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Attained entropy-maximizing mixtures on compact phase domains
Mixtures of a compact set of declared phase-generator states with continuous entropy and a fixed barycenter; every feasible Borel probability mixture is included, while no attainment claim is made for noncompact domains or a different physical normalization.
Statement
Let and let be a nonempty compact set of dimensionless generator coordinates. Each labels one model-specified phase-generator state; the model assigns it entropy per mole , and is continuous, using the numerical entropy value in that fixed unit. Define to be the set of all finite convex combinations of points of , and fix . Use the Borel sigma algebra relative to . A Borel probability mixture is a countably additive probability measure on that sigma algebra; its barycenter and entropy per mole are the coordinatewise integrals and . For , define the unit point mass by if and otherwise, for Borel . Assume every Borel probability mixture with barycenter is feasible and has entropy per mole . Then there are , points , and weights with such that is a feasible Borel probability mixture and for every feasible mixture .
Here integrals use the measure convention of Measure space and integral. The entropy map is part of the model; this theorem derives neither its microscopic meaning nor compactness of a physical phase domain.
Facts & Assumptions
Given: The nonempty compact set , , continuous entropy map , prescribed , coordinatewise integral convention, and feasibility of every Borel probability mixture with that barycenter. The normalization is per mole and no system-size limit is taken.
Phase branches and coexistence domains: A generator point is a model-specified state label; the theorem's mixture feasibility is an additional model assumption and does not assert that every phase collection is physically available.
Concave macroscopic fundamental entropy: Entropy is a finite state function on the declared physical states. Continuity of on this compact is the explicit regularity hypothesis here.
The Borel sigma-algebra of a topological space and Probability measures and probability spaces: The Borel sigma algebra is generated by the relatively open subsets of , and each probability measure has total mass one.
Measure space and integral and The thermodynamics measure integral agrees with the shared nonnegative integral: The local nonnegative integral is the supremum of simple-function integrals and agrees with the shared nonnegative Lebesgue integral. Since both signed-integral conventions use the difference of the positive and negative part integrals, they agree on bounded real functions as well.
Integrable real and complex functions, and their integrals, The Lebesgue integral is linear on , Monotonicity and nonnegative homogeneity of the nonnegative integral, and The modulus of an integral is bounded by the integral of the modulus: Bounded Borel real functions are integrable under a finite probability measure; their integrals are linear, order-preserving, and satisfy .
A continuous real-valued function on a nonempty compact metric space is bounded and attains a greatest and a least value: A continuous real function on a nonempty compact metric space is bounded and attains its minimum and maximum.
The image of a compact metric space under a continuous map is compact, and so is the image of any compact subset, A compact subset of a metric space is closed and bounded, and Heine-Borel in : with the Euclidean metric a subset of is compact if and only if it is closed and bounded, and the proof by bisection uses no choice principle; the same holds on the real line: Continuous images of compact metric spaces are compact; compact Euclidean subsets are closed and bounded; closed bounded subsets of finite-dimensional Euclidean spaces are compact.
Rank-nullity: : For a linear map between finite-dimensional vector spaces, domain dimension equals kernel dimension plus image dimension.
Proof
Given: The data in [A1]–[A2] and [F1]–[F3]. Write for the continuous map , and let and , where convex hull means finite convex combinations.
The map is continuous, so [L2] makes compact. For every Borel probability on , each coordinate of is bounded and Borel. Compactness and [L1] give boundedness. If for one such coordinate, [F3] gives , so is integrable.
Every point of is a finite convex combination of points . If such a representation has , the linear map defined by has a nonzero kernel vector by [L3], because the coordinate bases give domain dimension and codomain dimension . Thus and , so has both positive and negative coordinates. After dropping zero weights from the representation, set and replace each weight by . The new weights remain nonnegative, still sum to one, represent the same point, and at least one is zero. Repeating reduces every combination to at most terms. Hence is the image of under , where ; shorter combinations are padded with zero weights and any fixed point of nonempty . Each factor is closed and bounded by [L2], and is closed by continuity of the finite coordinate sum and its coordinate inequalities; it is bounded since . Their product is therefore closed and bounded in , so compact by [L2]. To check is continuous on this compact parameter set, fix a parameter . Each coordinate is bounded by some on and is continuous at each of the finitely many . For any , choose neighborhoods of the making for every output coordinate , and require . Since and , each product difference ; summing over makes each output-coordinate difference smaller than . Thus is continuous. The continuous-image clause of [L2] makes its image compact, and [L2] also makes closed.
Fix any Borel probability on and let , with coordinatewise integration. For , compactness of gives a finite cover of by open Euclidean balls of radius . Their preimages under are Borel; disjointifying them in a fixed finite order gives a finite Borel partition of . For every nonempty part choose and put . Then belongs to . For , both and lie in the same radius- ball, so each coordinate difference is at most . The simple map equal to on has integral by the simple-integral definition. By linearity and the integral triangle inequality in [F3], each coordinate of has absolute value at most . Consequently , so the sequence obtained with converges to . Since is closed by step 2.1, .
Because , a finite convex combination of generators has barycenter ; its corresponding combination of points shows that is nonempty. The set is bounded because is bounded, and it is closed because is closed and is continuous. By [L2] it is compact in , so [L1] applied to the identity function yields a maximum .
Represent by a finite convex combination , dropping zero weights. If , the linear map given by has a nonzero kernel vector by [L3], since its domain dimension is and its codomain dimension is . Hence and , with both signs among the . If , choose the sign of so that this sum is positive. For sufficiently small , the weights are nonnegative, preserve total mass and barycenter, and increase the last coordinate above , contradicting maximality in step 3.2. Thus . Now take and replace by . This removes at least one positive weight while preserving total mass, barycenter, and entropy value . Repeating finitely many times leaves at most positive weights.
Let be the probability measure from step 4.1. Each is countably additive because among disjoint Borel sets at most one contains , and ; hence is a Borel probability measure. It has barycenter and entropy , so it is feasible by the model assumption. For any other feasible Borel probability , step 3.1 gives , so . Thus attains the entropy maximum among all Borel mixtures and has at most atoms. No finite generator menu was assumed.
Remarks
The proof treats every feasible Borel probability mixture, not just finite mixtures. It proves that the vector of integrated generator coordinates and entropy lies in a compact finite-dimensional convex hull, then uses maximality at the prescribed barycenter to reduce the support to . It does not establish that a physical system has a compact generator domain or that every mathematical mixture is physically feasible; those remain explicit model hypotheses.
Depends on
Phase branches and coexistence domains
Concave macroscopic fundamental entropy
The Borel sigma-algebra of a topological space
Probability measures and probability spaces
Measure space and integral
The thermodynamics measure integral agrees with the shared nonnegative integral
Integrable real and complex functions, and their integrals
The Lebesgue integral is linear on
Monotonicity and nonnegative homogeneity of the nonnegative integral
The modulus of an integral is bounded by the integral of the modulus
A continuous real-valued function on a nonempty compact metric space is bounded and attains a greatest and a least value
The image of a compact metric space under a continuous map is compact, and so is the image of any compact subset
A compact subset of a metric space is closed and bounded
Heine-Borel in : with the Euclidean metric a subset of is compact if and only if it is closed and bounded, and the proof by bisection uses no choice principle; the same holds on the real line
Rank-nullity: