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First-order transition amplitudes for a bounded control: Dyson remainder, the sinusoidal drive with its co- and counter-rotating parts, and the outcome-probability error

Physical scope

First-order transition amplitudes and their error in the bounded-control driven model: the exact amplitude in an orthonormal family of H0 eigenvectors, its first-order term with the explicit Dyson remainder bound, the closed evaluation for a sinusoidal control split into co-rotating and counter-rotating parts with their bounds, the linear growth at resonance, and the resulting bound on the outcome probability. The theorem is conditional on a bounded self-adjoint control and an orthonormal eigenfamily of H0; it asserts no long-time limit, no Fermi golden rule, no continuum density of states, no transition rate, no decay and no empirical result.

Statement

Adopt the framework data and the declared driven model of The declared driven model: prescribed time-dependent energy families, propagator evolution and the two-level drive models in the bounded-control class of clause (b)(ii): H is the model's state space, H0 is self-adjoint on D(H0), V:I→B(H) is strongly continuous with self-adjoint values, v=sup⁡t∈I∥V(t)∥<∞ and H(t)=H0+V(t); let U(t,s) be the mild propagator and put K:=v/ℏ. Let (φj)j∈J be an orthonormal family in D(H0) with H0φj=Ejφj (Orthonormal families, complete orthonormal systems and Hilbert bases) — a complete family is not required — and fix labels i,j∈J and s≤t in I, with τ:=t−s and Δ:=Ej−Ei. Let Aji(t,s)=eiEjτ/ℏ⟨U(t,s)φi,φj⟩ be the transition amplitude of clause (e) of the model and define its first-order term Aji(1)(t,s):=−iℏ∫steiΔ(r−s)/ℏ⟨V(r)φi,φj⟩ dr. Assume the Axiom of Countable Choice and the Axiom of Choice (The Axiom of Countable Choice (ACω), The Axiom of Choice). Then:

(a) Exact amplitude with Dyson remainder. There is a remainder Rji(t,s) with Aji(t,s)=δij+Aji(1)(t,s)+Rji(t,s),∣Rji(t,s)∣≤eKτ(Kτ)22, and if η:I→[0,∞) is measurable and integrable, ∥V(r)−V0(r)∥≤η(r) for r∈I, and V0:I→B(H) has self-adjoint values with integrable scalar coefficient r↦⟨V0(r)φi,φj⟩, then the corresponding first-order amplitude differs from Aji(1) by at most 1ℏ∫stη(r) dr.

(b) Sinusoidal control. Let W∈B(H) be self-adjoint, ω,ϑ∈R, and suppose V(r)=Wcos⁡(ωr+ϑ) for r∈I. Put ϑ0:=ωs+ϑ and decompose Aji(1)=a++a−,a±:=−i2ℏ⟨Wφi,φj⟩e∓iϑ0 ei(Δ∓ℏω)τ/ℏ−1i(Δ∓ℏω)/ℏ, with the convention that the quotient is the limit τ when Δ∓ℏω=0. Then the co-rotating term a+ (the one whose denominator vanishes at Δ=ℏω) satisfies ∣a+∣=∣⟨Wφi,φj⟩∣ ∣sin⁡((Δ−ℏω)τ/(2ℏ))∣∣Δ−ℏω∣,and at Δ=ℏω:∣a+∣=∣⟨Wφi,φj⟩∣τ2ℏ, and the counter-rotating term satisfies ∣a−∣≤∣⟨Wφi,φj⟩∣/∣Δ+ℏω∣ whenever Δ+ℏω≠0.

(c) Outcome probability. The model's transition probability is pji(t,s)=∣Aji(t,s)∣2; with ε:=eKτ(Kτ)2/2 and A(1):=Aji(1), for distinct labels i≠j ∣pji(t,s)−∣A(1)∣2∣≤2∣A(1)∣ ε+ε2, and for i=j the survival probability obeys the analogous bound ∣pii(t,s)−∣1+A(1)∣2∣≤(2+2∣A(1)∣)ε+ε2; in both cases the exact outcome probability is controlled by the first-order term and the explicit Dyson error of clause (a).

(d) Scope. The statements are finite-time and conditional on the bounded control and on the orthonormal eigenfamily; the remainder bound grows like τ2eKτ and no long-time limit, transition rate, exponential decay, continuum density of states or Fermi golden rule is asserted, and no measured frequency, count or rate is claimed.

Facts & Assumptions

Given: the declared driven model in the bounded-control class; the orthonormal eigenfamily (φj) with H0φj=Ejφj; labels i,j, times s≤t, τ=t−s, Δ=Ej−Ei, K=v/ℏ; where clause (b) applies, W,ω,ϑ with V(r)=Wcos⁡(ωr+ϑ); the Axiom of Countable Choice and the Axiom of Choice.

[F1]

Amplitude supplier. Under the hypotheses of the Statement, with (φn) a complete orthonormal family of H0-eigenvectors and Ab0a0(t,s) as defined in clause (e) of The declared driven model: prescribed time-dependent energy families, propagator evolution and the two-level drive models, one has Ab0a0=δa0b0−iℏ∫stei(Eb0−Ea0)(r−s)/ℏ⟨V(r)φa0,φb0⟩dr+Rb0a0 with ∣Rb0a0∣≤eKτ(Kτ)2/2; for the optional comparison, if η is measurable, nonnegative and integrable, ∥V(r)−V0(r)∥≤η(r), and the selected scalar coefficient r↦⟨V0(r)φa0,φb0⟩ is measurable, the amplitude computed with V0 differs from the exact one by at most 1ℏ∫stη(r)dr+eKτ(Kτ)2/2 (First-order amplitude tail). The proof of that item uses only the two fixed basis vectors, so the completeness of the eigenfamily is not needed for the displayed conclusion on the pair (i,j).

