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Qm Math Fock And Equilibrium — Examples
1 · Prerequisites
- Absolute and Conditional Convergence; Rearrangement; Products
- Algebraic Closure, Embeddings, and Separability
- Algebraic Extensions, Extension Degree, and Finite Fields
- Analyticity of Holomorphic Functions; Liouville and Morera
- Approximation and Compactness in C(K)
- Arc Length and Rectifiable Curves
- Areas of Elementary Plane Figures
- Banach Alaoglu Goldstine and Krein Milman
- Banach Algebras Spectrum and Holomorphic Functional Calculus
- Banach Valued Integration and the Radon Nikodym Property
- Bessel-Potential Completions and Real-Order Sobolev Spaces
- Binary Operations, Monoids, Groups and Subgroups
- Bounded Linear Operators and Quotient Spaces
- Bounded Variation and the Riemann–Stieltjes Integral
- Compact Operators and Riesz Schauder Theory
- Compact Self Adjoint Hilbert Schmidt and Trace Class Operators
- Compactness
- Compactness in Metric Spaces
- Completeness, Completion, and Uniform Continuity
- Complex Differentiability and the Cauchy–Riemann Equations
- Complex Lp Spaces and Test-Function Conventions
- Complex Power Series and Analytic Functions
- Composition Series, the Jordan–Hölder Theorem and Solvable Groups
- Congruences, the Integers Modulo n and the Chinese Remainder Theorem
- Connectedness
- Construction of the Natural Numbers
- Construction of the Real Numbers via Cauchy Sequences
- Construction of the Real Numbers via Dedekind Cuts
- Continuity, IVT, EVT, and Uniform Continuity
- Continuous Functional Calculus for Self Adjoint and Normal Operators
- Contour Integration
- Convergence: Nets and Filters
- Cosets, Index and Lagrange's Theorem
- Countability and Uncountability
- Countability Axioms and Cardinal Functions
- Cyclic Groups and Direct Products
- Darboux, L'Hôpital, and Taylor's Theorem
- Density Separability and Convolution in Lᵖ
- Determinants of Matrices over a Commutative Ring
- Diagonalisation and the Minimal Polynomial
- Distributions Test Functions and Differentiation
- Divisibility, Euclidean Domains, Principal Ideal Domains and Unique Factorisation
- Divisibility, Greatest Common Divisors and Bézout's Identity
- Dual Spaces Adjoint Operators and Annihilators
- Dual Spaces, Bilinear and Quadratic Forms, and Sylvester's Law of Inertia
- Eigenvalues, Eigenvectors and the Characteristic Polynomial
- Euclidean Surface Measure, Divergence, and Green Identities
- Filters and Ultrafilters
- Finite Counting, Factorials and Binomial Coefficients
- Finite Dimensional Normed Spaces and Riesz Lemma
- Finite Probability and the Probabilistic Method
- Foundations of the Real Numbers for Analysis
- Fourier Multipliers and Sobolev Characterisations
- Fourier Transform Convolution and Approximate Identities
- Free Modules, Exact Sequences, Projective and Injective Modules
- Fubini and Change of Variables
- Function Space Topologies and the Exponential Law
- Fundamental Trigonometric Identities
- Gaussian Elimination, Elementary Matrices and Reduced Row Echelon Form
- Gelfand Theory and Commutative C Star Algebras
- Goursat's Theorem and Cauchy's Theorem in a Convex Domain
- Group Actions, Orbits, Stabilisers and Cayley's Theorem
- Group Homomorphisms and the Isomorphism Theorems
- Hausdorff via the Diagonal
- Hilbert Space Geometry and Riesz Representation
- Ideals, Quotient Rings and the Isomorphism Theorems for Rings
- Improper and Parameter-Dependent Multiple Integrals
- Improper Integrals
- Inner Product Spaces, Gram-Schmidt, Projections and Adjoints
- Lebesgue Measure on Euclidean Space
- Limits of Real Functions
- limsup, liminf, and Subsequential Limits
- Line Integrals and the Gradient Theorem
- Linear Independence, Bases and Dimension
- Linear Transformations, Rank-Nullity and Quotient Spaces
- Matrices, the Matrix of a Linear Map, and Change of Basis
- Measurable Functions and Simple Approximation
- Measures and Their Basic Properties
- Metric Spaces
- Mixed Partials, Taylor Formulae, and Extrema
- Modes of Convergence Egorov and Lusin
- Modules, Submodules, Quotient Modules and the Isomorphism Theorems
- Monotone Functions, Discontinuities, and Continuity Sets
