment ξ∗+th also lies in F∩U by [F2]. Let g(t)=f(ξ∗+th). [F4] gives (g(t)−g(0))/t≤g(1)−g(0) for 0<t<1; as t↓0, the left side tends to Df(ξ∗)h by [F1]. If every tangent derivative is nonnegative, then f(ξ)−f(ξ∗)=g(1)−g(0)≥Df(ξ∗)h≥0.

3.1F3givenalgebra∎

The affine map ξ↦n0+νξ has derivative h↦νh. By [F3], Df(ξ∗)h=DΦ(n∗)(νh). Since νh=∑j=1s(νh)jej and DΦ(n∗) is linear, this equals ∑j=1s(νh)jDΦ(n∗)ej=∑j=1sμj(νh)j=(νTμ)⋅h, as claimed.

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Local graph form at a nonsingular derivative minor

Statement

Let 1≤q≤n, let U⊆Rn be open, and let F:U→Rq be C1 in the sense of Continuously differentiable maps, local inverses, and local diffeomorphisms. Suppose F(x∗)=0 and some q×q minor of the derivative matrix DF(x∗) is invertible. This nonsingular-minor hypothesis is the explicit full-row-rank condition used here. If q<n, then after permuting coordinates x=(u,v)∈Rn−q×Rq, there are open neighborhoods P of u∗ and Q of v∗ and a unique C1 map φ:P→Q such that

F(u,v)=0⟺v=φ(u)((u,v)∈P×Q).

Its derivative is

Dφ(u)=−DvF(u,φ(u))−1DuF(u,φ(u)).

Thus the local zero set is a graph over n−q free coordinates. If q=n, the zero is locally isolated, so the local graph dimension is zero. Here “local graph dimension k” means a local graph parameterized by an open subset of Rk, with a singleton counted as dimension zero.

Facts & Assumptions

Given: The open domain, C1 map, zero, dimensions, and invertible derivative minor in the Statement.

[F1]

Continuously differentiable maps, local inverses, and local diffeomorphisms: a map is C1 when it is totally differentiable everywhere and the entries of its derivative matrix are continuous.

[F2]

Invertible Euclidean linear maps: a square linear map is invertible when it has a two-sided linear inverse.

[L1]

The Euclidean implicit function theorem with derivative formula: for an open set W⊆Rm+q and a C1 map G:W→Rq with m,q≥1, (a,b)∈W, G(a,b)=0, and invertible second-block derivative DyG(a,b), there are open neighborhoods P,Q and a unique C1 map φ:P→Q with G(u,v)=0 exactly when v=φ(u) on P×Q. After shrinking these neighborhoods, DyG(u,φ(u)) is invertible and Dφ(u)=−DyG(u,φ(u))−1DxG(u,φ(u)).

[L2]

The Euclidean inverse function theorem: a C1 map between open subsets of Rn with invertible derivative at a point is a local C1 bijection with a C1 inverse.

[L3]

Every Euclidean linear map has a unique matrix and satisfies ∥Lh∥2≤K∥h∥2 for some K≥0: linear maps between Euclidean spaces have coordinate matrices and are bounded, hence continuous; a coordinate permutation is an invertible linear map.

[L4]

The chain rule for total derivatives: D(g∘f)(a)=Dg(f(a))∘Df(a): composing a C1 map with a linear coordinate permutation preserves total differentiability and the derivative formula; [L3] and The metric topology: a set is open when every one of its points has a ball around it inside the set; closed means open complement make that permutation a homeomorphism, so it preserves open domains.

Proof

technique · reduction
1.1F1F2L1L3L4givenconstruct

First suppose q<n. Choose the coordinate permutation that puts the columns of the stated invertible minor into the second block v∈Rq, and write the remaining coordinates as u∈Rn−q. Composing F with the inverse permutation preserves openness and the C1 property by [F1], [L3], and [L4]; its second-block derivative at (u∗,v∗) is exactly the chosen invertible minor in the sense of [F2]. Since n−q≥1 and q≥1, [L1] applies and gives the neighborhoods, unique graph φ, equivalence, and displayed derivative formula.

2.1step 1.1algebra

The graph map u↦(u,φ(u)) is one-to-one because its first coordinate is u, and its inverse on the graph is coordinate projection. Its parameter domain P is open in Rn−q, so this is the claimed local graph dimension.

3.1F2L2givenalgebra∎

Now suppose q=n. The selected minor is the whole square derivative matrix DF(x∗), so it is invertible by [F2]. Apply [L2] on neighborhoods V of x∗ and W of 0. Injectivity of F∣V and F(x∗)=0 imply F(x)=0 for x∈V exactly when x=x∗. Thus the local zero set is a singleton and has the stated zero-dimensional graph form.

