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Exact finite-time response on a compact Hamiltonian phase
Statement
Let be a nonempty compact symplectic phase datum without boundary, with . Let be observables, let , and assume is finite and positive. Put . For and every , choose and perturb the Hamiltonian to , where is dimensionless. In SI, time has unit s. If is in J, has units , and has units , then has units J, has units J, and the response derivative has units .
Start every perturbed trajectory at the same unperturbed initial law and define . Then the derivative at exists and is For constant , define the equilibrium correlation Then the finite-time response is . If , its long-time limit is . No decay of this correlation is assumed in the finite-time formula.
Facts & Assumptions
Given: Compact boundaryless symplectic , smooth , a normalized canonical law, an unperturbed initial preparation, and a smooth finite-time control coupled as .
Assume for the positive-density measure construction in The Axiom of Countable Choice (). The phase is nonempty compact without boundary; are smooth real functions; ; ; is smooth on ; and the initial law is the fixed unperturbed .
is dimensionless, time is measured in s, has units J, has units , has units , has units J, and has units J.
Hamiltonian phase, complete-domain flow and reference measure and Hamiltonian vector field and Hamiltonian function: the sign convention is , so .
Time-dependent Hamiltonian vector field and flow: the perturbation field is .
Smooth dependence of ODE solutions on parameters: in Euclidean charts, solutions on a common compact time interval depend smoothly on the parameter. The finite-chart continuation and overlap argument needed for this compact-manifold application is supplied in step 1.1.
Liouville volume preservation and A volume-preserving diffeomorphism preserves its induced Borel measure: the unperturbed and flows preserve on their domains.
A Hamiltonian is conserved along its own flow: . Together, [F4], the definition of , and Integral invariance under measure-preserving maps make invariant under .
Integral invariance under measure-preserving maps: composition by a measure-preserving flow map leaves integrals unchanged.
Dominated convergence: on compact , the bounded parameter difference quotients may be passed through the integral.
The chain rule for total derivatives: : derivatives of smooth observables along the flow are obtained by applying the generating vector field, using the ordinary Euclidean chain rule in each coordinate chart.
Proof
Given: [A1]–[A2] and [F1]–[F8].
The perturbed field is the smooth time-dependent field by [F2]. Cover compact by finitely many smaller coordinate neighborhoods whose closures lie in larger coordinate charts. The coordinate fields and their first derivatives are bounded on these closures, uniformly for and in a fixed compact neighborhood of zero. Local ODE existence therefore gives a common positive continuation time from every point in each smaller neighborhood. Taking the minimum over the finite cover extends every solution across : a purported finite endpoint can be restarted from a point within that common time of the endpoint. The same argument applies backward for the unperturbed flow. The Euclidean smooth-parameter theorem [F3], applied in these charts on successive common time intervals, gives the smooth parameter variation with . In a chart , write and for the coordinate components. There the ordinary variational equation is Here is the matrix of derivatives of coordinate components in that chart; it is not asserted to be a canonical tangent endomorphism. If is another chart and is the transition map, then and , with the analogous identity for . Differentiating these identities along the reference path shows that the two variational equations agree: the extra term is , which equals by symmetry of the second derivative. Thus the variation is intrinsically defined. The tangent map is likewise intrinsic. In chart coordinates, variation of constants for the local linear variational equations, composed across the finite chart intervals, gives the intrinsic identity where the integral is in the fixed vector space . Applying the differential of and the chain rule [F8] gives
All integrands in step 1.1 and their parameter difference quotients are bounded on the compact manifold and finite time slab. Thus [F7] passes the derivative through the initial-law integral. Invariance of under from [F5]–[F6] then gives
Write . For any smooth , let be the flow of . By [F4], preserves . Consequently Differentiate at ; compactness bounds the derivatives, so differentiation under the integral is justified by [F7]. This proves . From [F1], , hence . Therefore
Apply step 2.2 with in step 2.1. This gives and proves the stated response formula.
For the correlation, differentiate under the integral on compact : . Applying the same measure-preserving-flow argument as step 2.2 with and using gives ; the constant contributes zero since . For constant , step 3.1 is therefore . If , the limit is .
Remarks
The conclusion is a mathematical model prediction conditional on its compact phase, smooth-control, and canonical-preparation hypotheses. The cited statistical-mechanics treatments motivate response/correlation formulas; the proof above supplies this precise finite-time sign convention and does not extend it to noncompact phases or unproved decay assumptions.
Depends on
Hamiltonian phase, complete-domain flow and reference measure
A volume-preserving diffeomorphism preserves its induced Borel measure
The Axiom of Countable Choice ()
Hamiltonian vector field and Hamiltonian function
Time-dependent Hamiltonian vector field and flow
Smooth dependence of ODE solutions on parameters
The chain rule for total derivatives:
Liouville volume preservation
A Hamiltonian is conserved along its own flow
Integral invariance under measure-preserving maps
Dominated convergence