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Selected stationary thermal equilibrium

1 · Prerequisites

2 · Summary

This page adopts one selected comoving stationary bath, derives its conditional Tolman–Ehrenfest temperature relation, and records two separate particle-exchange protocols before deriving the conditional Tolman–Klein relation. It also defines one finite, normalized classical Jüttner preparation from the exact mass-shell measure and partition supplier. The conclusions carry their stated connected-domain, positive-temperature, full-mass-shell or finite-cell hypotheses. They do not assert universal equilibrium, a generic curved-spacetime Gibbs/KMS state, collisional equilibration, or empirical material validity.

3 · Logical flowchart

4 · Definitions, postulates, theorems and proofs

PostulateStatement: Literature-sourcedProof: Not applicablejudge pass (gpt-6-luna)Open item page →

Selected stationary thermal equilibrium

Physical scope

One selected comoving bath on a connected smooth Lorentzian domain with a future timelike Killing field and a Killing inverse-temperature vector; no universal equilibrium existence, KMS state, or empirical thermometer law.

Postulate

On a nonempty connected open set O in the smooth, time-oriented Lorentzian four-manifold of Thermodynamics-GR fields, currents, reference normalization and units, select one smooth future timelike Killing field ξ and one smooth scalar T:O→(0,∞) in kelvins. Its dimensionless lapse and selected observer congruence are

Nξ:=−g(ξ,ξ)>0,u:=ξ/Nξ.

Thus g(u,u)=−1 and the physical four-velocity is cu in the length-coordinate convention x0=ct. A reference normalization of ξ is part of the selected model. The local temperature T is assigned to this comoving observer congruence; it is not a coordinate temperature or a value assigned to every observer.

Adopt the inverse-temperature vector

β:=ukBT,

where kB>0 is Boltzmann's constant in joules per kelvin, and assume that this field is Killing on O. In this item, a selected stationary thermal equilibrium means precisely this adopted bath, observer congruence, positive proper-temperature field, and Killing condition on β. The field NξT is not assumed constant here; its constancy is the conclusion of Conditional Tolman–Ehrenfest relation.

This is a model assumption, not a statement that every stationary geometry admits a thermal state or that every material realizes this bath. It asserts no complete Killing flow, KMS state, trace-class stress exponential, collision or thermalization law, Hawking or Unruh temperature, or empirical thermometer reading.

Physics theoremStatement: Literature-sourcedProof: AI-generatedjudge pass (gpt-6-luna)Open item page →

Conditional Tolman–Ehrenfest relation

Physical scope

Conditional redshift law for the local proper temperature of one selected connected stationary bath; no claim that arbitrary stationary flows or geometries are in equilibrium.

Statement

Use the connected stationary thermal carrier of Selected stationary thermal equilibrium on O. Let Nξ=−g(ξ,ξ)>0, u=ξ/Nξ, and β=u/(kBT) as there, and assume the postulated Killing condition on β. Then a positive constant TK exists such that

Nξ(x)T(x)=TKandβ=ξkBTK(x∈O).

In the same convention, ξ(Nξ)=0, the observer acceleration satisfies a=∇log⁡Nξ, the expansion and shear vanish, and

∇log⁡T=−a.

For any chosen reference event xref∈O, TK=Nξ(xref)T(xref). If the reference normalization has Nξ(xref)=1, then TK is the local temperature at that event. Rescaling ξ by a constant b>0 rescales Nξ and TK by b while leaving the local scalar T unchanged. The result is a conditional deduction from the selected physical postulate and the stated mathematical supplier; it is not a thermometer law for arbitrary observers or a KMS-existence theorem.

Facts & Assumptions

Given: A connected open Lorentzian domain, a smooth future timelike Killing field ξ, a smooth positive proper-temperature scalar T, the observer u=ξ/Nξ, and the adopted condition that β=u/(kBT) is Killing.

[A1]

Selected stationary thermal equilibrium adopts the selected comoving bath and the Killing condition on its inverse-temperature vector β. It does not assert that every geometry or material has such a bath.

[F1]

Killing temperature normalization and rigidity: for the exact connected stationary carrier and smooth fields above, β is Killing if and only if NξT=TK for one positive constant TK. Under this condition, β=ξ/(kBTK), ξ(Nξ)=0, a=∇log⁡Nξ, and θ=σab=0. Its current status is draft with a current Step 1 ready record; that record is authoring readiness only, not independent proof approval.

Proof

technique · Apply the exact field-normalization lemma to the adopted stationary carrier, then evaluate its constant at the supplied reference
1.1givenA1F1

By [A1], O is connected, ξ is future timelike Killing, T is smooth and strictly positive, and β=u/(kBT) is Killing. These are the carrier and field hypotheses in [F1].

