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Ensembles And Limits — Examples
1 · Prerequisites
- Absolute and Conditional Convergence; Rearrangement; Products
- Binary Operations, Monoids, Groups and Subgroups
- Compactness in Metric Spaces
- Completeness, Completion, and Uniform Continuity
- Construction of the Natural Numbers
- Construction of the Real Numbers via Cauchy Sequences
- Construction of the Real Numbers via Dedekind Cuts
- Continuity, IVT, EVT, and Uniform Continuity
- Countability and Uncountability
- Ensembles And Limits
- Finite Counting, Factorials and Binomial Coefficients
- Finite Probability Spaces and Random Variables
- Foundations of the Real Numbers for Analysis
- Limits of Real Functions
- limsup, liminf, and Subsequential Limits
- Metric Spaces
- Monotone Functions, Discontinuities, and Continuity Sets
- Monotone Sequences, Bolzano-Weierstrass, and Cauchy Completeness
- Order, Zorn's Lemma, and the Axiom of Choice
- Power Series and Real-Analytic Functions
- Properties of the Integral and the Working FTC
- Relations, Functions, and Quotients
- Roots, Rational Powers, and Classical Inequalities
- Sequences and Limits
- Sequences and Series of Functions; Uniform Convergence
- Series: Convergence and the Nonnegative Tests
- Suprema and Infima
- The Derivative and the Mean Value Theorems
- The Exponential Function
- The Logarithm and General Powers
- The Riemann Integral: Definition and Integrability
- The ZFC Axioms and the Basic Set Constructions
- Topology of ℝ
- Vector Spaces, Linear Subspaces, Span and Direct Sums
2 · Summary
These examples calculate one countable partition sum and three finite probability models. Each example checks definitions and conditional results on the A page; no measurement or physical preparation is asserted.
3 · Logical flowchart
4 · Definitions, postulates, theorems and proofs
None yet.
5 · Examples, experiments and counterexamples
A lower energy bound does not ensure a countable partition function
Facts & Assumptions
Given: As stated in the item.
Countable canonical model: is the extended nonnegative sum and a canonical probability law is defined only when .
The state set is and every state has zero energy and unit weight.
Example
Take , , and for every . The energy list is bounded below, but for every real , so this model has no normalized canonical law.
Verification
Given: The countable model in [F1] with the data in [A1].
Every summand is , so the first terms sum to for every ; their supremum is infinite.
Thus , which violates the finite-normalization condition in [F1]; no normalized canonical probabilities are defined.
Canonical mean and variance for a two-level system
Facts & Assumptions
Given: As stated in the item.
Countable canonical model: the finite partition sum and normalized state weights are defined as stated there.
Summable canonical differentiation: a finite energy list has the required local summable moment envelope on every compact parameter interval (each of finitely many terms is bounded there), so is the mean and is the variance.
, , , and .
Example
Let the state set be , with energies , , unit weights, and . Writing , the excited-state probability is , the mean energy is , and the energy variance is .
Verification
Given: The finite canonical model [F1] with data [A1].
Direct summation gives , hence and .
The finite weighted sum gives . The second centered moment is , which is positive because . The values also agree with the finite-list derivative identities of [F2].
A finite canonical law differs from a narrow-shell microcanonical law
Facts & Assumptions
Given: As stated in the item.
Countable canonical model: finite canonical probabilities are normalized exponential weights.
Summable canonical differentiation: if each compact interval admits a summable nonnegative majorant with for all and , then is positive, finite and on , and the canonical law is normalized.
The natural logarithm as the inverse of the exponential function identifies the exponential as a bijection from onto ; The exponential function is strictly increasing supplies its monotonicity.
The state set has energies and , the weights are one, , and . The finite-shell convention is the uniform law on states with energies in when the shell is nonempty.
Example
Let a two-state model have energies and , with unit state weights and . Adopt the finite-shell convention that the microcanonical law is uniform over states whose energy lies in when the shell is nonempty. For , that shell contains only the ground state, whereas the canonical law assigns the excited state probability . Thus the two finite-ensemble laws differ.
Verification
Given: The finite model and shell convention in [A1].
Take . For any nonempty compact interval , set and . These two finite nonnegative numbers are summable and bound the ground and excited terms in [F2], by [F3]. Thus the hypotheses of [F2] hold on . The canonical partition sum is ; its excited probability is , strictly positive because the exponential is positive.
The shell condition includes the state of energy zero and excludes the state of energy , since . Uniform weighting of this one-state shell gives excited probability zero, which differs from step 1.1.