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Regular rank form of the finite-component phase dimension count

Statement

Let C≥1 be the number of components and P≥1 the number of phases. Use common positive real coordinates T,p, expressed in fixed units if they are given a physical interpretation, and, for each phase α, an interior composition vector

xα∈ΩC:={x∈RC−1:xi>0, ∑i=1C−1xi<1},

with the convention R0={0} and Ω1={0}. The final component fraction is 1−∑i<Cxi>0. The ambient coordinate domain U=(0,∞)2×ΩCP is open in Rn, where n=2+P(C−1). For each phase α and component i, let μiα(T,p,xα) be a real-valued C1 coordinate function; these are mathematical maps and no thermodynamic potential or physical realization is assumed.

For P≥2, define the q=C(P−1) coexistence equations

Fi,α(T,p,x1,…,xP)=μiα(T,p,xα)−μi1(T,p,x1)=0(1≤i≤C, 2≤α≤P).

At a solution z∗∈U, assume some q×q derivative minor of F:U→Rq is invertible. Then the local solution set is a graph of dimension

n−q=2+P(C−1)−C(P−1)=C−P+2.

For P=1 there are no coexistence equations and the coordinate domain itself has dimension n=C+1=C−P+2. In a specified reactive variant with R≥1, let ν1,…,νR∈RC be linearly independent dimensionless stoichiometric vectors and add the R affinity equations Ar=∑i=1Cνirμi1=0. If the combined equation map has an invertible (q+R)×(q+R) derivative minor at a solution and q+R≤n, its local zero set has dimension

n−q−R=C−P+2−R.

These are conditional local dimensions under the displayed nonsingular-minor assumptions. No dimension formula follows at singular solutions, on composition boundaries, or from equation counting alone; no empirical or general physical phase rule is asserted.

Facts & Assumptions

Given: The finite integers, open coordinate domain, C1 chemical-potential coordinate functions, coexistence equations, and nonsingular-minor assumptions in the Statement.

[F1]

Continuously differentiable maps, local inverses, and local diffeomorphisms: C1 means total differentiability with continuous derivative-matrix entries.

[L1]

Local graph form at a nonsingular derivative minor: for an open V⊆Rn, a C1 map H:V→Rk, 1≤k≤n, and a zero z∗∈V with an invertible k×k derivative minor, the local zero set is a C1 graph over n−k coordinates when k<n, and an isolated point when k=n.

[L2]

Sums and scalar multiples of totally differentiable maps are totally differentiable with the expected derivatives: if f,g are totally differentiable at z and c∈R, then f+g and cf are totally differentiable there, with D(f+g)(z)=Df(z)+Dg(z) and D(cf)(z)=cDf(z). Repeated application gives the derivative of every finite linear combination; continuity of its derivative entries must also be checked to establish C1 regularity.

Proof

technique · direct
1.1F1L1L2givenalgebraconstruct

For each phase let πα:U→(0,∞)2×ΩC select (T,p,xα), and write μ~iα=μiα∘πα. The same coordinate selection on increments is linear and satisfies ∥παh∥2≤∥h∥2. Substituting παh into the first-order expansion of μiα gives derivative Dμ~iα(z)=Dμiα(παz)πα and remainder o(∥h∥2), with zero remainder when παh=0. Its derivative entries are selected entries of Dμiα(παz) or zero; they are continuous because πα does not increase distances and the original entries are continuous. For P≥2, F has q=C(P−1) scalar components, each a difference of these lifted maps. By [L2] their derivative rows are Dμ~iα−Dμ~i1; the entries are continuous since the increment of each difference is bounded by the sum of the two entry increments. The finitely many scalar remainders assemble to a vector remainder o(∥h∥2), since its norm is at most q times their largest absolute value. Thus F is C1 by [F1]. The assumed q×q minor entails 1≤q≤n, so [L1] gives local graph dimension n−q=2+P(C−1)−C(P−1)=C−P+2, including an isolated point if q=n.

1.2givenalgebra

If P=1, no phase-equality equations are indexed because there is no α≥2. The local solution set is all of the open domain U, which has n=2+(C−1)=C+1=C−P+2 coordinates.

2.1step 1.1F1L1L2givenalgebra∎

In the reactive variant put q=0 if P=1. The lifted maps constructed in step 1.1 are C1 for every P≥1. By [L2], DAr(z)=∑i=1CνirDμ~i1(z). For each derivative entry, its increment is bounded by the finite sum of ∣νir∣ times the corresponding continuous entry increments, which tends to zero. Thus the affinity derivative entries are continuous. As in step 1.1, the finitely many scalar remainders assemble to a vector remainder o(∥h∥2), so the combined map is C1 by [F1] and has q+R scalar equations. Since 1≤q+R≤n, its stated minor lets [L1] give graph dimension n−q−R=C−P+2−R, with an isolated point if q+R=n. Linear independence of the νr identifies R distinct reaction directions, while the nonsingular derivative minor remains a separate assumption.

5 · Examples, experiments and counterexamples

None yet.

Sources