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Repeated-orbital fermion exclusion

Example

Slot convention. For ℓ≥1, Sℓ acts on {0,…,ℓ−1} as in Permutation sector projections on the n-fold tensor power. On one-based tuple positions use π^(k):=1+π(k−1) for 1≤k≤ℓ. Conjugation by k↦k−1 gives πσ^=π^∘σ^ and π−1^=π^−1; thus the supplier's tensor action becomes Uπ(v1⊗⋯⊗vℓ)=vπ^−1(1)⊗⋯⊗vπ^−1(ℓ). The parameters of Uπ and sgn⁡(π) remain canonical zero-based permutations.

Assume the Axiom of Countable Choice and the Axiom of Choice. Let H be a complex Hilbert space, let H⊗n be its completed tensor powers with the unitaries Uπ and projections P±(n) of Permutation sector projections on the n-fold tensor power. Fix n≥2 and vectors u1,…,un∈H, and let S(u1,…,un):=1n!∑σ∈Snsgn⁡(σ) uσ^(1)⊗⋯⊗uσ^(n) be the Slater vector of Slater direct and exchange calculation. This example verifies concretely that:

(a) for every u∈H the antisymmetrised two-particle tensor vanishes, P−(2)(u⊗u)=0, because the canonical transposition τ=(0 1)∈S2 of the two tensor factors satisfies Uτ(u⊗u)=u⊗u and P−(2)=12(id−Uτ);

(b) consequently the Slater vector with a repeated orbital is the zero vector, S(u,u)=12(u⊗u−u⊗u)=0(u∈H), and the norm-one conclusion of Slater direct and exchange calculation (a) does not apply to the degenerate list (u,u): orthonormality of u1,…,un is an essential hypothesis, not a convenience; for orthonormal u1,u2 one has ∥S(u1,u2)∥=1;

(c) exclusion is a property of the state and not only of basis labels: for H=C2 with orthonormal basis e1,e2 and the non-basis vector u:=e1+e2 the antisymmetric part still vanishes. Indeed u⊗u=e1⊗e1+e1⊗e2+e2⊗e1+e2⊗e2, and P−(2) annihilates the two diagonal tensors while exchanging the two crossed tensors with opposite sign, so P−(2)(u⊗u)=0;

(d) in the actual tensor space H⊗2, the two-particle antisymmetric sector ran⁡P−(2) contains no nonzero vector of the form P−(2)(u⊗u): every repeated-orbital projection is zero, and zero belongs to this sector as it does to every linear subspace. Thus a nonvanishing antisymmetric two-particle vector cannot be built from two copies of the same one-particle vector. This sector is distinct from the symmetric two-particle sector of the bosonic F(H) in Hilbert direct-sum construction.

The antisymmetric sector and its projection are mathematical objects; as recorded in the cited suppliers, selecting this sector for a species is a postulate and no spin-statistics statement is proved here.

Verification

Given: the complex Hilbert space H, its completed tensor powers H⊗n, the permutation unitaries Uπ and the projections P±(n), the transposition τ∈S2, the vector u=e1+e2∈C2 and the orthonormal family (e1,e2).

[F1] For every π∈Sn there is a unique unitary Uπ with Uπ(v1⊗⋯⊗vn)=vπ^−1(1)⊗⋯⊗vπ^−1(n), Uπ∗=Uπ−1; for n=2 and the transposition τ one has τ−1=τ and Uτ(v1⊗v2)=v2⊗v1. Moreover P−(2)=12(id−Uτ), and Uτ(u⊗u)=u⊗u (Permutation sector projections on the n-fold tensor power (a), (b), Hilbert tensor construction: inner product, completion and product bases).

[F2] S(u1,u2)=12(u1⊗u2−u2⊗u1)=2 P−(2)(u1⊗u2), and ∥S(u1,u2)∥=1 whenever u1,u2 are orthonormal; for u1=u2=u the two summands coincide, so the alternating sum vanishes (Slater direct and exchange calculation (a), Orthonormal families, complete orthonormal systems and Hilbert bases).

[F3] The actual two-particle antisymmetric sector is ran⁡P−(2)⊆H⊗2, a closed linear subspace and hence containing zero (Permutation sector projections on the n-fold tensor power (b)). The source F(H) is the symmetric bosonic direct sum, whose two-particle sector is ι2(ran⁡P+(2)), not the antisymmetric sector (Hilbert direct-sum construction).

1.1F1algebra

[The two-particle exclusion] For u∈H the swap identity Uτ(u⊗u)=u⊗u of [F1] gives P−(2)(u⊗u)=12(u⊗u−Uτ(u⊗u))=0. This is (a).

2.1F2step 1.1algebra

[Slater vector with repeated orbital] By [F2] with u1=u2=u, S(u,u)=12(u⊗u−u⊗u)=0; equivalently S(u,u)=2P−(2)(u⊗u)=0 by step 1.1. For orthonormal u1,u2, [F2] gives ∥S(u1,u2)∥=1, so the hypothesis of pairwise orthonormal orbitals in [F2] cannot be dropped. This is (b).

2.2F1step 1.1algebra

[Superposition check] Let u=e1+e2∈C2. Bilinearity of the tensor product gives u⊗u=e1⊗e1+e1⊗e2+e2⊗e1+e2⊗e2. By [F1], Uτ fixes e1⊗e1 and e2⊗e2 and interchanges e1⊗e2 with e2⊗e1; hence P−(2)(u⊗u)=12((e1⊗e2+e2⊗e1)−(e2⊗e1+e1⊗e2))=0, in agreement with step 1.1. This is (c).

2.3F3step 1.1algebra

[Consequence in the antisymmetric sector] If u≠0 then u⊗u≠0 (the tensor product of nonzero vectors has norm ∥u∥2>0), while step 1.1 gives P−(2)(u⊗u)=0; so no nonzero two-particle antisymmetric vector arises by antisymmetrising u⊗u. By [F3] this is a statement about the sector ran⁡P−(2) of H⊗2 ; the zero projection belongs to that linear sector, but no nonzero vector of that form exists. The bosonic F(H) has the distinct symmetric sector of [F3]. This is (d).

3.1step 1.1step 2.1step 2.2step 2.3∎

[Conclusion and scope] Steps 1.1 and 2.1 prove (a) and (b), step 2.2 proves (c), and step 2.3 proves (d). The scope paragraph of the example records that the symmetric/antisymmetric sector assignment is a postulate and that no spin-statistics statement is proved. This completes the verification.

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