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Uniform exterior-pressure limit for tempered configurations

Statement

Assume a stable regular pair potential ϕ as in Superstable regular pair interactions and configurational ensemble notation, with stability constant B, and the genuine finite-valued positive-core condition of Superquadratic cell coercivity from a divergent or hard core: for some r0>0, a nonincreasing χ:(0,r0]→(0,∞) satisfies ϕ(x)≥χ(∣x∣∞) for 0<∣x∣∞≤r0 and ∫0r0χ(r)rd−1 dr=+∞. Let Λn=[−n−12,n+12)d, Vn=(2n+1)d, Ci=i+[−12,12)d, and Clf be the set of locally finite simple configurations ζ⊂Rd. For t≥0 define Ω(t)={ζ∈Clf:∑i∈Λn∩ZdNCi(ζ)2≤tVn for every integer n≥0}. For ω=(q1,…,qN)∈SN(Λn), write Hn,free(ω)=∑1≤i<j≤Nϕ(qi−qj). For ζ∈Ω(t), let ζnout=ζ∖Λn and define the finite-volume boundary Hamiltonian Hn,ζ(ω)=Hn,free(ω)+∑i=1N∑y∈ζnoutϕ(qi−y). The exterior series has finite negative part by the proof below; its extended value may be +∞, with e−β(+∞)=0. Define Zn,ζ(N;β)=1N!∫SN(Λn)e−βHn,ζ(ω) dq1⋯dqN,Zn,ζ(0;β)=1,Ξn,ζ(z,β)=∑N≥0zNZn,ζ(N;β). For fixed z,β>0 and t<∞, the free-wall grand pressure with this exterior pair energy satisfies lim⁡n→∞sup⁡ζ∈Ω(t)∣1Vnlog⁡Ξn,ζ(z,β)−p(z,β)∣=0, where p(z,β) is the free-cube pressure from Free-cube grand-pressure limit for decreasing integrable tails. The exterior configuration is restricted to the stated fixed square-count class; no volume-filling external field is included. The conclusion is conditional on the genuine positive core and does not infer it from superstability alone.

Facts & Assumptions

Given: The positive divergent core, regular far tail, fixed z,β>0, and a fixed finite tempering constant t.

[F1]

Superstable regular pair interactions and configurational ensemble notation: stability gives ϕ(x)≥−2B for every nonzero separation, and the far pair interaction is bounded in absolute value by a decreasing integrable envelope ψ outside some radius R0.

[F2]

Diagonal gap for a decreasing integrable interaction tail: the cell envelope is summable, and the diagonal tail choice has g(ℓ)→∞, g(ℓ)/ℓ→0, and (ℓ/g(ℓ))dη(g(ℓ))→0.

[F3]

Superquadratic cell coercivity from a divergent or hard core: for the genuine core there is an increasing finite-valued h:N0→[0,∞) with h(0)=0, h(m)/m2→∞, and H≥∑ih(Ni)−bN on unit cells. Translation invariance gives the same inequality for the centered cells Ci used here.

[F4]

Free-cube grand-pressure limit for decreasing integrable tails: all perturbed free-cube grand pressures at positive activity and inverse temperature exist and are finite.

[F5]

Holder's inequality for integrals, including the endpoint cases: Hölder’s inequality gives convexity of finite-volume log partition functions in inverse temperature and log activity.

[L1]

Ruelle's tempered-boundary estimates apply to superstable, lower-regular interactions with the stated square-count exterior class; the full source proof and exact hypotheses were read. The near/far estimate used below is written explicitly in the proof.

Proof

Given: The hypotheses and suppliers in Facts & Assumptions.

1.1F1F2F3algebra

Put Sn={i∈Zd:∣i∣∞≤n}, vn=∣Sn∣=Vn, Ni(ω)=∣ω∩Ci∣, Tn(ω)=∑i∈SnNi(ω)2, and Tnh(ω)=∑i∈Snh(Ni(ω)). Choose m0≥⌈R0+1⌉ and M0≥max⁡{2B,ψ(m0−1)}. Set γm=M0 for integers m<m0 and γm=ψ(m−1) for m≥m0. Then γ is nonincreasing, dominates the negative part at every cell offset, dominates ∣ϕ∣ at offsets m≥m0, and ∑j∈Zdγ∣j∣∞<∞ by [F1]–[F2]. Let Δm=γm−γm+1≥0 and vm=(2m+1)d. Since γr=∑m≥rΔm, Tonelli gives ∑mΔmvm=∑jγ∣j∣∞<∞. Thus δk:=12∑m≥kΔmvm→0.

