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Isotropic Lamb shift preserves magnetic degeneracy

PDF p. 11: Opening continuation of S2

Statement

Assume the Axiom of Choice, Countable Choice and Dependent Choice. Use the finite-emitter angular-momentum and regulated photon model of Angular-momentum emitter, photon bath, and dipole approximation, with the isotropic thermal bath and continuum-limit hypotheses of Off-diagonal correlators vanish in an isotropic photon bath. Also impose all system, bath, preparation, weak-Markov, Fourier-integrability and principal-value hypotheses of Static ULE formulas and principal-value kernel, with three Cartesian channels and a common coupling normalization. In particular, use a pointwise nonnegative scalar spectral-density representative at every frequency required by that ULE formula.

Let the emitter space be a finite direct sum of complete spin blocks, and let Uk(t)=exp⁡(−itJk) be its axis rotations, as in Rotational scalars on multiplicity-resolved spin blocks. Suppose HS commutes with these rotations and the three Hermitian system coupling operators Xi transform as a Cartesian vector: for each axis rotation U there is a real orthogonal matrix R such that UXiU−1=∑jRjiXj. Assume the resulting ULE Lamb-shift operator Λ is Hermitian.

Then Λ commutes with every axis rotation. On the sum of copies of spin J, it has the form A(J)⊗I2J+1, where A(J) acts on the copy labels. In the article's multiplicity-one model this reduces to Λ∣VJ=λJI, with real λJ, so it does not split the magnetic labels m. Adding it to HS replaces ηJ by ηJ+λJ/ω0; the shifted level factors need not remain monotone.

Facts & Assumptions

[F1]

Under its stated hypotheses, the static ULE supplier gives Λ=∑l,m,n,i,jfij(El−Em,En−El)Xml(i)Xln(j)∣m⟩⟨n∣, with f(E1,E2)=−2πγPV⁡∫−∞∞ω−1g(ω−E1)g(ω+E2) dω and g=[J/(2π)]1/2. Static ULE formulas and principal-value kernel

[F2]

The atomic model has complete angular-momentum blocks and HS=∑J,mω0ηJ∣J,m⟩⟨J,m∣, with one specified block for each J and ω0>0. The dipole interaction is a model assumption. Angular-momentum emitter, photon bath, and dipole approximation

[F3]

Under the regulated isotropic thermal-bath hypotheses, the Cartesian spectral matrix has an almost-everywhere scalar representative; for a chosen nonnegative representative its positive jump kernel is g(x)=s(x)I3, where s(x)=J(x)/(2π). The additional ULE regularity and pointwise conditions are separately assumed. Off-diagonal correlators vanish in an isotropic photon bath

[F4]

A contraction ∑iDiFDi commutes with all axis rotations when the Di transform as a Cartesian vector and F commutes with those rotations. An operator commuting with the rotations has a unique matrix on each spin-copy space tensored with the identity on the magnetic space. Rotational scalars on multiplicity-resolved spin blocks

[A1]

Proof

Given: The model, covariance, Hermiticity, choice and ULE regularity hypotheses in the Statement.

Goal: Prove rotational invariance of the Lamb shift and its stated action on magnetic labels.

1.1givenF1F3

By [F3], g(x)=s(x)I3 at the frequencies used in [F1]. Matrix multiplication in the kernel therefore gives fij(a,b)=δijh(a,b), where h(a,b)=−2πγPV⁡∫ω−1s(ω−a)s(ω+b) dω. The assumed principal values make these expressions meaningful.

2.1givenF1step 1.1algebra

Let PE denote the orthogonal projection onto the eigenspace of HS with eigenvalue E. Grouping the finite sums in [F1] by the three energy eigenvalues and applying step 1.1 yields Λ=∑E,E′,Fh(F−E,E′−F)PE(∑iXiPFXi)PE′. Because HS commutes with each rotation, the rotation maps every eigenspace of HS to itself; its inverse does so as well. Hence each PE commutes with each rotation.

3.1givenF4step 2.1

The assumed vector transformation of Xi, the commutation of PF, and [F4] show that each ∑iXiPFXi commutes with every axis rotation. The projections on its left and right commute with those rotations too, so the finite sum in step 2.1 commutes with them.

4.1givenF2F4step 3.1algebra∎

Apply the block conclusion of [F4] to Λ. It has the form A(J)⊗I2J+1 on each spin sector, with no coupling between different spins. In the multiplicity-one model of [F2], A(J) is a scalar λJ; its reality follows from the assumed Hermiticity of Λ. Adding λJ to the common unperturbed energy ω0ηJ gives the displayed shifted level factor and leaves all magnetic states in that block degenerate. No ordering of shifted energies follows.

Source notes

The article attributes the scalar-block conclusion to Wigner–Eckart. The local argument instead uses the completed rotational-scalar block supplier and the static ULE formula. Isotropy of the bath alone does not establish the separately stated covariance of the matter coupling or rotational invariance of HS.

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