2.1F1step 1.1algebra

Apply the forward implication of [F1] to the fields from step 1.1. It gives a positive constant TK on all of O with NξT=TK and β=ξ/(kBTK), along with ξ(Nξ)=0, a=∇log⁡Nξ, and zero expansion and shear. Since T=TK/Nξ and both fields are smooth and positive, differentiating its logarithm gives ∇log⁡T=−∇log⁡Nξ=−a.

3.1step 2.1algebra∎

Evaluating the constant identity of step 2.1 at any supplied xref yields TK=Nξ(xref)T(xref). If Nξ(xref)=1, this is the reference local temperature. Under ξ↦bξ, Nξ↦bNξ and therefore TK↦bTK; the formula T=TK/Nξ leaves T unchanged.

Remarks

The mathematical supplier is a conditional local field argument. The cited treatments provide independent context; none supplies an empirical observation or proves that a selected bath describes every material.

PostulateStatement: Literature-sourcedProof: Not applicableOpen item page →

Specified equilibrium particle exchange

Physical scope

A selected fixed-composition local material branch with either a finite independent-cell exchange model or a massive classical charged Liouville ansatz; charged conclusions require the stated global potential symmetry and reference.

Postulate

For a selected fixed-composition material branch, adopt the local state function and energy convention of Restricted local equilibrium parcel with adopted material state function and Rest fluid state, frame and geometric current definitions. In that state map, T>0 is the derivative of the supplied energy per marker with respect to entropy per marker, and the chemical potential is μ=H−Tσp in joules per marker. Rest energy stays in the energy convention used for μ and for any particle generator; a rest-energy subtraction made in a different convention must be tracked explicitly.

For particle exchange, select and declare one of these physical model protocols:

  • Finite-cell exchange. Supply r≥1 finitely many independent cells with open convex state domains Ui⊆R2, coordinates (Ei,ni), and concave entropy functions Si∈C1(Ui,R). Here Ei is in joules, ni is a continuous dimensionless particle-number coordinate, and Si is in joules per kelvin. Fix dimensionless lapse values Ni>0, a common charge q in coulombs, and potential values Φi in volts in a stated common reference. Put U=∏iUi and Stot=∑iSi. The adopted exchange conserves E=∑i(NiEi+qΦini) and N=∑ini. At a supplied feasible interior point x∗∈U, with these totals fixed and ∂EiSi(xi∗)>0 for every i, adopt the following equilibrium criterion: DStot(x∗)[h]=0 for every h=(δE1,δn1,…,δEr,δnr) satisfying ∑i(NiδEi+qΦiδni)=0 and ∑iδni=0. All such independent infinitesimal variations are admitted. Define 1/Ti=∂EiSi(xi∗) and μi/Ti=−∂niSi(xi∗), so Ti>0 is in kelvins and μi is in joules per particle. This criterion is an adopted condition on any selected equilibrium point, not a consequence of conservation, an existence assertion, or a relaxation law. Independent finite entropy-exchange equilibrium supplies its conditional consequences. Identification of these variables with another material state map is an additional model identification, not inferred here.

  • Charged kinetic exchange. On the selected stationary domain, supply a species of rest mass m>0, charge q, smooth local fields T>0 and μ, a global smooth real potential A with F=dA, and a smooth compensator Λξ satisfying LξA=dΛξ. Use the future massive shell, charged transport, and dimensionless exponential ansatz exactly as defined in Charged particle and Liouville data on a stationary Lorentzian domain. Adopt whole-shell stationarity LF,qf=0 as the exchange criterion. This is a model assumption on every future mass-shell momentum, not an assertion that collisions drive a gas to this ansatz.

The two protocols are separate model choices. This postulate does not derive either protocol from gravity, assert a global electrostatic potential when no single-valued symmetry compensator exists, establish a Gibbs state or material realization, or identify finite entropy variables with kinetic fields without an explicit model assumption.

Physics theoremStatement: Literature-sourcedProof: AI-generatedOpen item page →

Conditional Tolman–Klein relation

Physical scope

Conditional redshift relation in either the stated connected charged kinetic model or a finite independent-cell entropy-exchange model; no universal chemical law, chemical reaction, hydrostatic equation of state, or non-exact global potential.

Statement

Use the selected stationary carrier of Selected stationary thermal equilibrium and the declared exchange protocol of Specified equilibrium particle exchange. The following two conclusions are conditional on their respective model inputs.

