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Thermal occupation means of the declared free-mode models: Bose and Fermi factors, product convergence and dilute remainders

Physical scope

The declared free-mode thermal models of the pair: a single bosonic mode with energy operator epsilon N on the one-mode Fock space, a single fermionic orbital with two-dimensional occupation space and grand-canonical shift, and countably many independent modes with positive energies, each equipped with the adopted canonical preparation at assigned temperature. The theorem records the model's thermal occupation means, the partition-product convergence criterion and the dilute remainders; it asserts no thermodynamic limit, no continuum density of states, no Bose-Einstein condensation, no measured occupation and no thermalisation of any sample.

Statement

Adopt the canonical equilibrium-ensemble postulate The canonical equilibrium-ensemble assumption: the Gibbs preparation of a declared model at assigned temperature for the mode models declared below, the state and probability postulates P1, P2 (State and composition postulate P1: Hilbert spaces, preparations and composite systems, Observable and probability postulate P2: self-adjoint observables, spectral probability and finite unsharp outcomes) in the readings of Assigned sharp observables and the outcome law of the framework and Mean, second moment and variance of an assigned observable in a preparation, and the identical-particle and spin postulate P6 (Identical-particle and spin assignments P6: permutation sectors and finite-spin representations); assume the Axiom of Countable Choice and the Axiom of Choice (The Axiom of Countable Choice (ACω), The Axiom of Choice). Temperatures are assigned as in Entropy, the Boltzmann constant and the free-energy functional of the declared finite-sector model, so that β=1/(kBT) in J−1. Declare the occupation readouts as assigned sharp observables (N,1) and (N−,1), with unit particle-count, which is dimensionless. The total particle-number operator N in the countable-mode reading has the same unit; every occupation mean and higher number moment below is read in the corresponding dimensionless count unit. Then:

(a) single bosonic mode: let F(C) be the one-mode Fock space with number operator N and orthonormal number basis (en) (Fixed-mode number law, Number operator domain), let ε>0 and let the model declare the energy operator H:=εN on F(C); the model's canonical preparation at temperature T is ρβ=e−βH/Z with Z=(1−e−βε)−1, the number readout N is an assigned sharp observable with finite thermal mean ⟨N⟩β=1eβε−1=1eε/(kBT)−1, and all moments ⟨Nk⟩β, k≥1, are finite;

(b) single fermionic orbital and grand-canonical shift: on h=C2 with occupation operator N− and ε1,μ∈R, the model's canonical (grand-canonical) preparation F=Z−1∑k=01e−β(ε1−μ)kTuk,uk has Z=1+e−β(ε1−μ), tr⁡F=1, and occupation mean ⟨N−⟩=1eβ(ε1−μ)+1; the same formula is the model's thermal mean when μ=0 and ε1>0;

(c) countably many independent modes: let (εj)j≥1⊆(0,∞) and μ∈R, and let the model declare the free-mode energies εj (one mode case of clause (a)) with the product reading of Countable-mode product criterion; then the bosonic product partition is finite exactly when ∑je−βεj<∞ and μ<inf⁡jεj, and the fermionic product partition is finite exactly when ∑je−βεj<∞; in the finite cases the products equal ∏j(1−e−β(εj−μ))−1 and ∏j(1+e−β(εj−μ)) respectively;

(d) dilute remainders: for q=e−β(ε−μ) the model's occupation means satisfy the exact identities q1−q=q+q21−q(bosonic, 0<q<1),q1+q=q−q21+q(fermionic, q>0), so both differ from q by at most q2/(1−q) and q2/(1+q) respectively;

(e) scope: clauses (a)-(d) are conditional statements about the declared mode models together with the adopted ensemble assignment; they assert no thermodynamic limit, no continuum of radiation modes, no Bose-Einstein condensation, no measured occupation number, and no thermalisation of a sample. All numerical equalities are exact identities of the declared finite-mode (or product) models at the assigned temperature.

Facts & Assumptions

Given: the mode models of the statement with their energies, the assigned temperature T and inverse temperature β=1/(kBT), and the adopted canonical preparations.

