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Thermal occupation means of the declared free-mode models: Bose and Fermi factors, product convergence and dilute remainders
The declared free-mode thermal models of the pair: a single bosonic mode with energy operator epsilon N on the one-mode Fock space, a single fermionic orbital with two-dimensional occupation space and grand-canonical shift, and countably many independent modes with positive energies, each equipped with the adopted canonical preparation at assigned temperature. The theorem records the model's thermal occupation means, the partition-product convergence criterion and the dilute remainders; it asserts no thermodynamic limit, no continuum density of states, no Bose-Einstein condensation, no measured occupation and no thermalisation of any sample.
Statement
Adopt the canonical equilibrium-ensemble postulate The canonical equilibrium-ensemble assumption: the Gibbs preparation of a declared model at assigned temperature for the mode models declared below, the state and probability postulates P1, P2 (State and composition postulate P1: Hilbert spaces, preparations and composite systems, Observable and probability postulate P2: self-adjoint observables, spectral probability and finite unsharp outcomes) in the readings of Assigned sharp observables and the outcome law of the framework and Mean, second moment and variance of an assigned observable in a preparation, and the identical-particle and spin postulate P6 (Identical-particle and spin assignments P6: permutation sectors and finite-spin representations); assume the Axiom of Countable Choice and the Axiom of Choice (The Axiom of Countable Choice (), The Axiom of Choice). Temperatures are assigned as in Entropy, the Boltzmann constant and the free-energy functional of the declared finite-sector model, so that in . Declare the occupation readouts as assigned sharp observables and , with unit particle-count, which is dimensionless. The total particle-number operator in the countable-mode reading has the same unit; every occupation mean and higher number moment below is read in the corresponding dimensionless count unit. Then:
(a) single bosonic mode: let be the one-mode Fock space with number operator and orthonormal number basis (Fixed-mode number law, Number operator domain), let and let the model declare the energy operator on ; the model's canonical preparation at temperature is with , the number readout is an assigned sharp observable with finite thermal mean and all moments , , are finite;
(b) single fermionic orbital and grand-canonical shift: on with occupation operator and , the model's canonical (grand-canonical) preparation has , , and occupation mean the same formula is the model's thermal mean when and ;
(c) countably many independent modes: let and , and let the model declare the free-mode energies (one mode case of clause (a)) with the product reading of Countable-mode product criterion; then the bosonic product partition is finite exactly when and , and the fermionic product partition is finite exactly when ; in the finite cases the products equal and respectively;
(d) dilute remainders: for the model's occupation means satisfy the exact identities so both differ from by at most and respectively;
(e) scope: clauses (a)-(d) are conditional statements about the declared mode models together with the adopted ensemble assignment; they assert no thermodynamic limit, no continuum of radiation modes, no Bose-Einstein condensation, no measured occupation number, and no thermalisation of a sample. All numerical equalities are exact identities of the declared finite-mode (or product) models at the assigned temperature.
Facts & Assumptions
Given: the mode models of the statement with their energies, the assigned temperature and inverse temperature , and the adopted canonical preparations.
One-mode bosonic calculation. For and , on the one-mode Fock space with number operator and orthonormal basis , the bounded operator is positive with , is a density operator, , and for every (Single-mode thermal trace clauses (a)-(d)).
Fermionic and grand-canonical formulas. For , and , with : the two-dimensional occupation operator on has and mean occupancy ; the products and are finite exactly under the stated summability and positivity conditions; and the single-mode dilute identities and remainder bounds hold, all as statements about diagonal weights (Fermion and dilute grand-canonical formulas clauses (a)-(c)).
Countable-mode product criterion. For a separable with countable complete orthonormal family and weights over finite multisets, the diagonal operator is trace class exactly when , with trace in the finite case (Countable-mode product criterion clauses (b), (d), (e)).
Observable reading and moments. An assigned sharp observable has outcome law , and its mean in a pure or mixed preparation is the corresponding spectral sum when finite; the number operator is self-adjoint on its domain with (Assigned sharp observables and the outcome law of the framework, Mean, second moment and variance of an assigned observable in a preparation, Number operator domain, Density operators and scalar spectral probability).
The finite-particle bosonic and fermionic occupation bases for a supplied countable mode basis are constructed in Fixed-particle-number occupation bases and the countable-mode partition criterion (a); the vacuum is the scalar degree-zero sector of Hilbert direct-sum construction. On a supplied countable orthonormal basis, arbitrary real diagonal weights define a self-adjoint operator on its exact squared-weight domain, with finite coordinate sums as a graph core (Diagonal adjoint and graph-core lemma (a)-(e)).
Proof
Given: the data of the statement and [F1]-[F5].
[The single bosonic mode] Apply [F1] with : is the canonical preparation of the declared energy operator , the number readout is self-adjoint with by [F4], and its thermal mean in equals the absolutely convergent sum with ; all higher moments are finite by [F1]. This proves (a).
[The fermionic orbital and the shift] For the stated arbitrary real , direct evaluation in the two occupation vectors gives the unnormalized positive operator with and . Thus has trace one and occupation mean with ; for , this is the model's thermal mean at the declared energy . This proves (b) and the identities of (d).
