How statement and proof provenance work
The first chip identifies the source of the statement or construction; the second identifies the source of its local proof or verification.
- Literature-sourced: the exact statement appears in a cited source; only wording and notation differ.
- AI-adapted: a semantically identical restatement of literature-sourced material, modulo indexing, notation, and boundary cases adopted by the library.
- AI-generated: a genuinely novel statement formulated by AI, with no source for the claim itself.
These labels describe origin, not correctness: citations and verification chips remain separate evidence.
Qm Controlled Approximations
1 · Prerequisites
- Absolute and Conditional Convergence; Rearrangement; Products
- Absolute Continuity and the Sharp Fundamental Theorem of Calculus
- Algebraic Closure, Embeddings, and Separability
- Algebraic Extensions, Extension Degree, and Finite Fields
- Analyticity of Holomorphic Functions; Liouville and Morera
- Approximation and Compactness in C(K)
- Arc Length and Rectifiable Curves
- Areas of Elementary Plane Figures
- Banach Alaoglu Goldstine and Krein Milman
- Banach Algebras Spectrum and Holomorphic Functional Calculus
- Banach Valued Integration and the Radon Nikodym Property
- Banach-Space Differential Calculus and Banach Manifolds
- Bessel-Potential Completions and Real-Order Sobolev Spaces
- Binary Operations, Monoids, Groups and Subgroups
- Bounded Linear Operators and Quotient Spaces
- Bounded Variation and the Riemann–Stieltjes Integral
- Cm Math Central
- Cm Math Geometry
- Cm Math Rigid
- Compact Operators and Riesz Schauder Theory
- Compact Self Adjoint Hilbert Schmidt and Trace Class Operators
- Compactness
- Compactness in Metric Spaces
- Completeness, Completion, and Uniform Continuity
- Complex Differentiability and the Cauchy–Riemann Equations
- Complex Lp Spaces and Test-Function Conventions
- Complex Power Series and Analytic Functions
- Composition Series, the Jordan–Hölder Theorem and Solvable Groups
- Congruences, the Integers Modulo n and the Chinese Remainder Theorem
- Connectedness
- Construction of the Natural Numbers
- Construction of the Real Numbers via Cauchy Sequences
- Construction of the Real Numbers via Dedekind Cuts
- Continuity, IVT, EVT, and Uniform Continuity
- Continuous Functional Calculus for Self Adjoint and Normal Operators
- Contour Integration
- Convergence: Nets and Filters
- Convexity
- Cosets, Index and Lagrange's Theorem
- Countability and Uncountability
- Countability Axioms and Cardinal Functions
- Cyclic Groups and Direct Products
- Darboux, L'Hôpital, and Taylor's Theorem
- Density Separability and Convolution in Lᵖ
- Determinants of Matrices over a Commutative Ring
- Diagonalisation and the Minimal Polynomial
- Differentiation of Monotone Functions and the Vitali Covering Theorem
- Distributions Test Functions and Differentiation
- Divisibility, Euclidean Domains, Principal Ideal Domains and Unique Factorisation
- Divisibility, Greatest Common Divisors and Bézout's Identity
- Dual Spaces Adjoint Operators and Annihilators
- Dual Spaces, Bilinear and Quadratic Forms, and Sylvester's Law of Inertia
- Eigenvalues, Eigenvectors and the Characteristic Polynomial
- Euclidean Surface Measure, Divergence, and Green Identities
- Exterior Powers, Orientation and Hodge Duality
- Filters and Ultrafilters
- Finite Counting, Factorials and Binomial Coefficients
- Finite Dimensional Normed Spaces and Riesz Lemma
- Finite Probability and the Probabilistic Method