2.1F2step 1.1algebra

For an interior configuration ω⊂Λn and any ζ∈Ω(t), the long-offset cell sum satisfies ∑i∈Sn, j∈Zd: ∣i−j∣∞≥kγ∣i−j∣∞Ni(ω)Nj(ζ)≤δk(Tn(ω)+2dtVn). Indeed, expand γr=∑m≥rΔm and enlarge the offset set in the mth term to j∈Sm+i. With Sn,m(ζ)=∑j∈ZdNj(ζ)2 #{i∈Sn:j∈Sm+i}, the inequality ab≤(a2+b2)/2 bounds that term by 12Δm(vmTn+Sn,m). The multiplicity is at most min⁡(vn,vm) and vanishes unless j∈Sn+m, so Sn,m≤min⁡(vn,vm)tvn+m≤2dtvnvm. Summing proves the estimate.

3.1F1F2F3step 1.1step 2.1algebra

Set g(r)=rh(r) for r∈N0 and g∗(s)=sup⁡r∈N0{rs−g(r)}. Then g(r)/r2→∞ and g(r)/h(r)→0, so g∗(s)/s2→0: for each a>0, eventually g(r)≥r2/(4a), and completing the square gives g∗(s)≤as2+Ca. Also rs≤g(r)+g∗(s). For a fixed k≥m0, every near cross pair has its inside cell in Sn∖Sn−k and its exterior cell in Sn+k∖Sn; its negative energy is at most M0. Counting the finitely many offsets of size below k, for every a>0 we obtain Wnear−≤Ck(aTnh+Ca∣Sn∖Sn−k∣+atvn+k+Ca∣Sn+k∖Sn∣). Here g(r)≤ah(r)+Ca and g∗(s)≤as2+Ca were used, with ∑j∈Sn+k∖SnNj(ζ)2≤tvn+k. First choose k large in step 2.1 so that its far negative-energy bound is at most ϵ(Tnh+Vn)/2. For this fixed k, both boundary-cell counts are Ok(nd−1) and vn+k/vn→1, so choosing a small and then n large makes the near bound at most ϵ(Tnh+Vn)/2. The far estimate uses Tn≤Tnh+q2Vn for a fixed q with h(r)≥r2 when r≥q. Consequently, for each 0<ϵ<1 and all sufficiently large n, Wn(ω,ζ)≥−ϵTnh(ω)−ϵVn uniformly over ζ∈Ω(t).

3.2F1F2F3step 1.1step 2.1algebra

For the lower bound, restrict interior particles to Λn−k, leaving the corridor empty. Choose k≥m0, so every interior-exterior cell offset is in the far tail. The two-sided estimate of step 2.1 gives ∣W(ω,ζ∖Λn)∣≤δk(Tn−k(ω)+2dtVn−k). With Tn−k≤Tn−kh+q2Vn−k, choose k large enough that the right side is at most ϵ(Tn−kh+Vn). Since Tn−kh≤Hn−k,free+bN, integration over the restricted positions yields Ξn,ζ(z,β)≥e−βϵVnΞ(2(n−k)+1;ze−βϵb,β(1+ϵ)) uniformly over ζ. For fixed ϵ, the selected k is fixed as n→∞, and the removed corridor volume fraction vanishes.

4.1F3step 3.1algebra

By [F3], Tnh≤Hn,free+bN. For each 0<ϵ<1 and all sufficiently large n, step 3.1 therefore gives Ξn,ζ(z,β)≤eβϵVn∑N≥0zNN!∫SN(Λn)e−βHn,free+βϵTnh dqN and ∑N≥0zNN!∫SN(Λn)e−βHn,free+βϵTnh dqN≤Ξ(2n+1;zeβϵb,β(1−ϵ)). The inequality is uniform over ζ∈Ω(t).

5.1F4F5step 4.1step 3.2algebra∎

Divide the bounds in steps 4.1–3.2 by Vn and let n→∞; [F4] supplies the perturbed free-cube pressure limits. These limits are finite convex functions of (β,log⁡z) by Hölder's inequality [F5], since finite-volume log partition functions are convex and pointwise limits preserve convexity. A finite convex function is continuous on the open parameter domain β>0, z>0. Let ϵ↓0 in both uniform bounds. Their upper and lower limits coincide with p(z,β) uniformly over Ω(t). For t=0, every exterior configuration in Ω(0) is empty, so the equality with the free-wall pressure is immediate.

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