- Monotone Sequences, Bolzano-Weierstrass, and Cauchy Completeness
- Normal Subgroups and Quotient Groups
- Normed and Banach Spaces
- Norming and Separation under Hahn–Banach
- Order, Zorn's Lemma, and the Axiom of Choice
- Orthonormal Bases, Parseval and Fourier Series
- Outer Measure and the Caratheodory Extension Theorem
- Partitions of Unity and Paracompactness
- pi: the Equivalent Characterizations
- Polynomial Rings, the Division Algorithm and Roots
- Power Series and Real-Analytic Functions
- Primes, Euclid's Lemma and the Fundamental Theorem of Arithmetic
- Product Measures and the Fubini Tonelli Theorems
- Properties of the Integral and the Working FTC
- Qm Math Composites
- Qm Math Coulomb
- Qm Math Fock And Equilibrium
- Qm Math Oscillator
- Radon Measures and the Riesz Markov Kakutani Theorem
- Regular Surfaces and Surface Integrals
- Relations, Functions, and Quotients
- Rings, Subrings, Integral Domains and Fields
- Rⁿ as a Normed Space; Vector-Valued Functions
- Roots, Rational Powers, and Classical Inequalities
- Schwartz Space and the Plancherel Theorem
- Separation Axioms: the Hierarchy
- Sequences and Limits
- Sequences and Series of Functions; Uniform Convergence
- Series: Convergence and the Nonnegative Tests
- Sigma Algebras and Borel Sets
- Signed and Complex Measures Hahn and Jordan
- Simple Field Extensions and the Construction of the Complex Numbers
- Sine, Cosine, and the Definition of Pi
- Smooth Approximation and Sobolev Extension
- Smooth Partitions of Unity and Exhaustions
- Spectral Measures and Borel Functional Calculus
- Splitting Fields
- Stone–Weierstrass in General
- Subspaces, Products, and Quotients
- Suprema and Infima
- Sylow's Theorems, p-Groups and Nilpotent Groups
- Symmetric Groups, Cycle Decomposition and the Sign Homomorphism
- Tempered Distributions and the Fourier Transform
- Tensor Products of Modules
- The Analytic Hahn Banach Theorem
- The Baire Principles of Functional Analysis
- The Cantor Set, Baire Category, and Measure Zero in ℝ
- The Complex Exponential and Euler's Formula
- The Derivative and the Mean Value Theorems
- The Determinant of a Linear Operator, Cofactors and Cramer's Rule
- The Divergence Theorem and Classical Stokes
- The Exponential Function
- The Fundamental Theorem of Algebra
- The Fundamental Theorem of Finite Abelian Groups
- The Fundamental Theorems of Calculus
- The Galois Correspondence
- The Inverse and Implicit Function Theorems
- The Inverse Function Theorem Completed
- The Lebesgue and Riemann Integrals Compared
- The Lebesgue Integral and the Convergence Theorems
- The Logarithm and General Powers
- The Lᵖ Spaces Holder Minkowski and Riesz Fischer
- The Maximal Function and Lebesgue Differentiation
- The Riemann Integral in Rᵐ and Jordan Content
- The Riemann Integral: Definition and Integrability
- The Spectral Theorem, Positive Operators and Singular Value Decomposition
- The Topology of Euclidean Space
- The Total Derivative in ℝᵐ → ℝⁿ
- The ZFC Axioms and the Basic Set Constructions
- Topological Spaces and Continuity
- Topology of ℝ
- Triangularisation, Generalised Eigenspaces and Jordan Canonical Form
- Unbounded Self Adjoint Operators and Stones Theorem
- Urysohn's Lemma and the Tietze Extension Theorem
- Vector Spaces, Linear Subspaces, Span and Direct Sums
- Volumes of Elementary Solids and Solids of Revolution
- Weak Derivatives and Sobolev Spaces
2 · Summary
The companion page to qm-math-fock-and-equilibrium records three explicit
mathematical checks on its equilibrium and exclusion statements. All three
items are mathematics: they carry domain: mathematics, depend only on the
parent page, earlier mathematical suppliers and published mathematics, and make
no physical or empirical claim.
Infinite identical-mode divergence takes the degenerate mode list on a separable infinite-dimensional one-particle space: the weight sum diverges, the partial products grow at least like , and the diagonal weight operator of Countable-mode product criterion is not trace class, while a single mode of the same frequency has the finite trace by Single-mode thermal trace; the divergence is caused by the infinite multiplicity, not by the value of the frequency.
