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The two spin-half fermion sector: the spin-singlet and spin-triplet parts and their orbital symmetry
The conditional model computation for two declared spin-half fermions with a finite orbital factor: the decomposition of the antisymmetric sector into spin-singlet and spin-triplet parts, the opposite orbital symmetry in each part, and the explicit components of an antisymmetrised product of two declared one-particle states. The computation is conditional on the adopted antisymmetric sector of P6 and on the declared finite orbital factor; it asserts no spin-statistics theorem, no interaction, no dynamics, no measurement and no empirical claim.
Statement
Adopt the state and composition postulate P1 (State and composition postulate P1: Hilbert spaces, preparations and composite systems) and the identical-particle and spin postulate P6 (Identical-particle and spin assignments P6: permutation sectors and finite-spin representations) in the readings of Declared species sectors and their preparations: the framework's reading of P6, and assume the Axiom of Countable Choice (The Axiom of Countable Choice ()). Declare a spin-half fermionic species with an arbitrary model-assigned mass parameter , unused in this calculation and not assigned an empirical value here, whose one-particle space is the completed product of a nonzero finite-dimensional complex Hilbert space (the orbital factor) with (the internal factor of P6 clause (ii) for ), with carrying the orthonormal basis of Composition of two spin labels: total spin operators, the Clebsch-Gordan block decomposition and the spin-half singlet, and declare particles in the adopted antisymmetric sector of the declared species, with the regrouping unitary of Regrouping two factors: the symmetry decomposition of a two-particle sector over an orbital and an internal factor. Write and for , and for the spin combinations. Then, as conditional statements of the declared model:
(a) sector decomposition: carries onto the orthogonal direct sum , where is the one-dimensional spin-singlet line spanned by the singlet of Composition of two spin labels: total spin operators, the Clebsch-Gordan block decomposition and the spin-half singlet clause (d) and is the three-dimensional spin-triplet space of that theorem; consequently the antisymmetric two-particle sector is the sum of a spin-singlet part , of dimension for , with symmetric orbital factor, and a spin-triplet part , of dimension , with antisymmetric orbital factor;
(b) opposite orbital symmetry: for all and , the spin-singlet component therefore multiplies the symmetric orbital component and the spin-triplet component multiplies the antisymmetric orbital component, so within each component the orbital exchange symmetry is opposite to the spin exchange symmetry;
(c) parallel spins: if are orthonormal and is a unit vector, then carries the ray of to the ray of , whose unit representative is ; for this is the triplet component with an antisymmetric orbital factor;
(d) antiparallel spins: if are orthonormal, then carries the ray of to the ray of , an equal-amplitude superposition of the singlet component with symmetric orbital factor and the triplet component with antisymmetric orbital factor; in particular such an antisymmetrised product of two orthonormal one-particle states has no definite orbital exchange symmetry.
The model assignment of the antisymmetric sector is that of P6; the statements above are conditional on it and assert no spin-statistics theorem, no interaction, no dynamics and no measurement.
Facts & Assumptions
Given: The declared spin-half fermionic species with orbital factor of dimension , internal factor with basis , the two-particle antisymmetric sector, the regrouping unitary , and vectors , .
Sector vocabulary. The sector space is with the inner product of the completed tensor square, the rays of its nonzero vectors are the declared pure preparations of the two particles, and the exchange operator and projections act as in the cited lemmas (Declared species sectors and their preparations: the framework's reading of P6 clauses (c)-(d), The two-particle exchange operator and the symmetric and antisymmetric combinations clauses (a),(b)).
Regrouping and its identities. The regrouping unitary is unitary with , maps onto , and satisfies the vector identity (Regrouping two factors: the symmetry decomposition of a two-particle sector over an orbital and an internal factor clauses (b),(d),(e)).
Spin-half internal factor. For the total spin operators of Composition of two spin labels: total spin operators, the Clebsch-Gordan block decomposition and the spin-half singlet decompose with , ; the vector is a unit vector with for all and is, up to a phase, the unique unit vector in the kernel of ; the products are -eigenvectors with weight , so has weight and the combinations and are unit vectors in and with -weight (Composition of two spin labels: total spin operators, the Clebsch-Gordan block decomposition and the spin-half singlet clauses (b),(c),(d)).
Orbital symmetric and antisymmetric combinations. For a Hilbert space and orthonormal the vectors and are orthonormal, and and are orthogonal eigenvectors of the exchange operator; moreover for every (The two-particle exchange operator and the symmetric and antisymmetric combinations clauses (b),(c),(d)).