[The number-variable space and complete basis] Let be the one-particle Hilbert space with supplied countable orthonormal basis of [F3]. For either sign define and with inner product , whose absolute convergence follows from Cauchy-Schwarz applied to the two square-summable sector norm sequences as in the direct-sum construction of [F5], where the positive-degree sectors are those of [F5]. The plus space is the supplied bosonic direct sum. For the minus space, each coordinate of a Cauchy sequence converges in its closed Hilbert sector; bounded finite partial sums of squared norms put the coordinate limit in , and taking coordinate limits in the Cauchy bound, then the supremum over finite partial sums, proves convergence in the full norm. Thus it too is Hilbert; this is a local argument, not a fermionic clause attributed to the bosonic supplier. Embed each fixed- basis of [F5] in coordinate and add the unit vacuum in coordinate zero. Orthogonality holds between different degrees, and truncating degree tails then approximating in each of finitely many complete sector bases proves completeness of their union. Label this countable basis by , with ; for minus use the Slater vector of the occupied subset. Enumerate these labels by finite integer sequences and apply the diagonal lemma of [F5].
[Exact generator and trace] On this basis define the self-adjoint diagonal , and with respective eigenvalues , and , each on its exact domain for the corresponding weight , by [F5]. The self-adjoint is the closure of the common finite-occupation action , since finite sums are its graph core; it is not an assertion about the domain of a formal unbounded subtraction. In the finite bosonic-product case . In the finite fermionic-product case summability gives , so , the sum having finitely many terms. The coordinate spectral PVM is , and spectral integration gives the bounded positive with weights , where . Its extended positive trace is the nonnegative sum of these weights by the ensemble postulate. Restricting support to gives for bosons with all , and for fermions, by geometric summation or expansion of the finite binary product. These support sets exhaust , so the full sum is the increasing limit of those products; if a bosonic , its one-mode subseries already diverges. [F2] now proves precisely the finiteness criteria in (c), including the bosonic strict chemical-potential condition. In each finite case the ensemble postulate identifies this sum with the ordinary trace of a trace-class operator and licenses normalization to a density. For each , the same diagonal lemma defines the mode readout with weights on its exact squared-weight domain. The normalized marginal of each mode is proportional to , for bosons and for fermions, by separating that mode in the same nonnegative sums; its mean is therefore the corresponding factor of [F2]. This proves (c) on the explicitly realized number-variable spaces.
[Readings] In each case the occupation number is an assigned sharp observable by [F4], so the mean of its outcome law in the canonical preparation is the number computed in steps 1.1-1.3 and 2.1; the identification of the computed parameters with a physical temperature and chemical potential is the adopted assumption of the ensemble postulate, and no convergence statement beyond the displayed criteria is asserted. This gives the readings of (a)-(d).
[Conclusion and scope] Steps 1.1-1.3, 2.1 and 3.1 prove (a)-(d). The argument is a finite-mode or product computation at assigned temperature; no thermodynamic limit, continuum of modes, condensation or measured occupation entered, which is (e).
Remarks
- No continuum claim. The product criterion covers the declared countable discrete occupation bases only. These suppliers establish no continuum partition-trace result; such a model requires its own one-particle space, measure, self-adjoint energy realization and trace analysis.
- The chemical potential. is an assigned model parameter in joules with its uncertainty; the bosonic condition is required for each geometric factor, while the fermionic factors are finite for every real .
Depends on
The canonical equilibrium-ensemble assumption: the Gibbs preparation of a declared model at assigned temperature
Entropy, the Boltzmann constant and the free-energy functional of the declared finite-sector model
Assigned sharp observables and the outcome law of the framework
Mean, second moment and variance of an assigned observable in a preparation
Dimensions, SI unit conventions and quantity types of the framework
State and composition postulate P1: Hilbert spaces, preparations and composite systems
Observable and probability postulate P2: self-adjoint observables, spectral probability and finite unsharp outcomes
Identical-particle and spin assignments P6: permutation sectors and finite-spin representations
Preparation and apparatus postulate P7: declared preparations, isolation and sampling assumptions
Single-mode thermal trace
Fermion and dilute grand-canonical formulas
Countable-mode product criterion
Number operator domain
Fixed-mode number law
Density operators and scalar spectral probability
The natural logarithm as the inverse of the exponential function
Hilbert space
The Axiom of Countable Choice ()
The Axiom of Choice
Fixed-particle-number occupation bases and the countable-mode partition criterion
Diagonal adjoint and graph-core lemma
Hilbert direct-sum construction
Dependency tree · 2 levels
Sources
- I. Burmistrov and A. Lunkin, Lecture Notes on Statistical Mechanics (HSE, January 10, 2023), Section 1.3.1 printed pages 24-27: the single-level and many-level grand-canonical partition functions for fermions and the Fermi-Dirac distribution; Section 1.4.1 printed pages 33-34: the geometric sums for one bosonic level and the Bose-Einstein distribution; Section 1.4.2 printed page 34: the canonical partition function for N bosons
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 10.1 printed pages 226-230 (PDF pages 234-238): single-particle states of a species and the counting of antisymmetric and symmetric configurations underlying the mode occupations