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An exact two-level energy readout and its moments
A finite, exact model computation in the two-level state space of the framework: the energy observable E_1 P_1 + E_2 P_2 for two distinct energies in joules, its spectral measure, the outcome probabilities of a pure and of a statistical mixture (mixed for interior weights and pure at the endpoints), and the mean, second moment and variance of the readout. The energies are model parameters; the item asserts no apparatus realization, no measurement statistics from a laboratory and no empirical value.
Example
Let carry the standard inner product (Real and complex inner product spaces, with the inner product linear in the first argument, Hilbert space, The induced length is a norm, Conjugation is an involutive real-field automorphism, , and modulus is definite, multiplicative, and subadditive), with orthonormal basis , . Fix two distinct energies in joules (model parameters, not measured values), and consider the assigned sharp observable with the rank-one calculus of Rank-one operator calculus (Assigned sharp observables and the outcome law of the framework). Then:
(i) is bounded and self-adjoint with ; its spectral projection-valued measure is so the spectrum is and the outcome lies in it almost surely: for every preparation . This probability-one statement does not logically exclude realizations in a null event.
(ii) For the pure preparation of the unit vector , , the outcome law is and for the statistical mixture with the law is , . This preparation is mixed exactly when ; at it is the pure state , and at it is the pure state .
(iii) With and , the mean, second moment and variance of the pure preparation are and for the mixture replace by and by ; all three numbers are finite and exact because is bounded.
The computation is a model-internal readout: the are parameters of the assigned observable, the probabilities are those of the framework's outcome law, and no laboratory measurement, apparatus or empirical value is asserted.
Facts & Assumptions
Given: The Hilbert space with the standard inner product and orthonormal basis ; distinct real energies in joules; the assigned observable with unit ; a unit vector ; a weight ; the Axiom of Countable Choice and the Axiom of Choice (The Axiom of Countable Choice (), The Axiom of Choice), the choice hypotheses of the cited spectral suppliers.
Rank-one calculus and one-dimensional projections. is linear in , with and self-adjoint and positive; for unit the operator is the orthogonal projection onto with , its trace is , and for orthonormal one has (Rank-one operator calculus, Rays, unit vectors and rank-one Hilbert projections,).
Finite-dimensional spectral structure. The eigenvectors of the normal operator form an orthonormal basis of , so (Complex spectral theorem: a normal endomorphism of a finite-dimensional complex inner product space has an orthonormal eigenbasis, and conversely).
Spectral PVM uniqueness. A self-adjoint operator has a unique regular PVM on the Borel sets of representing it, and the spectral PVM is that measure (Spectral theorem for unbounded self-adjoint operators (PVM form)).
Outcome law. For an assigned observable the law is , equal to for a pure preparation, and it is affine under mixtures (Assigned sharp observables and the outcome law of the framework clauses (b) and (c), The Born outcome law: probability measure, mixtures, atoms and spectral support clauses (a) and (b)).
Moments. For a unit vector in the mean and second moment are and , and the variance is the second moment minus the square of the mean (clauses (a)-(c), Mean, second moment and variance of an assigned observable in a preparation clauses (a) and (b)).
States of the model. A state is a self-adjoint positive trace-class operator of trace one. A pure state is for a unit vector , equivalently a rank-one orthogonal projection; a state is mixed when it is not pure (The state space: density operators, pure and mixed states, and purity, Density operators and Pure states). The statistical mixture here is a state by positivity and the rank-one trace formulas in [F1].
Verification
[The observable and its spectral measure] is bounded with and self-adjoint because each is self-adjoint by [F1] and ; and . Define ; [F1] gives that each value is an orthogonal projection and that , while [F2] gives ; multiplicativity and countable additivity hold because the two-point space is finite, and the integral of the identity against is . By uniqueness [F3], is the spectral PVM of , so . Its displayed PVM has , so [F4] gives for every preparation, proving the almost-sure support claim of (i).
[Outcome probabilities] For the unit vector , the identity from [F1] gives , whose norm squared is ; by [F4] this is , so in particular and the total mass is . For the mixture, is self-adjoint, positive and trace class by [F1] and , with trace , so it is a state by [F6]. If , then and give range , of dimension two; hence is not a rank-one projection and is mixed. At or it equals the respective rank-one projection or and is pure. Now [F4] and linearity of the trace give because and by [F1], and similarly ; this is clause (ii).
[Moments of the readout] With , , the vector lies in , so [F5] applies: the mean is , the second moment is , and the variance is their difference, computed as , using and . For the mixture , which is a state by [F6], the same identities give mean and variance , since the law is the two-point law of (ii) and the moments of a finite two-point law are the displayed sums. All quantities are finite because is bounded. This is clause (iii).
Remarks
- The two eigenvalues are distinct, so the eigenspaces are one-dimensional and the spectral projections are exactly the rank-one projections ; a degenerate energy would replace them by the projection onto the eigenspace and the exact-value probabilities by its trace weight, in agreement with Atoms of the spectral measure and eigenvalues of a self-adjoint operator.
- The example is a finite model computation, not a reported experiment: nothing here identifies with the levels of a specific physical system, and no counts, uncertainty or apparatus behaviour is asserted.
Depends on
The induced length is a norm
The Axiom of Choice
The Axiom of Countable Choice ()
Hilbert space
Real and complex inner product spaces, with the inner product linear in the first argument
Assigned sharp observables and the outcome law of the framework
The state space: density operators, pure and mixed states, and purity
Conjugation is an involutive real-field automorphism, , and modulus is definite, multiplicative, and subadditive
Rank-one operator calculus
Atoms of the spectral measure and eigenvalues of a self-adjoint operator
Rays, unit vectors and rank-one Hilbert projections
The Born outcome law: probability measure, mixtures, atoms and spectral support
Mean, second moment and variance of an assigned observable in a preparation
Complex spectral theorem: a normal endomorphism of a finite-dimensional complex inner product space has an orthonormal eigenbasis, and conversely
Spectral theorem for unbounded self-adjoint operators (PVM form)
Dependency tree · 2 levels
Sources
- B. Zwiebach, MIT 8.05 Quantum Physics II (Fall 2013), Chapter 7 'Two State Systems', Section 1, printed pages 1-6 (the two-state Hamiltonian with energies g_0 plus or minus g and its energy eigenstates)
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Sections 1.3.6 and 2.1, printed pages 13-14 and 17-21 (probabilities in a two-state space and the operator description of observables)