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Faithful scalar-kernel detailed balance gives a relaxation gap

Statement

Let d≥1, and let G=K+D and the faithful density matrix σ satisfy Specified finite GNS detailed balance, with ker⁡D=CI. Write M0={A∈Md(C):Tr⁡(σA)=0}. If d>1, the restriction D∣M0 has only strictly negative eigenvalues. Define

γ:=min⁡{−λ:λ∈spec⁡(D∣M0)}>0.

Then for every A∈M0 and t≥0,

∥etGA∥σ≤e−γt∥A∥σ.

For every density matrix ρ, let ρt=etLρ, where L is the Schrödinger trace-dual generator. Then

∥ρt−σ∥1≤∥σ−1/2(ρ−σ)∥2e−γt.

Here ∥X∥1=Tr⁡X∗X and ∥X∥2=(Tr⁡X∗X)1/2. For centered A,B∈M0, the correlation t↦⟨etGA,B⟩σ is absolutely integrable. Also

Γ(A):=Re⁡∫0∞⟨etGA,A⟩σ dt=Re⁡⟨(−G∣M0)−1A,A⟩σ≥0.

For d=1, M0={0}, ρ=σ, and all centered and relaxation claims are trivial; no γ is defined. The units of γ are seconds−1. These are finite-dimensional conditional model results; they assert no infinite-dimensional bath limit.

Facts & Assumptions

Given: The finite observable generator G=K+D, faithful density σ, self-adjoint dissipator D, [Hs,σ]=0, and ker⁡D=CI.

[F1]

Specified finite GNS detailed balance: D(I)=0, D is self-adjoint for ⟨A,B⟩σ=Tr⁡(σB∗A), and K(A)=i[Hs,A]/ℏ with [Hs,σ]=0.

[F2]

Finite GKSL generates CPTP semigroups: the finite Schrödinger semigroup etL is completely positive and trace-preserving for t≥0.

[F3]

Channel duals and norm closure: the trace-dual of a finite channel is unital and completely positive.

[F4]

Schwarz and trace-norm channel contraction: a unital completely positive map satisfies the Schwarz inequality; its proof also establishes ∥X∥1=sup⁡∥A∥∞≤1∣Tr⁡(AX)∣.

[F5]

Finite matrix spectral and state calculus: finite self-adjoint endomorphisms have an orthonormal eigenbasis; the finite weighted inner product satisfies Cauchy–Schwarz.

[F6]

Finite matrix trace cyclicity and nondegeneracy: finite matrix traces are cyclic.

Proof

1.1F1F6givenalgebra

If d=1, then M0={0} and the only density matrix is σ, so all assertions are immediate. For the remainder assume d>1. By [F1], self-adjointness and D(I)=0 give Tr⁡(σD(A))=⟨D(A),I⟩σ=⟨A,D(I)⟩σ=0. For the Hamiltonian part, cyclicity [F6] and [Hs,σ]=0 give Tr⁡(σK(A))=0. Since G is the trace dual of L, differentiating Tr⁡(σetGA) now shows it is constant. Applying the same calculation with K=0 shows Tr⁡(σetDA)=Tr⁡(σA). Thus σ is stationary for both dual semigroups.

2.1F1F2F3F4F6step 1.1algebra

Let LD(X)=∑j(LjXLj∗−12{Lj∗Lj,X}), the Schrödinger GKSL generator with zero Hamiltonian and the same jump matrices. The finite trace calculation in [F1], [F6] shows its trace dual is D. Applying [F2] to LD and [F3] to its channel semigroup makes etD unital and completely positive. The Schwarz inequality [F4] and stationarity from step 1.1 give

∥etDA∥σ2=Tr⁡(σ(etDA)∗etDA)≤Tr⁡(σetD(A∗A))=∥A∥σ2.

Differentiating at t=0 yields Re⁡⟨D(A),A⟩σ≤0; self-adjointness in [F1] makes this quantity real.

3.1givenF1F5step 2.1algebra

The subspace M0 is the orthogonal complement of CI, and [F1] gives D(M0)⊆M0. The finite-dimensional spectral theorem [F5] applies to the self-adjoint endomorphism D on (Md,⟨⋅,⋅⟩σ). Step 2.1 makes all eigenvalues nonpositive; ker⁡D=CI excludes zero on M0. Because d>1, M0≠{0}, so its finite nonempty list of eigenvalues has maximum −γ<0, and ⟨D(A),A⟩σ≤−γ∥A∥σ2.

4.1givenF1F5F6step 1.1step 3.1algebra

By [F6] and [Hs,σ]=0, K is anti-self-adjoint for ⟨⋅,⋅⟩σ. Both K and D preserve M0: for D this follows from step 1.1, and for K from the same trace-cyclicity calculation. For At=etGA with centered A, differentiating gives

ddt∥At∥σ2=2Re⁡⟨G(At),At⟩σ=2⟨D(At),At⟩σ≤−2γ∥At∥σ2.

Thus e2γt∥At∥σ2 is nonincreasing, proving the asserted decay. Cauchy–Schwarz [F5] then bounds each centered correlation by e−γt∥A∥σ∥B∥σ, an integrable function.

5.1step 4.1algebra

The decay in step 4.1 makes Y:=∫0∞etGA dt converge in the finite-dimensional space M0. Differentiating etGA and integrating gives −GY=A. If GZ=0 for centered Z, then step 4.1 gives ∥Z∥σ=∥etGZ∥σ≤e−γt∥Z∥σ, so Z=0; hence −G∣M0 is invertible and Y=(−G∣M0)−1A.

6.1F1step 3.1step 5.1algebra

Let Y be as in step 5.1. Then Γ(A)=Re⁡⟨Y,−G(Y)⟩σ. The anti-self-adjoint K contributes zero real part, while step 3.1 gives ⟨Y,−D(Y)⟩σ≥γ∥Y∥σ2≥0. Therefore Γ(A)≥0.

7.1F1F4F5F6step 1.1step 4.1algebra∎

Let X=ρ−σ=X∗, and take any A with ∥A∥∞≤1. Set A0=A−Tr⁡(σA)I. Stationarity and trace duality give Tr⁡((ρt−σ)A)=Tr⁡(XetGA0). By cyclicity [F6], the trace-norm dual formula [F4] applies to this product order. Put C=etGA0. Since Tr⁡(XC)=Tr⁡(CX)=Tr⁡((Cσ1/2)(σ−1/2X)), the Hilbert–Schmidt trace inequality ∣Tr⁡(UV)∣≤∥U∥2∥V∥2 yields

∣Tr⁡(XetGA0)∣≤∥σ−1/2X∥2 ∥etGA0∥σ≤∥σ−1/2X∥2e−γt∥A0∥σ.

The identity ∥A0∥σ2=Tr⁡(σA∗A)−∣Tr⁡(σA)∣2≤∥A∥∞2≤1 gives a bound independent of A. Taking the supremum in [F4] proves the stated trace-norm relaxation estimate.

Remarks

The proof uses only finite matrices. In particular, the decay of etG follows from the dissipator's gap even when K and D do not commute. The correlation integral is a model coefficient, not a measured transport quantity.

Depends on

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