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Partial-wave cross-section convergence
Statement
Assume the Axiom of Countable Choice (The Axiom of Countable Choice ()). Let be real, bounded, central (invariant under rotations) and supported in , let , and let be the scattering amplitude of Stationary outgoing integral and flux. Then:
(a) depends only on , and its Legendre expansion converges in (and absolutely, since is smooth), where is a unit-modulus number determined by the regular radial solution normalized by and by the outgoing solution with : explicitly and with the phase shift defined modulo .
(b) , so , and the total cross section is the series converging because and the expansion in (a) is an orthogonal expansion.
(c) Resonance model. For the single-channel model with one has for real and ; substituting into (b) gives the corresponding single-channel cross section. This is a conditional model calculation, not a theorem that every potential has such a pole.
Facts & Assumptions
Given: Countable Choice; almost everywhere with real and for ; ; incident direction ; the stationary solution and amplitude of the cited stationary supplier. Set , where the prime denotes the radial derivative.
The stationary construction supplies the unique solving and its integral continuation , with , , and . This is uniqueness of the integral-equation construction; no uniqueness among all outgoing PDE solutions is imported. Its compact source ; outside , satisfies with the same order for the first radial derivative, and (Stationary outgoing integral and flux, Outgoing Fredholm invertibility).
The Rodrigues polynomials satisfy , have leading coefficient and obey (Legendre Rodrigues equation). Orthogonality and completeness of the associated angular harmonics follow from Associated Legendre function normalization, Weighted angular completeness and Sphere ONB.
Polar volume integration is (Polar coordinates decompose Lebesgue measure into r^{n-1} dr d sigma); smooth approximation in is available under CC (Compactly supported smooth functions are dense in W^{k,p}(R^n)). All radial equations below are distributional, equivalently with locally absolutely continuous function and derivative away from , and bounded measurable is sufficient (Integer-order Sobolev spaces and their norms).
Proof
(Angular normalization, the plane wave and smooth amplitude.) For a rotation fixing , let on . Rotation preserves the ball and Lebesgue measure, so is unitary. Substituting in the kernel integral and using and almost everywhere gives . Also . Thus , and invertibility in [F1] gives . Applying the same substitution to the integral continuation and the amplitude integral yields and . Only integral-equation uniqueness is used. Thus these functions depend on the angle only through . The amplitude is genuinely smooth without differentiating : the source is compactly supported and in , and every angular derivative of is bounded on , so differentiation under this integral gives derivatives of every order. Rodrigues integration by parts times gives ; the last integral follows from and by one integration by parts. Consequently . Define , , and recursively , for . Rodrigues integration by parts also gives : the resulting expression is , whose quotient by equals by induction using the displayed recurrence and integration by parts in . Therefore the orthogonal angular expansion of the plane wave is in for each fixed . In particular the normalization of , of the incident coefficients and of the spherical Bessel functions has been derived rather than imported from a Coulomb spectral transform.
(Regular solution for a bounded measurable radial potential.) For fixed set and seek . The equation is equivalent to . Its normalized regular solution is the Volterra equation . On every , the kernel has absolute value at most with , so the th iterated integral is bounded by . The resulting uniformly convergent series gives a continuous real solution, and applying the same estimate to differences proves uniqueness; solutions constructed on different finite intervals agree. Differentiating the integral gives , whence , as , and are locally absolutely continuous with the radial equation valid almost everywhere. Conversely a solution with has no integration constant in (a nonzero constant would make unbounded near zero), so it satisfies this Volterra equation. Near zero , and reduction of order gives an independent solution with leading nonzero term proportional to . Such a branch is incompatible with the local stationary domain: for its reduced coefficient is not in near zero, while for its unreduced coefficient has a nonzero term with radial derivative proportional to and is not locally . Thus every projected radial channel of the stationary solution is a multiple of this regular . Projection and the radial equation are justified on compact annuli by smooth approximation, the polar Laplacian identity and angular integration by parts; the angular eigenfunction identity follows with the negative derivative sign in [F2]. No derivative of or regularity stronger than boundedness has entered.