Charged kinetic protocol. Let O be connected, let ξ be the selected future timelike Killing field, and set Nξ=−g(ξ,ξ)>0. For a species with m>0 and charge q, assume a global smooth potential symmetry LξA=dΛξ and define Φξ=−c(ιξA−Λξ) in volts. Suppose the smooth fields T>0 and μ define β=u/(kBT) and ζ=μ/(kBT), and the ansatz f=exp⁡(ζ+g(β,P)) is stationary under the charged transport of Charged particle and Liouville data on a stationary Lorentzian domain at every future massive-shell momentum. Then there are constants TK>0 and μK such that

NξT=TK,β=ξkBTK,Nξμ+qΦξ=μK.

Here μ and μK use the same full-energy convention as the conserved generator, including rest energy when that generator includes it. The gauge-compensated potential reference may be shifted by Φξ↦Φξ+C only with μK↦μK+qC.

Finite-cell exchange protocol. For r≥1 finitely many independent cells with C1 concave entropies Si(Ei,ni), positive lapse values Ni, common charge q, and the supplied potential values Φi, define 1/Ti=∂EiSi>0 and μi/Ti=−∂niSi at a supplied feasible interior point. If independent variations preserving ∑i(NiEi+qΦini) and ∑ini leave the total entropy stationary, then constants TK>0,μK exist with

NiTi=TK,Niμi+qΦi=μK(1≤i≤r).

That stationary point is a global entropy maximum on the feasible set when the cell entropies are concave, and it is unique if they are strictly concave. No existence or boundary attainment is asserted. In either branch, q=0 gives the neutral relation Nμ=μK (or Niμi=μK). The finite-cell symbols are not identified with the kinetic fields unless the model explicitly supplies that identification.

Facts & Assumptions

Given: The selected connected stationary carrier, one of the two declared exchange protocols, positive local temperatures, and either whole-future-shell charged stationarity or a feasible interior finite-cell stationary point under independent constraint-preserving variations.

[F1]

Selected stationary thermal equilibrium adopts one selected connected bath with future timelike Killing field ξ, Nξ>0, u=ξ/Nξ, and positive smooth proper temperature T. It adopts β=u/(kBT) Killing; it does not assert that every stationary geometry has such a bath.

[F2]

Specified equilibrium particle exchange separately adopts either whole-shell charged Liouville stationarity with a global potential compensator, or finite-cell exchange with the stated common constraints. The two protocols have no implicit cross-identification.

[F3]

Global electrochemical redshift from charged Liouville stationarity: on the exact connected smooth stationary Lorentzian carrier, if m>0, T>0, μ and A are smooth, the charged exponential ansatz is stationary on every future massive-shell momentum, and a global smooth Λξ satisfies LξA=dΛξ, then NT=TK, β=ξ/(kBTK), and Nμ+qΦξ=μK for constants TK>0,μK. The theorem carries only the explicit countable-choice assumption used by its geometry and integration suppliers; its current ready record is authoring readiness, not independent proof approval.

[F4]

Independent finite entropy-exchange equilibrium: for finitely many C1 concave entropy functions on open convex state domains, positive Ni, fixed q,Φi, a feasible interior point with ∂EiSi>0, and stationarity under every tangent vector preserving the two affine constraints, the entropy-gradient multiplier equations give NiTi=TK and Niμi+qΦi=μK. The supplier also proves global maximality under concavity and uniqueness under strict concavity, without an existence or attainment claim. It has no choice assumption.

[A1]

In the charged branch, m>0, F=dA for a global smooth potential, and the global compensator is required; a closed but non-exact ιξF is not enough for the global constant μK.

[A2]

In the finite-cell branch, r≥1 is finite, Ni>0, each Si∈C1(Ui) is concave on an open convex Ui⊂R2, the point is feasible and interior, every ∂EiSi>0, and variations are independent over ker⁡A for the two constraints.

Proof

technique · Apply each exact mathematical supplier only to the branch whose hypotheses match it
1.1givenF1F2F3A1

In the charged kinetic branch, [F1] supplies the connected stationary Lorentzian carrier and [A1] supplies the global smooth potential-compensator condition. By [F2], the selected model's T,μ define the exact exponential ansatz and its adopted equilibrium condition is LF,qf=0 on the whole future massive shell. Thus the charged branch matches the smooth-field, positive-mass, connected-domain, global-compensator, and full-shell hypotheses of [F3].

1.2givenF2F4A2

In the finite-cell branch, [A2] supplies exactly the finite state domains, differentiable concave entropies, positive energy derivatives, feasible interior point, and independent variations preserving the two affine constraints. By [F4], the temperatures and chemical potentials used here are defined from those entropy derivatives, so the branch matches the finite-dimensional theorem's inputs.