- Foundations of the Real Numbers for Analysis
- Fourier Multipliers and Sobolev Characterisations
- Fourier Transform Convolution and Approximate Identities
- Fredholm Elliptic Problems and the Elliptic Spectrum
- Free Modules, Exact Sequences, Projective and Injective Modules
- Fubini and Change of Variables
- Function Space Topologies and the Exponential Law
- Fundamental Trigonometric Identities
- Gaussian Elimination, Elementary Matrices and Reduced Row Echelon Form
- Gelfand Theory and Commutative C Star Algebras
- Goursat's Theorem and Cauchy's Theorem in a Convex Domain
- Group Actions, Orbits, Stabilisers and Cayley's Theorem
- Group Homomorphisms and the Isomorphism Theorems
- Harmonic Functions and Mean Values in Rn
- Hausdorff via the Diagonal
- Hereditary and Productive Behaviour of the Separation Axioms
- Hilbert Space Geometry and Riesz Representation
- Ideals, Quotient Rings and the Isomorphism Theorems for Rings
- Improper and Parameter-Dependent Multiple Integrals
- Improper Integrals
- Inner Product Spaces, Gram-Schmidt, Projections and Adjoints
- Interior and Boundary Sobolev Elliptic Regularity
- Lax--Milgram and Weak Elliptic Solutions
- Lebesgue Measure on Euclidean Space
- Lebesgue-Stieltjes Measures and Distribution Functions
- Limits of Real Functions
- limsup, liminf, and Subsequential Limits
- Line Integrals and the Gradient Theorem
- Linear Algebra Methods in Combinatorics
- Linear Independence, Bases and Dimension
- Linear Transformations, Rank-Nullity and Quotient Spaces
- Matrices, the Matrix of a Linear Map, and Change of Basis
- Measurable Functions and Simple Approximation
- Measures and Their Basic Properties
- Metric Spaces
- Mixed Partials, Taylor Formulae, and Extrema
- Modes of Convergence Egorov and Lusin
- Modules, Submodules, Quotient Modules and the Isomorphism Theorems
- Monotone Functions, Discontinuities, and Continuity Sets
- Monotone Sequences, Bolzano-Weierstrass, and Cauchy Completeness
- Normal Subgroups and Quotient Groups
- Normed and Banach Spaces
- Norming and Separation under Hahn–Banach
- Order, Zorn's Lemma, and the Axiom of Choice
- Orthonormal Bases, Parseval and Fourier Series
- Outer Measure and the Caratheodory Extension Theorem
- Partitions of Unity and Paracompactness
- pi: the Equivalent Characterizations
- Picard-Lindelöf and First-Order Ordinary Differential Equations
- Poisson Problems and Interior Harmonic Estimates
- Polynomial Rings, the Division Algorithm and Roots
- Power Series and Real-Analytic Functions
- Primes, Euclid's Lemma and the Fundamental Theorem of Arithmetic
- Product Measures and the Fubini Tonelli Theorems
- Projective Algebraic Sets Projective Morphisms and Cones
- Properties of the Integral and the Working FTC
- Qm Autonomous Dynamics
- Qm Central Potentials And Hydrogen
- Qm Framework And Quantities
- Qm Massive Particle Kinematics
- Qm Math Composites
- Qm Math Controlled Dynamics
- Qm Math Coulomb
- Qm Math Fock And Equilibrium
- Qm Math Intervals And Contacts
- Qm Math Magnetic And Detection
- Qm Math Orbital And Spin
- Qm Math Oscillator
- Qm Observables And Born Probabilities
- Qm One Dimensional Potentials
- Qm State Geometry
- Radon Measures and the Riesz Markov Kakutani Theorem
- Rees Modules Artin Rees and Hilbert Samuel Theory
- Reflexivity and Eberlein Smulian
- Regular Surfaces and Surface Integrals
- Relations, Functions, and Quotients
- Rings, Subrings, Integral Domains and Fields
- Rⁿ as a Normed Space; Vector-Valued Functions
- Roots, Rational Powers, and Classical Inequalities
