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Interval models: discrete spectra, complete eigenbases, min-max bounds and nodal counts
The declared confined interval models of the pair with Dirichlet and separated Robin boundary conditions and a real continuous potential on the interval: self-adjointness of the assigned energy operators, discrete spectra with complete orthonormal eigenbases, the min-max comparison of the Dirichlet energies with the free box energies, simplicity of the eigenvalues, the nodal counts of the Dirichlet eigenfunctions, and the Robin eigenvalue condition. The statement is conditional on P1, P2, P4, P5, the declared boundary conditions and the cited mathematics; it asserts no laboratory realisation of a box or wall, no measured spectrum and no empirical result.
Statement
Adopt the state and composition postulate P1, the observable and probability postulate P2, the autonomous-dynamics postulate P4 and the kinematics and massive-particle model postulate P5 (State and composition postulate P1: Hilbert spaces, preparations and composite systems, Observable and probability postulate P2: self-adjoint observables, spectral probability and finite unsharp outcomes, Autonomous dynamics postulate P4: self-adjoint generators and unitary evolution, Kinematics and massive-particle model postulate P5: Newtonian frames and one-particle operators), read through the declared interval models The declared interval models with Dirichlet and Robin boundary conditions, and the declared zero-range (delta) model with , , , and assume the Axiom of Countable Choice and the Axiom of Choice (The Axiom of Countable Choice (), The Axiom of Choice). For a real write and put , so that the assigned energy operators of the definition satisfy and . Then:
(a) Dirichlet interval model. is an assigned sharp observable; is self-adjoint with compact resolvent and has a complete orthonormal family of eigenvectors. Its eigenvalues, listed with multiplicity, form a sequence with and , and no other spectral points; each eigenspace is one-dimensional, so the list is strict, , and the eigenvector belonging to has exactly zeros in . The min-max comparison holds. If , a complete orthonormal family of eigenpairs of is with , , a complete orthonormal family of . Every eigenvector at the displayed energy is a nonzero scalar multiple of the corresponding .
(b) Robin interval model. For real (the declared boundary parameters in ), is an assigned sharp observable; is self-adjoint with compact resolvent; it has a complete orthonormal eigenfamily, every eigenspace is one-dimensional, its spectrum consists exactly of its eigenvalues, which can be listed strictly increasingly as with , and its essential spectrum is empty. With and the unique solution of with , , one has and
(c) Scope. The statement is conditional on P1, P2, P4, P5, on the declared boundary conditions and on the cited mathematics. The boundary conditions and parameters are declared model assumptions; the eigenvalues are read in joules when and enter in the units of Dimensions, SI unit conventions and quantity types of the framework. No laboratory wall, box or surface is identified with the boundary conditions, no measured spectrum is asserted, and no completeness of any continuum or scattering object is claimed.
Facts & Assumptions
Given: The postulates P1, P2, P4, P5 and the choice hypotheses; , , ; real and ; real ; the operators and of The declared interval models with Dirichlet and Robin boundary conditions, and the declared zero-range (delta) model clauses (b), (c).
Dirichlet Laplacian and its bounded perturbations. Let be the Dirichlet Laplacian with and , and let . Then on is self-adjoint; is compact for every ; has a complete orthonormal family of eigenvectors; all eigenspaces are finite dimensional; the eigenvalues , listed with multiplicity, satisfy and ; and with one has for every (Bounded perturbations of the interval Dirichlet Laplacian clauses (a)-(c)).
Dirichlet eigenvalues, simplicity and nodes. An is a Dirichlet eigenvalue of when there is a nonzero with and pointwise; the Dirichlet eigenvalues are exactly the numbers of the strictly increasing sequence of Dirichlet eigenvalues, simplicity and the nodal theorem on an interval, each with one-dimensional eigenspace , the solution of , , ; and has exactly zeros in (Dirichlet eigenvalues, simplicity and the nodal theorem on an interval clauses (a), (b), (d)). The eigenvalue equation of the operator is, by its definition on , exactly the condition that be a nonzero Dirichlet eigenfunction: , , (Identification of the Dirichlet Laplacian with the sine diagonal operator, One-dimensional Sobolev spaces on intervals).
Free Dirichlet box. The diagonal operator of Diagonal adjoint and graph-core lemma with the sine family and eigenvalues equals the Dirichlet Laplacian on ; is self-adjoint and with eigenvector for ; is a complete orthonormal family of (Identification of the Dirichlet Laplacian with the sine diagonal operator, Completeness of the Dirichlet sine system on an interval).
Robin realisation. For real and , the operator with and is self-adjoint with compact resolvent; it has a complete orthonormal family of eigenvectors; every eigenspace is one-dimensional; the spectrum consists exactly of the eigenvalues, which can be listed strictly increasingly with and ; and for an eigenvalue the eigenvector is a nonzero multiple of the solution of , , , and , with (Green resolvent for separated Robin boundary conditions, Simple complete spectrum of the separated Robin realisation).
Compact resolvent and eigenbasis. For a self-adjoint with a compact resolvent at some real point, a complete orthonormal eigenfamily exists, every eigenspace is finite dimensional, and with ; moreover every resolvent is compact (Self-adjoint operators with compact resolvent: eigenbasis and discrete spectrum).