No automatic equilibration exhibits the non-stationary unit vector of the one-mode Fock space: under the unitary group generated by the state keeps returning to itself, the expectation of equals and has no limit, and the state has no norm limit, whereas the weight operator of Single-mode thermal trace is invariant under the same dynamics; unitary evolution alone therefore does not equilibrate a non-stationary state.
Repeated-orbital fermion exclusion verifies concretely that for every because the transposition fixes , that the Slater vector with a repeated orbital is the zero vector (so the norm-one statement of Slater direct and exchange calculation genuinely needs orthonormal orbitals), and that exclusion survives for the non-basis vector in : it is a property of the state, not of basis labels.
3 · Logical flowchart
4 · Definitions, postulates, theorems and proofs
None yet.
5 · Examples, experiments and counterexamples
Infinite identical-mode divergence
Example
Assume the Axiom of Countable Choice and the Axiom of Choice. Let be a separable infinite-dimensional complex Hilbert space with complete orthonormal family , let , , and consider the degenerate mode list (infinitely many modes of one and the same positive frequency). Adopt the notation , , , , , of Countable-mode product criterion. This example verifies concretely that:
(a) the one-particle weight sum diverges for every , so the product criterion of Countable-mode product criterion (d) is violated;
(b) the grand-canonical weights do not converge: for every and these partial products increase to ; quantitatively for every ;
(c) consequently the diagonal operator is not trace class, and there is no finite grand-canonical partition sum for this mode list;
(d) the divergence is caused by the infinite multiplicity of the frequency, not by its value: for the one-mode space with frequency , Single-mode thermal trace gives the finite value of the trace of the weight operator, whereas the countable product of these one-mode factors diverges here.
No thermodynamic interpretation of , of or of the divergence is asserted; the example is a statement about the convergence of the displayed series for a degenerate mode list.
Verification
Given: the separable infinite-dimensional with complete orthonormal family , the constant mode list , , and the objects of Countable-mode product criterion.
[F1] For every , , and if and only if , in which case the sum equals the infinite product; (Countable-mode product criterion (c), (d)).
[F2] is trace class exactly when , and then equals that sum (Countable-mode product criterion (b), (e)).
[F3] If a series of reals converges then its terms tend to ; contrapositively, a series whose terms do not tend to diverges (If a series converges then its terms tend to , Series and absolute convergence in a normed space).
[F4] For , put . The integral inequalities give , and the reciprocal law of the natural logarithm gives ; the supplier also gives the product law ; is increasing and is inverse to the real exponential (The natural logarithm has derivative 1/x and equals the integral from 1 to x of 1/t, If on and both are integrable then ; and , Order, continuity, range, and the product, quotient, and reciprocal laws for the natural logarithm).
[F5] For the one-mode space with frequency and , and the weight operator is trace class with (Single-mode thermal trace (b), (c)).
[Divergence of the one-particle weights] By the definition of the mode list, for every , a constant strictly positive sequence that does not converge to ; by [F3] the series diverges, and since all its terms are positive its value is . This is (a).
[Divergent partial products and the finite- identity] By [F1] applied to the constant list, for every , . Since , these finite powers strictly increase. Put . By [F4] and the logarithm product and reciprocal laws, , so monotonicity of gives . For any , choose ; if , then , hence because the exponential is the increasing inverse of . Thus the partial products tend to , proving the quantitative bound in (b).
[Divergence of the grand-canonical weights, no trace] By step 1.1 the series is not finite, so the equivalence in [F1] gives ; by step 1.2 its finite partial sums are finite and increasing, consistently. By [F2], is not trace class and does not exist as a finite number. This is (c).
[The single-mode contrast] For with , [F5] gives and a trace-class weight operator with trace ; the same closed-form expression appears in step 1.2 with each of the infinitely many factors equal to it, and step 1.2 proves that these constant-factor products diverge by the quantitative bound . Thus the infinite multiplicity, not the value of the positive frequency, produces the divergence. This is (d).
[Conclusion and scope] Steps 1.1-1.2 prove (a) and (b), step 2.1 proves (c), and step 2.2 proves (d). The scope paragraph of the example records that no thermodynamic interpretation of , or the divergence is asserted. This completes the verification.