- Schwartz Space and the Plancherel Theorem
- Separation Axioms: the Hierarchy
- Sequences and Limits
- Sequences and Series of Functions; Uniform Convergence
- Series: Convergence and the Nonnegative Tests
- Sigma Algebras and Borel Sets
- Signed and Complex Measures Hahn and Jordan
- Simple Field Extensions and the Construction of the Complex Numbers
- Sine, Cosine, and the Definition of Pi
- Smooth Approximation and Sobolev Extension
- Smooth Partitions of Unity and Exhaustions
- Sobolev Poincare and Morrey Inequalities
- Sobolev Traces and Zero Boundary Values
- Spectral Measures and Borel Functional Calculus
- Splitting Fields
- Stone–Weierstrass in General
- Strongly Continuous Semigroups and Hille Yosida
- Subspaces, Products, and Quotients
- Suprema and Infima
- Sylow's Theorems, p-Groups and Nilpotent Groups
- Symmetric Groups, Cycle Decomposition and the Sign Homomorphism
- Tempered Distributions and the Fourier Transform
- Tensor Products of Modules
- The Analytic Hahn Banach Theorem
- The Baire Principles of Functional Analysis
- The Branching Rule and the Young Graph
- The Cantor Set, Baire Category, and Measure Zero in ℝ
- The Complex Exponential and Euler's Formula
- The Derivative and the Mean Value Theorems
- The Determinant of a Linear Operator, Cofactors and Cramer's Rule
- The Divergence Theorem and Classical Stokes
- The Duality of Lᵖ and L^q
- The Exponential Function
- The Fundamental Theorem of Algebra
- The Fundamental Theorem of Finite Abelian Groups
- The Fundamental Theorems of Calculus
- The Galois Correspondence
- The Group Algebra and Representations of Finite Groups
- The Identity Theorem, the Maximum Principle and the Open Mapping Theorem
- The Inverse and Implicit Function Theorems
- The Inverse Function Theorem Completed
- The Lebesgue and Riemann Integrals Compared
- The Lebesgue Integral and the Convergence Theorems
- The Logarithm and General Powers
- The Lᵖ Spaces Holder Minkowski and Riesz Fischer
- The Maximal Function and Lebesgue Differentiation
- The Radon Nikodym Theorem and Lebesgue Decomposition
- The Riemann Integral in Rᵐ and Jordan Content
- The Riemann Integral: Definition and Integrability
- The Spectral Theorem, Positive Operators and Singular Value Decomposition
- The Topology of Euclidean Space
- The Total Derivative in ℝᵐ → ℝⁿ
- The Winding Number and the Global Cauchy Theorem
- The ZFC Axioms and the Basic Set Constructions
- Topological Spaces and Continuity
- Topology of ℝ
- Triangularisation, Generalised Eigenspaces and Jordan Canonical Form
- Unbounded Self Adjoint Operators and Stones Theorem
- Uniform Spaces: the Three Definitions
- Unitary Representations, Positive Type and GNS
- Urysohn's Lemma and the Tietze Extension Theorem
- Vector Spaces, Linear Subspaces, Span and Direct Sums
- Volumes of Elementary Solids and Solids of Revolution
- Weak and Weak Star Topologies
- Weak Derivatives and Sobolev Spaces
2 · Summary
This page declares the framework's controlled-approximation models and proves their conditional statements: the variational trial reading of an assigned energy observable, the bounded stationary perturbation of a gapped isolated label, and the semiclassical WKB regime of a one-dimensional stationary equation. It states every approximation with its controls: form domains and spectral lower bounds for the variational bounds, isolated gaps and quantitative smallness for perturbation theory, and smoothness, simple separated turning points and an explicit semiclassical parameter for the WKB regime.