(Outgoing normalization and nonzero Wronskians.) Put and ; the superscript distinguishes this free solution from the potential coefficient . Their recurrence is . Differentiation shows that this sends to the same equation with replaced by . Starting with proves the spherical Bessel equation and the finite sine/cosine expansions , , with differentiated errors of the same order. Their -Wronskian is constant and has limit , hence equals . Define the outgoing solution exactly for by ; then and , while is the incoming solution and . Extend inward to every interval , , by its continuous Cauchy data at and the bounded-coefficient integral equation for the first-order radial system; its convergent successive-integration series provides existence and uniqueness. At jumps of , function and derivative remain continuous and locally absolutely continuous, so there is no unmatched interface term. For solutions of this equation the Wronskian has derivative zero almost everywhere. In the exterior write the real regular solution as , where , and set . This cannot vanish: it would imply and then by Cauchy uniqueness, contrary to its origin normalization. Therefore is well-defined and ; writing defines modulo . For , the Volterra regular solution is , since at zero from the integral formula in step 1.1. Here is real, so , verifying the free normalization and its sign.
(Matching one channel without exchanging infinite limits.) Define the zonal coefficient and the reduced coefficient . By step 1.2, is a multiple of ; outside the support it is a combination of . The incident reduced coefficient is . The scattered reduced coefficient is purely outgoing: projecting the uniform far-field and derivative bounds in [F1] gives and for this fixed ; since the incoming component would contribute , its coefficient is zero. Thus the total incoming coefficient remains . The outgoing/incoming ratio of the regular solution in step 2.1 is , so and . Comparing the fixed-channel far field and using yields , which is the claimed Legendre coefficient. This uses no unproved global radial spectral transform and no interchange between an infinite channel sum and a large- expansion.
(Convergence of the full series.) Completeness in [F2] first gives in . For , repeated integration by parts on the smooth compact sphere gives , hence by Cauchy–Schwarz and the norm computed in step 1.1. All these derivatives exist by the compact-source differentiation argument there; no smoothness of is required. Also for : the finite-binomial expansion of is the Rodrigues polynomial , while the modulus of the integrand is at most one. Choosing therefore gives , including the finite term. The series is consequently absolutely and uniformly convergent, and its limit agrees with the expansion and hence everywhere with the smooth amplitude. With step 3.1 these coefficients give the complete expansion in (a).
(Cross section with the exact Legendre norm.) Orthogonality and Parseval give . The factor is , because the azimuthal integral multiplies the Legendre norm . Since , this is also . Both series converge by the already established expansion. In the free test , every and the amplitude and total cross section both vanish. This proves (b) with the stated normalization.
(Retained resonance-model calculation.) For the conditional scalar model let and . Then has modulus one for every real and , so and . Substitution in the single-channel term of step 5.1 gives at the wave number assigned to that model energy (in the normalization , for ). The peak phase factor at is and the phase-shift factor reaches one; this is a conditional model calculation, with no assertion that a generic compact potential has this pole or that is defined by for negative . This retains (c) and completes the proof.
Depends on
Stationary outgoing integral and flux
Outgoing Fredholm invertibility
Legendre Rodrigues equation
Associated Legendre function normalization
Weighted angular completeness
Sphere ONB
Integer-order Sobolev spaces and their norms
A bounded linear operator between normed spaces
The operator norm as the least bound and as the unit-sphere or unit-ball supremum
Hilbert space
The Axiom of Countable Choice ()
Polar coordinates decompose Lebesgue measure into r^{n-1} dr d sigma
Compactly supported smooth functions are dense in W^{k,p}(R^n)
Dependency tree · 2 levels
Sources
- R. Fitzpatrick, Quantum Mechanics (University of Texas at Austin, author-hosted course text), Partial Waves pp. 213-216 and Determinants of Phase-Shifts pp. 216-219 (partial-wave expansion and phase-shift form of the cross section)
- G. Teschl, Mathematical Methods in Quantum Mechanics, 1st edition 2009, Chapter 12 pp. 245-256 (scattering amplitudes and phase shifts)