[F1]

One-mode bosonic calculation. For ω>0 and β>0, on the one-mode Fock space with number operator N and orthonormal basis (en), the bounded operator Gβen=e−βωnen is positive with Z(β)=tr⁡Gβ=(1−e−βω)−1, ρβ=Gβ/Z(β) is a density operator, ⟨N⟩β=1/(eβω−1), and ∑nnke−βωn<∞ for every k≥1 (Single-mode thermal trace clauses (a)-(d)).

[F2]

Fermionic and grand-canonical formulas. For β>0, (εj)⊆(0,∞) and μ∈R, with qj=e−β(εj−μ): the two-dimensional occupation operator N− on C2 has Z=1+e−β(ε1−μ) and mean occupancy 1/(eβ(ε1−μ)+1); the products ZB=sup⁡N∏j∈N(1−qj)−1 and ZF=sup⁡N∏j∈N(1+qj) are finite exactly under the stated summability and positivity conditions; and the single-mode dilute identities and remainder bounds hold, all as statements about diagonal weights (Fermion and dilute grand-canonical formulas clauses (a)-(c)).

[F3]

Countable-mode product criterion. For a separable H with countable complete orthonormal family (ej) and weights e−βλI over finite multisets, the diagonal operator Dβ is trace class exactly when ∑je−βεj<∞, with trace ∏j(1−e−βεj)−1 in the finite case (Countable-mode product criterion clauses (b), (d), (e)).

[F4]

Observable reading and moments. An assigned sharp observable has outcome law μρA(B)=tr⁡(ρEA(B)), and its mean in a pure or mixed preparation is the corresponding spectral sum when finite; the number operator N is self-adjoint on its domain with Nen=nen (Assigned sharp observables and the outcome law of the framework, Mean, second moment and variance of an assigned observable in a preparation, Number operator domain, Density operators and scalar spectral probability).

[F5]

The finite-particle bosonic and fermionic occupation bases for a supplied countable mode basis are constructed in Fixed-particle-number occupation bases and the countable-mode partition criterion (a); the vacuum is the scalar degree-zero sector of Hilbert direct-sum construction. On a supplied countable orthonormal basis, arbitrary real diagonal weights define a self-adjoint operator on its exact squared-weight domain, with finite coordinate sums as a graph core (Diagonal adjoint and graph-core lemma (a)-(e)).

Proof

technique · direct; instantiate the supplied one-mode, fermionic and product calculations at the declared energies and read the occupation operators as assigned observables

Given: the data of the statement and [F1]-[F5].

1.1F1F4algebra

[The single bosonic mode] Apply [F1] with ω=ε: ρβ is the canonical preparation of the declared energy operator εN, the number readout N is self-adjoint with Nen=nen by [F4], and its thermal mean in ρβ equals the absolutely convergent sum ∑nnqn/∑nqn=1/(eβε−1) with q=e−βε; all higher moments are finite by [F1]. This proves (a).

1.2F2algebra

[The fermionic orbital and the shift] For the stated arbitrary real ε1,μ, direct evaluation in the two occupation vectors gives the unnormalized positive operator G=∑k=01qkTuk,uk with q=e−β(ε1−μ)>0 and tr⁡G=Z=1+q. Thus F=G/Z has trace one and occupation mean q/(1+q)=1/(eβ(ε1−μ)+1) with q=e−β(ε1−μ); for μ=0, ε1>0 this is the model's thermal mean at the declared energy ε1. This proves (b) and the identities of (d).