The supporting mathematics comes first. Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent is the exact nondimensionalisation identity that transfers the physical line-model equation, forbidden-region exponent and allowed-region phase into the dimensionless equation carrying the semiclassical parameter . The declared variational trial reading: assigned energy observable, form domain, trial value, bottom and gap declares the variational reading: a self-adjoint energy observable bounded below, its form domain and form , the model bottom , a bottom gap and the discrete ladder below the essential spectrum. The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster declares the perturbed family with a bounded self-adjoint perturbation, the isolated finite-multiplicity label with its gap, the first-order operator and the followed perturbed label of the contour construction. The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading declares the WKB regime model: a compactly supported potential, the reference scales and dimensionless parameter , the turning-point vocabulary and the declared barrier transmission reading. Static finite-level electric-dipole coupling: compressed dipole of the declared two-body Coulomb model in a uniform field adopts the compressed finite-level dipole coupling of the declared Coulomb pair in a uniform static field, with the uncompressed linear potential explicitly excluded.
Variational trial bounds, gap-overlap control and the min-max characterisation of the declared model's discrete eigenvalues proves the trial lower bound , the gap-overlap control for trial values within of an isolated bottom, and the min-max characterisation of the model's discrete ladder. Nondegenerate stationary perturbation of a simple gapped label: first- and second-order coefficients and an explicit cubic remainder proves the existence, reality and analyticity of the followed label, the first- and second-order coefficients with the reduced inverse of the full complementary spectral subspace and the explicit cubic remainder bound. Degenerate stationary perturbation: the perturbed eigenvalues stay within 4 lambda^2 v^2/g of the first-order shifts, and no branch relaxation is asserted localises every perturbed eigenvalue within of and states explicitly that no branch selection or relaxation is deduced. WKB approximation on an allowed interval of the declared regime model: explicit Gronwall error bound away from turning points gives the Gronwall error of the WKB wave on an allowed interval away from turning points; Airy connection across a single simple turning point of the declared regime model, with envelope error control proves the Airy connection across a single simple turning point with envelope error control; and Separated smooth-barrier tunnelling: the declared transmission coefficient is exp(-2S/h) up to explicit small-h and barrier-thickness errors proves the separated smooth-barrier transmission law with its physical exponent. What the controlled-approximations page adopts, proves and does not claim: gaps, branch populations, turning points and the static-Stark limitation records what the page adopts, proves and excludes, including the static-Stark limitation and the absence of any empirical record on this page.
3 · Logical flowchart
4 · Definitions, postulates, theorems and proofs
Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent
Statement
Let and be real reference scales, let and be real, and define Let be a nonempty open interval, let , let , and let be a function. Then:
(a) is of class on and satisfies if and only if the function , , is of class on the open interval and satisfies
(b) if are points of , then each of the following identities holds under its indicated strict-sign hypothesis:
(i) if for every , then
(ii) if for every , then
All square roots here are the nonnegative real square roots of strictly positive numbers. Part (i) is the forbidden-region exponent identity; part (ii) is the allowed-region phase identity.
The identities are statements about the displayed functions and integrals only. The number is dimensionless because is in and is in ; no physical interpretation, no approximation and no error estimate is asserted here.
Facts & Assumptions
Given: the scales , the interval , the functions , the number , and the number . For part (b), also take points in satisfying the strict-sign hypothesis for the part being proved.
Chain rule. If is differentiable at and differentiable at , then is differentiable at with ; the statement applies to real and imaginary parts separately (The chain rule, in one line from Carathéodory: if is differentiable at and is differentiable at , then is differentiable at with , The derivative of at a point that is a limit point of , and differentiability on a set).
One-dimensional change of variables. If is and injective on a neighbourhood of with there, and is continuous on an interval containing , then (In one dimension the compact-Jordan formula is substitution over the unoriented image interval with the absolute derivative).
Proof
Given: the data of the statement and [F1]-[F2].
[Second derivatives under the substitution] Since is with derivative and inverse , the map is exactly when is, and by [F1] applied twice,
[The scale identity] From the definition of and , ,
[Forbidden-region exponent identity (b)(i)] On the function is and strictly increasing with derivative , and the integrand is continuous on because . By [F2] applied to , Dividing by and using gives (b)(i).
