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Interacting Ensemble Geometry — Examples

1 · Prerequisites

2 · Summary

These leaf examples keep the ensemble qualifications concrete. A one-dimensional hard-rod calculation shows that retaining the forbidden-pair rule at zero inverse temperature does not produce an unrestricted Poisson gas. A uniform field throughout an ideal-gas volume changes the pressure exactly. Close packing can have zero canonical configuration volume, and a nonunique variational minimum permits multiple local accumulation points. The last example is an abstract conditional convex-mixture demonstration; it does not claim that a particular potential has a phase transition.

3 · Logical flowchart

4 · Definitions, postulates, theorems and proofs

None yet.

5 · Examples, experiments and counterexamples

ExampleConstruction: AI-adaptedVerification: AI-adaptedverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

A hard core remains at zero inverse temperature

Example

In one spatial dimension, let ϕ(x)=+∞ for ∣x∣<a and 0 otherwise, with a>0. On an interval [0,L], define the beta-zero weight by retaining the forbidden-pair exclusion as in Zero-inverse-temperature-parameter limit with forbidden pairs retained. If L>a, the two-particle canonical partition is Z(L,2;0)=(L−a)22, while the unrestricted ideal-gas value is L2/2. Thus the retained hard-core beta-zero ensemble is not the Poisson ideal gas.

Facts & Assumptions

Given: a>0, L>a, and the hard-admissibility convention.

[F1]

Superstable regular pair interactions and configurational ensemble notation: the canonical positional integral has normalization 1/N!.

[F2]

Zero-inverse-temperature-parameter limit with forbidden pairs retained: the grand beta-zero weight is zN1admissible. On the fixed-N sector the canonical coefficient is the weight divided by zN (equivalently, set z=1), namely 1admissible; hence it contains no activity factor. For the free interval here, admissibility means ∣x1−x2∣≥a.

Verification

Given: The one-dimensional hard-rod potential and the stated interval.

1.1F1F2F3F4algebra

On the ordered region x1<x2, allowed pairs satisfy x2≥x1+a, so their volume is ∫0L−a(L−x1−a) dx1=(L−a)2/2. The coordinate-swap map preserves product Lebesgue measure, so the region x2<x1 has the same volume; the diagonal has zero product measure. Thus the full labeled allowed volume is (L−a)2, and division by 2! gives Z(L,2;0)=(L−a)2/2.

2.1F1F2step 1.1algebra∎

Since 0<a<L, (L−a)2/2<L2/2, the unrestricted ideal-gas two-particle canonical term. The strict deficit is caused by the forbidden separation band and remains at beta zero by [F2].

CounterexampleConstruction: AI-adaptedVerification: AI-adaptedverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

A volume-sized external field changes ideal-gas pressure

Statement refuted

At fixed activity z>0 and inverse temperature β>0, adding any spatially constant one-particle external energy throughout a continuum ideal-gas region leaves the thermodynamic-limit log grand partition sum per volume unchanged, as would a negligible boundary perturbation.

Facts & Assumptions

Given: V>0, z>0, β>0, constant c∈R, and the 1/N!-normalized positional grand sum.

[A1]

The model has zero pair energy and assigns each N-point configuration external energy cN.

Counterexample

Given: V>0, z>0, β>0, constant c∈R, and the 1/N!-normalized positional grand sum.

For the continuum ideal gas in a bounded measurable region Ω of volume V, use activity z>0, inverse temperature β>0, and no pair interaction. Add a constant external one-particle energy c throughout Ω. This volume-sized field changes the pressure per volume whenever c≠0, so it is not a negligible boundary perturbation.

1.1givenA1F1F2algebra

The N-particle term without the field is zNVN/N!, by the product volume [F1] and the 1/N! convention [given]. Summing over N≥0 gives Ξ0=∑N(zV)N/N!=ezV by [F2].

2.1givenA1F2step 1.1algebra∎

With the field, each term is multiplied by e−βcN, so Ξc=∑N(ze−βcV)N/N!=eze−βcV by [F2]. Therefore V−1log⁡Ξ0=z and V−1log⁡Ξc=ze−βc. If c≠0, these differ because z,β>0.

ExampleConstruction: AI-adaptedVerification: AI-adaptedverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

The close-packing endpoint can have zero canonical weight

Example

In one dimension, let the pair potential be infinite when the separation is less than a>0, and zero otherwise. For N≥1 labeled rods in [0,L], with canonical positional normalization 1/N!, write S=L−(N−1)a. If S>0, translating the ordered coordinates by yi=xi−(i−1)a gives Z(L,N;β)=SNN!=(L−(N−1)a)NN!,β>0. If S=0, the allowed configuration set has zero Lebesgue measure and Z(L,N;β)=0. Along N→∞ with L=(N−1)a, the density N/L→1/a while every finite-volume partition is zero. Thus the thermodynamic close-packing endpoint is approached by a sequence of zero-weight finite systems; it is not realized by a positive canonical partition. The interior canonical limit theorem makes no assertion at that endpoint.