Dimensions. For a -dimensional space, and (Slater and symmetric occupation-number bases of the finite-dimensional permutation sectors clauses (b),(c)); the dimensions of the two orthogonal summands add (Regrouping two factors: the symmetry decomposition of a two-particle sector over an orbital and an internal factor clause (f)).
Proof
Given: The data of the statement and [F1]-[F5].
[Decomposition of the internal factor] By [F3] the antisymmetric combination spans and span the three-dimensional space ; since is antisymmetric under the exchange and are symmetric, and ; the two subspaces are orthogonal complements of each other because .
[Sector decomposition] By [F2] the unitary image of the sector is , an orthogonal direct sum, and step 1.1 identifies its summands as the spin-triplet part and the spin-singlet part ; by [F5] the singlet part has dimension , and the triplet part has dimension ; this is (a) up to the assignment of the names singlet and triplet, which is the naming of and in [F3].
[Opposite symmetry] The identity of (b) is the vector identity of [F2] under the identifications of steps 1.1 and 2.1: the first summand carries the internal factor in , the singlet, and the orbital factor in , the symmetric orbital component, while the second summand carries the internal factor in , the triplet, and the orbital factor in , the antisymmetric orbital component. This proves (b).
[Parallel spins] Let be orthonormal and a unit vector. By [F4] one has and ; hence the identity of (b) gives , and multiplying by gives the unit vector because and by [F4]; the nonzero original vector lies in the declared sector, and its image lies in the regrouped sector of [F2], so the two displayed image rays coincide, which is (c).
[Antiparallel spins] Let be orthonormal. The orbital projections are and by their definitions. In the internal tensor square, and by [F2] and the exchange formulas in [F4]. Substituting these four identities into (b) gives . The two tensor summands inside the parentheses are orthogonal unit vectors, by [F3] and [F4], so this complete projected vector has norm . Multiplying it by gives the unit representative of the image ray, as in (d). The orbital exchange fixes the first orthogonal nonzero component and negates the second, so their sum cannot be an eigenvector: comparison of the two components would require its eigenvalue to be both and . Thus the ray has no definite orbital exchange symmetry.
[Assembly and scope] Steps 1.1 and 2.1 prove (a), step 3.1 proves (b), step 4.1 proves (c) and step 4.2 proves (d). Every statement is conditional on the adopted antisymmetric sector of P6 and on the declared finite orbital factor; the internal factor is the bookkeeping factor of P6 and no spatial position, interaction, dynamics or measurement is introduced.
Remarks
- The singlet and triplet names. The names refer to the total spin of the pair in the sense of the internal-factor composition theorem: is the kernel of and is the triplet block. The orbital factor carries no spin and the theorem attributes no spin to the orbital degrees of freedom.
- A Slater determinant is a superposition. As clause (d) shows, the antisymmetrised product of two orthonormal one-particle states with opposite spin orientations contains both the singlet and the triplet components with equal amplitudes; a definite orbital exchange symmetry belongs to the components, not to every vector of the sector.
Depends on
Declared species sectors and their preparations: the framework's reading of P6
The declared finite-mode model and its occupation readouts
Regrouping two factors: the symmetry decomposition of a two-particle sector over an orbital and an internal factor
The two-particle exchange operator and the symmetric and antisymmetric combinations
Slater and symmetric occupation-number bases of the finite-dimensional permutation sectors
Composition of two spin labels: total spin operators, the Clebsch-Gordan block decomposition and the spin-half singlet
State and composition postulate P1: Hilbert spaces, preparations and composite systems
Identical-particle and spin assignments P6: permutation sectors and finite-spin representations
The state space of the framework: preparations, pure rays and density operators
The state space: density operators, pure and mixed states, and purity
Hilbert space
The Axiom of Countable Choice ()
Dependency tree · 2 levels
Sources
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 10.1.2 printed pages 229-230 (PDF pages 237-238): for a pair of spin-half particles, the spin-triplet states have antisymmetric spatial wavefunctions and the spin-singlet state a symmetric one
- D. Skinner, Principles of Quantum Mechanics (Cambridge Part II, Michaelmas 2021), Chapter 7 'Identical Particles', pp. 4-10: exchange symmetry, spin, and the symmetric and antisymmetric decomposition of a two-particle state; Internet Archive copy of the original https://www.damtp.cam.ac.uk/user/dbs26/PQM/chap7.pdf