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Controlled shrinking energy-density shell and three-ensemble equivalence

Statement

Assume AC, the ultrafilter extension principle, DC, and HB, and the superstable regular model of Periodic fixed-particle canonical limit, an interior density NL/Ld→ρ, and differentiability of β↦Fβ(ρ) at β>0. Put e=−∂βFβ(ρ). Suppose the grand variational minimizer at a supporting activity z>0 is a singleton P∗. Let RL,ω be the periodized empirical field of Periodized empirical field of a finite configuration. There exists a specified sequence δL↓0 such that the uniform positional shell law QΛL ⁣( ⋅ | N=NL, ∣HL,per/Ld−e∣≤δL) is eventually defined, and its empirical field converges in probability in τL to P∗. The free and periodic exact-N canonical empirical fields and the matching periodic grand-canonical empirical field converge in probability to the same limit. Convergence in probability here uses outer probabilities for arbitrary open neighborhoods, as defined in Conditioning grand empirical fields on an exact particle number, and ordinary probabilities for measurable ones. The energy width 2δLLd=o(Ld); no arbitrary prescribed width or zero-width surface measure is asserted.

Facts & Assumptions

Given: The four named choice hypotheses, interaction, density, differentiability, supporting activity, and singleton minimizer stated above.

[F1]

Periodic fixed-particle canonical limit: periodic exact-N log partitions converge to Fβ(ρ), and their empirical fields concentrate near the supporting minimizer set; that statement alone supplies no exponential rate.

[F2]

Fixed-particle local ensemble equivalence at interior density: free exact-N empirical fields concentrate near the supporting grand minimizer set.

[F3]

Superstable regular continuum grand pressure and variational formula: the grand variational minimizer set is compact in τL.

[F4]

Periodized empirical field of a finite configuration and Stationarity and intensity of a periodized empirical field: periodized empirical fields are stationary laws with intensity NL/Ld.

[F5]

Conditioning grand empirical fields on an exact particle number: under the four choice hypotheses, superstability, regularity, an interior density, a supporting activity, and the exact-N canonical rate, for either boundary condition the outer probability outside every open neighborhood of the grand minimizer set has a strictly negative exponential rate.

[L1]

Georgii's Theorem 2 (1994, Sections 3–5) gives the good τL large-deviation bounds on evaluation-measurable sets for periodized empirical fields under the periodic grand-canonical law, with zero set equal to its stationary variational minimizers. The complete Sections 3–5 proof was read; arbitrary open neighborhoods are handled below by measurable basic neighborhoods.

Proof

Given: The assumptions and suppliers in Facts & Assumptions.

1.1F1algebra

Let CL be the periodic exact-NL canonical law. For ∣t∣<β, ECLetHper=Zper(L,NL;β−t)/Zper(L,NL;β). By [F1], the normalized log moment generating function converges to Fβ−t(ρ)−Fβ(ρ), whose derivative at zero is e. For any fixed ϵ>0, choose small positive and negative t so the Chernoff exponents for H/Ld≥e+ϵ and H/Ld≤e−ϵ are strictly negative. Hence the canonical probability outside the fixed ϵ-window tends to zero.

1.2A1F1F3F4F5algebra

The supporting activity and singleton minimizer are given. The exact-N periodic rate is [F1]; the choices in [A1], the superstable regular potential, and the empirical-field convention [F4] are precisely the other hypotheses of [F5]. Applying [F5] with periodic boundary gives, for every open U∋P∗, a constant cU>0 with lim sup⁡L−dlog⁡CL∗(RL,ω∉U)≤−cU. This supplies the exponential estimate needed for the shell comparison.

2.1step 1.1choose

Choose strictly increasing thresholds Lk≥k so that for every L≥Lk the probability outside the 1/k window is at most 1/k. Set k(L)=max⁡{k:Lk≤L} and δL=1/k(L). Then δL↓0 and the canonical probability of the selected shell tends to one. Positivity of the canonical weight on the shell implies positive Poisson reference measure, so the shell law is defined eventually.

3.1F4step 2.1step 1.2algebra

Let U be any open τL neighborhood of P∗ and let SL={N=NL, ∣HL,per/Ld−e∣≤δL} be the selected shell event. On SL, the unnormalized periodic Boltzmann factor lies between e−βLd(e+δL) and e−βLd(e−δL). For each measurable event, the normalization constants cancel when comparing conditional probabilities; taking infima over measurable supersets gives the same inequality for outer probabilities, so (QΛL( ⋅∣SL))∗(RL,ω∉U)≤e2βδLLdCLper(SL) (CLper)∗(RL,ω∉U). By step 2.1, CLper(SL)→1. By step 1.2, the last outer probability has a strictly negative exponential rate. Since δL→0, the right side tends to zero. Thus the uniform shell empirical field converges in probability to P∗.

4.1F2F3F4L1step 3.1∎

For any open neighborhood U of P∗, choose a basic neighborhood V of P∗ contained in U, defined by finitely many strict tame-expectation inequalities. It is evaluation-measurable. The free exact-N empirical fields concentrate on V by [F2], so their outer probabilities outside U vanish. The periodic grand empirical fields obey the good LDP [L1]; its unique zero is P∗ by [F3], so the measurable-set upper bound outside V has a strictly negative rate by compactness of rate sublevels. As Uc⊆Vc, its outer probability tends to zero. Together with steps 2.1 and 3.1, this proves the stated three-ensemble conclusion.

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