No automatic equilibration
Example
Assume the Axiom of Countable Choice and the Axiom of Choice. Let , , let be the one-mode Fock space with its complete orthonormal family , number operator and operators as in Fixed-mode number law and Number operator domain, and let the unitary group generated by the self-adjoint with spectral projection valued measure (Spectral theorem for unbounded self-adjoint operators (PVM form), A self-adjoint operator generates a strongly continuous unitary group). Put Then , for every , and with :
(a) ;
(b) the expectation equals ; consequently it tends to no limit as , since it equals at and at ;
(c) the state itself has no norm limit: , so for the two sequences of (b);
(d) in contrast, the weight operator and the density operator of Single-mode thermal trace are invariant under the same dynamics:
Thus a stationary equilibrium weight is available on this space, but the unitary dynamics of the non-stationary unit vector produces no convergence of the state or of the displayed expectation: equilibration is not a consequence of unitary evolution alone. No physical interpretation of , , or is asserted; in particular no thermal state is derived, and the example does not assert that any physical preparation oscillates.
Verification
Given: the one-mode Fock space with complete orthonormal family , the self-adjoint , its unitary group , the vector , the symmetric operator and the objects of Single-mode thermal trace.
[F1] is self-adjoint on , , , and the eigenvalues of on are exactly , each with eigenvector ; , and is dense (Number operator domain (a), (b), (d), Hilbert direct-sum construction (c)).
[F2] Oscillator coefficients (in particular for every , as required by these operator equalities): and for , (Fixed-mode number law (a)); is a complete orthonormal family of (Fixed-mode number law, Orthonormal families, complete orthonormal systems and Hilbert bases).
[F3] Spectral calculus: for a self-adjoint operator with PVM and , ; for bounded Borel the operator is bounded with ; if additionally then ; and is a strongly continuous unitary group expressed by the functional calculus (Spectral theorem for unbounded self-adjoint operators (PVM form), Unbounded Borel functional calculus: domains, products, spectral mapping, Projection valued measure, Integral of a measurable function against a projection-valued measure, A self-adjoint operator generates a strongly continuous unitary group).
[F4] A nonnegative measurable function has zero integral exactly when it vanishes almost everywhere w.r.t. the measure (A nonnegative measurable function has integral exactly when it vanishes almost everywhere).
[F6] is bounded self-adjoint, on the Fock sectors, , and (Single-mode thermal trace (a), (b), (d)).
[F7] Limits at : if a function has a limit then every sequence tending to has that limit (Limits at and , and infinite limits at a point).
[ on eigenstates] For the vector satisfies by [F1], hence ; by [F3] with , and , with a nonnegative integrand, so by [F4] the measure gives full mass to . Applying [F3] to the bounded Borel function and gives ; hence . For this gives and , so by linearity , which is (a); also .
[The expectation] By [F2], and , so maps into ; since by the operator equalities in [F2] and both domains are linear subspaces, both and lie in the finite-particle space, and is well-defined. With , orthonormality of and linearity in the first argument give .
[The stationary thermal weight] By [F6], is the direct sum of the scalars on the one-dimensional sectors of ; since the sector is spanned by , this says , so is diagonal in the complete orthonormal family . By step 1.1, for every , . Both and are bounded and agree on the complete orthonormal family, hence on its dense span, hence everywhere; dividing by the finite positive scalar gives . This is (d).
[Failure of convergence of the expectation and of the state] By step 2.1, equals at and at for every ; if a limit existed along , [F7] would give , a contradiction. This is (b). For two times , [F5] gives , which equals for , ; hence the family is not Cauchy at and has no limit in norm. This is (c).
[Conclusion and scope] Steps 1.1 and 2.1 establish the setting and the expectation , step 3.1 proves (b) and (c), and step 2.2 proves (d). The scope paragraph of the example records that no physical interpretation of the state, the coupling or the weights is asserted and that relaxation to equilibrium is not derived. This completes the verification.
Repeated-orbital fermion exclusion
Example
Slot convention. For , acts on as in Permutation sector projections on the n-fold tensor power. On one-based tuple positions use for . Conjugation by gives and ; thus the supplier's tensor action becomes . The parameters of and remain canonical zero-based permutations.