[F2]

Model and picture readings. The model defines the amplitude Aji=eiEjτ/ℏ⟨U(t,s)φi,φj⟩ and the probability pji=∣Aji∣2, with the reading of the outcome law of the energy observable in clause (e) (The declared driven model: prescribed time-dependent energy families, propagator evolution and the two-level drive models clauses (c)(ii), (e)); the physical propagator is the mild propagator of the bounded-control class (The bounded-control driven model: mild propagator, interaction-picture evolution and equivalence of the two readings clauses (a), (b); Strong bounded interaction picture; The interaction picture of the declared driven model: readings, the interaction propagator and picture equivalence of outcome laws clause (e)).

[F3]

Proof

technique · direct; instantiate the supplier's amplitude expansion, evaluate the sinusoidal integral by the exponential form of the cosine, and estimate the probability difference by the difference of the amplitudes

Given: the data of the Statement and [F1]-[F3].

1.1F1F2F3givenalgebra

[Exact pair amplitude without completeness] The interaction-picture supplier in [F2] gives U=E(t)UIE(−s) and UI=I+D1+T2 with D1ξ=−(i/ℏ)∫stVI(r)ξ dr and ∥T2∥≤eKτ(Kτ)2/2. For the two specified eigenvectors, ⟨E(t)x,φj⟩=e−iEjt/ℏ⟨x,φj⟩ and E(−s)φi=eiEis/ℏφi, so the correct model amplitude is Aji=ei(Ei−Ej)s/ℏ⟨UIφi,φj⟩. Its zeroth term is δij. Also ⟨VI(r)φi,φj⟩=ei(Ej−Ei)r/ℏ⟨V(r)φi,φj⟩. Passing this continuous bounded linear pairing through the vector integral gives exactly Aji(1) and Rji=ei(Ei−Ej)s/ℏ⟨T2φi,φj⟩, with the advertised remainder by [F3]. Only the fixed pair was used; a complete eigenfamily is unnecessary. For the selected integrable coefficient of V0, subtracting the two first-order scalar integrals and using ∣⟨(V−V0)φi,φj⟩∣≤η proves the stated ℏ−1∫stη bound. This proves (a), including free, zero-time and diagonal cases.

1.2F1F3algebra

[Sinusoidal evaluation] With V(r)=Wcos⁡(ωr+ϑ) and u:=r−s, ωr+ϑ=ωu+ϑ0, so cos⁡(ωr+ϑ)=12(ei(ωu+ϑ0)+e−i(ωu+ϑ0)) and Aji(1)=−i2ℏ⟨Wφi,φj⟩[eiϑ0∫0τei(Δ+ℏω)u/ℏdu+e−iϑ0∫0τei(Δ−ℏω)u/ℏdu], the two integrals being τ when their frequency vanishes and (eiθτ/ℏ−1)/(iθ/ℏ) otherwise; this is the displayed decomposition with a± and the stated convention. For a+, ∣eiθτ/ℏ−1∣=2∣sin⁡(θτ/(2ℏ))∣ and the modulus of the quotient by iθ/ℏ is 2ℏ∣sin⁡(θτ/(2ℏ))∣/∣θ∣ for θ=Δ−ℏω≠0, giving ∣a+∣=∣⟨Wφi,φj⟩∣∣sin⁡((Δ−ℏω)τ/(2ℏ))∣/∣Δ−ℏω∣; at Δ=ℏω the quotient is τ and the same modulus formula gives the limit ∣⟨Wφi,φj⟩∣τ/(2ℏ). For a− the same computation gives ∣a−∣=∣⟨Wφi,φj⟩∣∣sin⁡((Δ+ℏω)τ/(2ℏ))∣/∣Δ+ℏω∣≤∣⟨Wφi,φj⟩∣/∣Δ+ℏω∣. This is clause (b).

2.1step 1.1F2F3algebra

[Probability error for transition and survival] By [F2], pji=∣Aji∣2, and step 1.1 gives Aji=bji+R, where bji=δij+A(1) and ∣R∣≤ε. The identity ∣b+R∣2−∣b∣2=2Re⁡(Rb‾)+∣R∣2 therefore gives ∣pji−∣bji∣2∣≤2∣bji∣ε+ε2. For i≠j, bji=A(1), giving the displayed transition bound; for i=j, bii=1+A(1) and ∣bii∣≤1+∣A(1)∣, giving the displayed survival bound. No diagonal term is dropped. This proves (c).

3.1step 1.1step 1.2step 2.1given∎

[Scope] Only the bounded control, the fixed eigenpair, finite times and the choice hypotheses entered; the remainder grows like eKττ2 and no infinite-time limit, density of states, rate or decay was formed, which is clause (d).

Remarks

  • Resonance versus Rabi oscillation. Clause (b) shows that the first-order co-rotating amplitude grows linearly in τ at exact resonance. That linear growth is the small-coupling, short-time first-order behaviour of the general bounded-control model; the exact bounded oscillation of the two-level circular drive is proved separately on this page for the declared finite model, and the two statements have different hypotheses: the first applies to any bounded control with an orthonormal eigenpair, the second is exact for the declared two-level family.
  • What "first order" controls. The bound of clause (a) is uniform in the labels and in the family; it is a bound on the amplitude, not a rate, and the counter-rotating bound of clause (b) shows explicitly how far the physical first-order term is from its co-rotating part.

Depends on

Dependency tree · 2 levels

Sources