Facts & Assumptions

Given: Hard-core distance a>0 and inverse temperature β>0.

[F1]

Superstable regular pair interactions and configurational ensemble notation: the canonical positional partition integrates over labeled coordinates and divides by N!.

[F2]

Canonical free-cube limit at every interior attainable density: its canonical limit assertion is restricted to interior attainable densities.

[F4]

The factorial n! and the falling factorial nk‾, defined by recursion in N: the coordinate-order partition has N! permutation chambers and the canonical normalization divides by N!.

[F5]

Lebesgue outer measure, Lebesgue measurability and Lebesgue measure are unchanged by translation: translating a Lebesgue-measurable set preserves its Lebesgue measure.

Verification

Given: N≥1 and L≥(N−1)a.

1.1F1F3F4F5algebra

Order the coordinates 0≤x1<⋯<xN≤L. The exclusion constraints are xi+1−xi≥a. Apply the coordinatewise translation xi↦yi=xi−(i−1)a; each one-coordinate translation preserves Lebesgue measure [F5], so product measure is preserved. The ordered region becomes 0≤y1≤⋯≤yN≤S, where S=L−(N−1)a. The cube [0,S]N splits, up to equality sets of zero product measure, into N! coordinate-order regions. Product-measure uniqueness makes these permutation chambers equal in measure, so the ordered region has volume SN/N!. The full labeled allowed volume is N! times this, and canonical division by N! gives Z(L,N;β)=SN/N!.

2.1F1F2F3F4step 1.1algebra∎

If L=(N−1)a, then S=0 and the transformed region is a null set; its integral is zero. If L>(N−1)a, then S>0 and the ordered region has positive product volume. Thus the maximal-density endpoint does not carry a positive canonical partition at exact close packing; the interior-only theorem [F2] makes no contrary assertion.

ExampleConstruction: AI-adaptedVerification: AI-adaptedverified 2026-10-15 (gpt-6-luna, gpt-6.1-sol, and delegated Codex review/repair agents; see completed run evidence)Open item page →

Nonunique minimizers allow distinct local accumulation limits

Example

Suppose J(P)=I(P)+βΦ(P)−ρ(P)log⁡z has two distinct stationary minimizers P0≠P1 with equal finite value m. Every finite mixture Pθ=θP0+(1−θ)P1, 0≤θ≤1, also minimizes J. The sequence of stationary laws alternating between P0 and P1 has two distinct local accumulation points and does not converge. This conditional mathematical example shows why compactness alone yields minimizer-set accumulation; it does not assert a finite-volume ensemble realizes the sequence or that a particular continuum potential exhibits coexistence.

Facts & Assumptions

Given: Two distinct stationary minimizers P0,P1 with finite equal minimum m.

[F1]

Superstable regular continuum grand pressure and variational formula: Φ(P) is the limit of normalized finite-volume expected energies, and ρ(P) is expected unit-cell count.

[F2]

Specific Relative Entropy Density: I(P) is the large-cube limit of relative entropies against the unit-intensity Poisson reference.

[F3]

Relative Entropy Variational, Chain, and Conditioning Rules: relative entropy obeys the mixture-label chain rule and is nonnegative.

[F4]

Local-Tame Topology: τL tests every bounded measurable local observable.

Verification

Given: The assumptions above.

1.1F1F2F3algebra

Let P,R be stationary laws of finite specific entropy and let Pθ=θP+(1−θ)R. For a bounded cube G, the binary-label chain rule [F3] gives θD(PG∥QG)+(1−θ)D(RG∥QG)=D((Pθ)G∥QG)+I(S;XG), where S is the mixture label and XG the observed configuration. Since 0≤I(S;XG)≤H(S)<∞, divide by ∣G∣ and take the cube limit [F2]; H(S)/∣G∣→0, so I(Pθ)=θI(P)+(1−θ)I(R). The expectation defining ρ is affine. For finite energy densities, EPθHG=θEPHG+(1−θ)ERHG for every G; dividing by volume and taking limits gives affinity of Φ. Thus J is affine on finite mixtures of finite-J laws.

2.1givenF4step 1.1algebra∎

Applying step 1.1 to P0,P1 gives J(Pθ)=θJ(P0)+(1−θ)J(P1)=m, so every mixture is a minimizer. Put P2n=P0 and P2n+1=P1. The even and odd subsequences converge locally to P0 and P1. Since distinct laws differ on a bounded-region measurable event, its indicator is a bounded local test by [F4] with different expectations; the full sequence therefore has no τL limit. Both accumulation points are minimizers.

Sources