1.3F3F5constructalgebra

[The number-variable space and complete basis] Let H0 be the one-particle Hilbert space with supplied countable orthonormal basis (ej)j≥1 of [F3]. For either sign define H0σ=C and Fσ:={(ψN)N≥0:ψN∈HNσ, ∑N∥ψN∥2<∞} with inner product ∑N⟨ψN,φN⟩, whose absolute convergence follows from Cauchy-Schwarz applied to the two square-summable sector norm sequences as in the direct-sum construction of [F5], where the positive-degree sectors are those of [F5]. The plus space is the supplied bosonic direct sum. For the minus space, each coordinate of a Cauchy sequence converges in its closed Hilbert sector; bounded finite partial sums of squared norms put the coordinate limit in F−, and taking coordinate limits in the Cauchy bound, then the supremum over finite partial sums, proves convergence in the full norm. Thus it too is Hilbert; this is a local argument, not a fermionic clause attributed to the bosonic supplier. Embed each fixed-N basis of [F5] in coordinate N and add the unit vacuum in coordinate zero. Orthogonality holds between different degrees, and truncating degree tails then approximating in each of finitely many complete sector bases proves completeness of their union. Label this countable basis (bnσ) by Cσ:={n∈NN>0:n has finite support, nj≤1 if σ=−}, with ∣n∣=∑jnj; for minus use the Slater vector of the occupied subset. Enumerate these labels by finite integer sequences and apply the diagonal lemma of [F5].

2.1F2F4F5step 1.3algebra

[Exact generator and trace] On this basis define the self-adjoint diagonal H, N and G with respective eigenvalues En=∑jεjnj, ∣n∣ and gn=∑j(εj−μ)nj, each on its exact domain {∑nanbnσ:∑n∣wn∣2∣an∣2<∞} for the corresponding weight wn, by [F5]. The self-adjoint G is the closure of the common finite-occupation action H−μN, since finite sums are its graph core; it is not an assertion about the domain of a formal unbounded subtraction. In the finite bosonic-product case gn≥0. In the finite fermionic-product case summability gives εj→∞, so gn≥∑j:εj<μ(εj−μ)>−∞, the sum having finitely many terms. The coordinate spectral PVM is EG(B)∑nanbnσ=∑n1B(gn)anbnσ, and spectral integration gives the bounded positive e−βG with weights ∏jqjnj, where qj=e−β(εj−μ). Its extended positive trace is the nonnegative sum of these weights by the ensemble postulate. Restricting support to {1,…,M} gives ∏j=1M(1−qj)−1 for bosons with all qj<1, and ∏j=1M(1+qj) for fermions, by geometric summation or expansion of the finite binary product. These support sets exhaust Cσ, so the full sum is the increasing limit of those products; if a bosonic qj≥1, its one-mode subseries already diverges. [F2] now proves precisely the finiteness criteria in (c), including the bosonic strict chemical-potential condition. In each finite case the ensemble postulate identifies this sum with the ordinary trace of a trace-class operator and licenses normalization to a density. For each j, the same diagonal lemma defines the mode readout Nj with weights nj on its exact squared-weight domain. The normalized marginal of each mode is proportional to qjk, k≥0 for bosons and k∈{0,1} for fermions, by separating that mode in the same nonnegative sums; its mean is therefore the corresponding factor of [F2]. This proves (c) on the explicitly realized number-variable spaces.

3.1F4step 1.1step 1.2step 1.3step 2.1algebra

[Readings] In each case the occupation number is an assigned sharp observable by [F4], so the mean of its outcome law in the canonical preparation is the number computed in steps 1.1-1.3 and 2.1; the identification of the computed parameters with a physical temperature and chemical potential is the adopted assumption of the ensemble postulate, and no convergence statement beyond the displayed criteria is asserted. This gives the readings of (a)-(d).

4.1step 1.1step 1.2step 1.3step 2.1step 3.1∎

[Conclusion and scope] Steps 1.1-1.3, 2.1 and 3.1 prove (a)-(d). The argument is a finite-mode or product computation at assigned temperature; no thermodynamic limit, continuum of modes, condensation or measured occupation entered, which is (e).

Remarks

  • No continuum claim. The product criterion covers the declared countable discrete occupation bases only. These suppliers establish no continuum partition-trace result; such a model requires its own one-particle space, measure, self-adjoint energy realization and trace analysis.
  • The chemical potential. μ is an assigned model parameter in joules with its uncertainty; the bosonic condition εj−μ>0 is required for each geometric factor, while the fermionic factors are finite for every real μ.

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