Assume the Axiom of Countable Choice and the Axiom of Choice. Let be a complex Hilbert space, let be its completed tensor powers with the unitaries and projections of Permutation sector projections on the n-fold tensor power. Fix and vectors , and let be the Slater vector of Slater direct and exchange calculation. This example verifies concretely that:
(a) for every the antisymmetrised two-particle tensor vanishes, because the canonical transposition of the two tensor factors satisfies and ;
(b) consequently the Slater vector with a repeated orbital is the zero vector, and the norm-one conclusion of Slater direct and exchange calculation (a) does not apply to the degenerate list : orthonormality of is an essential hypothesis, not a convenience; for orthonormal one has ;
(c) exclusion is a property of the state and not only of basis labels: for with orthonormal basis and the non-basis vector the antisymmetric part still vanishes. Indeed , and annihilates the two diagonal tensors while exchanging the two crossed tensors with opposite sign, so ;
(d) in the actual tensor space , the two-particle antisymmetric sector contains no nonzero vector of the form : every repeated-orbital projection is zero, and zero belongs to this sector as it does to every linear subspace. Thus a nonvanishing antisymmetric two-particle vector cannot be built from two copies of the same one-particle vector. This sector is distinct from the symmetric two-particle sector of the bosonic in Hilbert direct-sum construction.
The antisymmetric sector and its projection are mathematical objects; as recorded in the cited suppliers, selecting this sector for a species is a postulate and no spin-statistics statement is proved here.
Verification
Given: the complex Hilbert space , its completed tensor powers , the permutation unitaries and the projections , the transposition , the vector and the orthonormal family .
[F1] For every there is a unique unitary with , ; for and the transposition one has and . Moreover , and (Permutation sector projections on the n-fold tensor power (a), (b), Hilbert tensor construction: inner product, completion and product bases).
[F2] , and whenever are orthonormal; for the two summands coincide, so the alternating sum vanishes (Slater direct and exchange calculation (a), Orthonormal families, complete orthonormal systems and Hilbert bases).
[F3] The actual two-particle antisymmetric sector is , a closed linear subspace and hence containing zero (Permutation sector projections on the n-fold tensor power (b)). The source is the symmetric bosonic direct sum, whose two-particle sector is , not the antisymmetric sector (Hilbert direct-sum construction).
[The two-particle exclusion] For the swap identity of [F1] gives . This is (a).
[Slater vector with repeated orbital] By [F2] with , ; equivalently by step 1.1. For orthonormal , [F2] gives , so the hypothesis of pairwise orthonormal orbitals in [F2] cannot be dropped. This is (b).
[Superposition check] Let . Bilinearity of the tensor product gives . By [F1], fixes and and interchanges with ; hence , in agreement with step 1.1. This is (c).
[Consequence in the antisymmetric sector] If then (the tensor product of nonzero vectors has norm ), while step 1.1 gives ; so no nonzero two-particle antisymmetric vector arises by antisymmetrising . By [F3] this is a statement about the sector of ; the zero projection belongs to that linear sector, but no nonzero vector of that form exists. The bosonic has the distinct symmetric sector of [F3]. This is (d).
[Conclusion and scope] Steps 1.1 and 2.1 prove (a) and (b), step 2.2 proves (c), and step 2.3 proves (d). The scope paragraph of the example records that the symmetric/antisymmetric sector assignment is a postulate and that no spin-statistics statement is proved. This completes the verification.
Sources
- F. H. L. Essler, Advanced Quantum Theory (Oxford lecture notes, 2017/18), Sections 1.2 and 4.1 pp. 5-6, 25 (Fock-space occupation numbers; ideal Bose gas partition function)
- I. Burmistrov and A. Lunkin, Lecture Notes on Statistical Mechanics (HSE, 2023), Sections 1.1.2-1.1.6 pp. 12-18 (Gibbs distribution, entropy and systems with an arbitrary number of particles)
- I. Burmistrov and A. Lunkin, Lecture Notes on Statistical Mechanics (HSE, 2023), Sections 1.1.1-1.1.3 pp. 12-14 (density matrix, Gibbs distribution, entropy; relaxation to equilibrium is an additional assumption)
- G. Teschl, Mathematical Methods in Quantum Mechanics, 1st edition 2009, Sections 3.1 and 5.1 (the spectral theorem; Stone's theorem and unitary dynamics)
- F. H. L. Essler, Advanced Quantum Theory (Oxford lecture notes, 2017/18), Sections 1.1-1.2 pp. 1-6 (many-particle antisymmetric states and Pauli exclusion)
- S. Pratt, Lecture Notes on Quantum Mechanics (Michigan State University, PHY 851/852; retrieved via the Internet Archive snapshot of 2024-04-21), Chapter 11 Sections 11.1-11.3 pp. 161-168 (spin statistics, multi-particle symmetrization and Slater determinants)