Positive scaling. For self-adjoint and , is self-adjoint; iff with ; compactness of resolvents is preserved; the eigenfamily of is an eigenfamily of with eigenvalues scaled by , and (Positive scalar multiples of self-adjoint operators: domains, resolvents, spectra and eigenbases clauses (a)-(d)).
Assigned observables. An assigned sharp observable is a densely defined self-adjoint operator together with a declared unit; the joule is the framework's energy unit (Assigned sharp observables and the outcome law of the framework clause (a), Dimensions, SI unit conventions and quantity types of the framework clause (d)4).
Proof
Given: The data and hypotheses of the statement and [F1]-[F7].
[Dirichlet operator after scaling] The mathematical operator is self-adjoint with compact resolvent, complete orthonormal eigenfamily and min-max eigenvalues , and with by [F1]. Since with , [F6] gives that is self-adjoint, that its resolvents are compact, that the same complete orthonormal family consists of eigenvectors with eigenvalues , and that with no other spectral points; moreover the eigenvectors of are exactly those of by clause (d) of [F6]. The min-max bound gives , since .
[Dirichlet eigenvalues are simple with the nodal counts] By [F2] the eigenvalue condition for is exactly the Dirichlet eigenvalue condition, so the eigenvalue set of is the strictly increasing sequence of the nodal theorem, each eigenspace being one-dimensional and the eigenvector for having zeros in . Therefore the min-max list of step 1.1 is this strict sequence, the eigenspaces of are one-dimensional, and the eigenvector belonging to has exactly zeros in .
[Robin model] By [F4] the mathematical operator is self-adjoint with compact resolvent, complete orthonormal eigenfamily, one-dimensional eigenspaces, strictly increasing eigenvalue list with and no essential spectrum, and eigenvalue condition with . Scaling by via [F6] preserves all these properties with eigenvalues , strictly increasing with , and the eigenvalue condition at is unchanged, giving (b); the compact-resolvent transfer used here is the general statement of [F5].
[Free box] If then and , so by [F3] the eigenvalues of are with eigenvectors ; after scaling by the eigenvalues of are with the same complete orthonormal eigenvectors , and the nodal count is read explicitly from the zeros , , of in .
[Observable reading and scope] Both and are densely defined, self-adjoint and read their spectral coordinate in joules by [F7], so each is an assigned sharp observable in the sense of clause (a) of the definition of assigned observables; no further physical reading of the eigenvalues is made, and the exclusions of (c) are those stated in clause (e) of The declared interval models with Dirichlet and Robin boundary conditions, and the declared zero-range (delta) model. This completes the proof of (a), (b) and (c).
Remarks
- Where the boundary conditions enter. The Dirichlet and Robin conditions are declared data of the interval models; the mathematics of this theorem begins with the operators and on their displayed domains, so the theorem transfers no property of the line model to the interval models and proves no limiting relation between Dirichlet and Robin conditions.
- The min-max bound is a comparison, not a measurement. It bounds the Dirichlet energies of the perturbed box by the free box energies with an additive constant ; the bound is stated for the energies in joules and involves no data.
Depends on
The declared interval models with Dirichlet and Robin boundary conditions, and the declared zero-range (delta) model
The declared one-dimensional line model: state space, Hamiltonian, bound states and generalized stationary solutions
State and composition postulate P1: Hilbert spaces, preparations and composite systems
Observable and probability postulate P2: self-adjoint observables, spectral probability and finite unsharp outcomes
Autonomous dynamics postulate P4: self-adjoint generators and unitary evolution
Kinematics and massive-particle model postulate P5: Newtonian frames and one-particle operators
Dimensions, SI unit conventions and quantity types of the framework
Assigned sharp observables and the outcome law of the framework
Assigned energy observable, unitary flow and the two pictures of autonomous evolution
Positive scalar multiples of self-adjoint operators: domains, resolvents, spectra and eigenbases
One-dimensional Sobolev spaces on intervals
Bounded perturbations of the interval Dirichlet Laplacian
Identification of the Dirichlet Laplacian with the sine diagonal operator
Dirichlet eigenvalues, simplicity and the nodal theorem on an interval
Simple complete spectrum of the separated Robin realisation
Green resolvent for separated Robin boundary conditions
Completeness of the Dirichlet sine system on an interval
Self-adjoint operators with compact resolvent: eigenbasis and discrete spectrum
Diagonal adjoint and graph-core lemma
The Axiom of Countable Choice ()
The Axiom of Choice
Dependency tree · 2 levels
Sources
- D. Tong, Quantum Mechanics (author-hosted lecture set), Section 2.1.2, printed pages 24-27 (PDF pages 27-30): the infinite potential well, its boundary conditions, eigenfunctions and quantized energies
- G. Teschl, Mathematical Methods in Quantum Mechanics, 1st edition 2009, Sections 9.1-9.2, printed pages 181-195 (PDF pages 193-207): Sturm-Liouville operators and separated self-adjoint boundary conditions (Theorem 9.6); Section 9.7, printed pages 214-220 (PDF pages 226-232): one-dimensional line operators, Sturm comparison and the full-line nodal count below the essential spectrum (Theorem 9.40 has line-domain hypotheses); PDF page = printed page + 12
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 5.1, printed pages 75-79 (PDF pages 83-87): the square potential well, its parity decomposition and its discrete bound states