2.1F3step 1.1

Apply [F3] under the conditions checked in step 1.1. It gives global constants TK>0,μK with NξT=TK, β=ξ/(kBTK), and Nξμ+qΦξ=μK. The global compensation hypothesis is essential for the last constant; stationarity of F alone would only make ιξF closed.

2.2F4step 1.2

Apply [F4] to the point of step 1.2. It gives constants TK>0,μK satisfying NiTi=TK and Niμi+qΦi=μK for every cell. Its concavity and strict-concavity conclusions give the stated maximum and uniqueness qualifications; no stationary point is asserted to exist.

3.1F3F4step 2.2algebra∎

In the charged branch, replacing Φξ by Φξ+C changes the multiplier to μK+qC by the exact reference convention in [F3], so the relation and the exponent convention remain unchanged. In the finite branch, replacing every Φi by Φi+C adds qC∑ini to the energy constraint; since ∑ini is separately fixed, the feasible set is unchanged, and the displayed relation is preserved by μK↦μK+qC. Setting q=0 removes the potential term in either branch.

Remarks

The finite-cell maximum-entropy argument is finite-dimensional and assumes independent variations. The charged branch uses the exact global gauge-compensated energy and full-shell stationarity. Neither branch imports a mean-field stellar equation, a chemical-reaction law, a Gibbs/Euler equation of state, or a continuum equilibrium state.

DefinitionDefinition: Literature-sourcedProof: Not applicablejudge pass (gpt-6-luna)Open item page →

Defined classical Jüttner kinetic preparation

Physical scope

One massive classical species with prescribed positive density and temperature and a chosen observer congruence; an exactly normalized model preparation, not an assertion of collisional equilibration, material validity, or quantum statistics.

Definition

Let (M,g,N0) be the smooth time-oriented Lorentzian geometry of Thermodynamics-GR fields, currents, reference normalization and units, with signature (−,+,+,+) and physical length coordinates x0=ct. On an open region O⊆M, take a smooth observer congruence u whose value at each event is a future unit timelike observer in the sense of Observers, rest spaces and the spatial projection at an event and Observer congruences, their observer curves and adapted charts. The congruence is a field of observer directions, not an adapted coordinate chart or a tetrad. Let n:O→(0,∞) be a smooth proper number density in m−3 and T:O→(0,∞) a smooth proper-temperature scalar in kelvins. These fields are prescribed model data.

Choose one species with rest mass m>0 in kilograms, put M∗:=mc2>0 in joules, choose kB>0 in J K−1, and choose a reference action href>0 in J s. At an event x∈O, the future massive shell HM∗,x+ and its tetrad-independent measure dμM∗ are those of Canonical future massive mass-shell measure. For each P∈HM∗,x+, define the positive observer-measured energy

Eu(P):=−gx(P,ux)>0,α(x):=1kBT(x).

In any future orthonormal tetrad whose time axis is ux, write the spatial energy-momentum coordinates as p∈R3, so Eu(P)=M∗2+∣p∣2 and d3p=Eu(P) dμM∗(P). The spatial mechanical momentum is p/c; p itself is the spatial part of the energy four-vector P.

Define

ZM∗(α):=4πM∗2αK2(αM∗),Kj(z):=∫0∞e−zcosh⁡tcosh⁡(jt) dt(j=1,2).

and the observer-rest momentum probability law

dνu,x(p):=ZM∗(α(x))−1e−α(x)Eu(P) d3p.

Set

β:=ukBT,ζ:=log⁡ ⁣(nhref3c3ZM∗(α)),f(x,P):=eζ(x)+gx(β(x),P).

Finally define the model number current and stress-energy tensor by the convergent shell moments

Ja(x):=(href3c3)−1∫HM∗,x+Paf(x,P) dμM∗(P),Tab(x):=(href3c3)−1∫HM∗,x+PaPbf(x,P) dμM∗(P).

The mathematical suppliers Jüttner partition, probability, and perfect-fluid moments and Probability measures and probability spaces give 0<ZM∗<∞, show that νu,x has total mass one, and evaluate the current and stress moments:

Ja=nua,Tab=(ε+p)uaub+pgab,ε=n(M∗K1(αM∗)K2(αM∗)+3α),p=nα=nkBT.

Here ε and p are the exact moments of this one-species kinetic model. They are not automatically identified with an independently adopted material state function or stress tensor. The suppliers use the stated countable-choice strength ACω only; this definition adds no arbitrary-index choice principle. The scale href is a declared phase-space unit convention, not Planck's constant or a measured parameter.

This is an exact classical model definition. It does not claim that an actual material realizes this distribution, that collisions drive it to equilibrium, that the full field f solves a transport equation, or that any quantum-statistical or empirical law follows.

5 · Examples, experiments and counterexamples

None yet.

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