[Forward implication of (a)] Suppose is with on . By step 1.1, is on and by step 1.2. Multiplying by and bringing terms to the left gives on .
[Converse implication of (a)] Suppose conversely that is with on . By step 1.1, is on with ; substituting the assumed equation at gives the last equality by step 1.2.
[Allowed-region phase identity (b)(ii)] If instead on , then is continuous and real on . The same change of variables gives Division by and the same scale identity prove (b)(ii), with the nonnegative real square roots justified by the strict sign hypothesis.
Remarks
- Role of the lemma. The lemma is the exact bookkeeping that lets the dimensionless equation , in which the semiclassical parameter is explicit, be read as the physical line-model equation with potential at energy . Both the equation and the phase integral transfer exactly; no approximation is involved.
- Small . The regime is the regime ; the lemma itself makes no smallness assumption, and the error theorems that use smallness state it separately.
Finite-rank gapped spectral cluster under a bounded perturbation
Statement
Assume Countable Choice (The Axiom of Countable Choice ()). Let be an arbitrary complex Hilbert space (Hilbert space) and a self-adjoint operator on its exact dense domain (Symmetric, self-adjoint and essentially self-adjoint operators). Let be an isolated eigenvalue with , and let its orthogonal spectral projection have finite rank . The PVM and gap calculus are those of CC spectral calculus on an arbitrary complex Hilbert space by compatible vector-local Cayley subspaces. Let and (A bounded linear operator between normed spaces, The operator norm as the least bound and as the unit-sphere or unit-ball supremum). Put on , and define For write , oriented counterclockwise, and .
(a) Resolvent and exact domain. is closed and densely defined on . Every is a resolvent point, with the convention of Resolvent and spectrum of an unbounded operator, and The series converges in operator norm uniformly on and locally uniformly in .
(b) Finite-rank holomorphic cluster. The norm contour integral is a bounded idempotent of rank exactly throughout , with and . It is holomorphic in operator norm. Its range lies in and is invariant under , and on . Both and are holomorphic in their respective operator norms.
(c) Exactly the enclosed spectrum. Let . Then This is a nonempty finite set of at most eigenvalues. The restriction of to has a bounded two-sided inverse on its exact domain for every . Consequently all generalized eigenvectors at an enclosed eigenvalue belong to ; their eigenspaces and generalized eigenspaces are those of this finite-dimensional restriction.
(d) Real coupling and zero perturbation. For real , is self-adjoint on . For real , is the orthogonal projection on the entire enclosed spectral cluster (Projection valued measure). If , then , and for every complex coupling, with and enclosed spectrum .
No separability or arbitrary-index Axiom of Choice is assumed. The claim supplies a cluster and its finite restriction; for it supplies no ordering or individually holomorphic scalar eigenvalue branches.
Facts & Assumptions
Given: CC; as in the statement. Inner products are linear in the first argument. Contour integrals are operator-norm limits of Riemann sums.
The CC arbitrary-Hilbert supplier CC spectral calculus on an arbitrary complex Hilbert space by compatible vector-local Cayley subspaces supplies the unique representing PVM, bounded Borel product/adjoint laws, exact square-integrability domains, concentration on the spectrum, spectral support equal to the spectrum and the distance resolvent bound. These are its current Statement and proof steps 4.1–6.2, rather than an AC global spectral decomposition. Its inverse is , with multiplier ; the convention here is , with multiplier . This sign conversion preserves its norm bound and exact range.
The operator, domain and inverse conventions are those of Symmetric, self-adjoint and essentially self-adjoint operators, Resolvent and spectrum of an unbounded operator, A bounded linear operator between normed spaces and The operator norm as the least bound and as the unit-sphere or unit-ball supremum. Bounded operator spaces are complete: an operator-norm Cauchy sequence has a pointwise limit in the complete target Hilbert space, which is linear and bounded, and the same uniform Cauchy estimates give operator-norm convergence. If the geometric series is the inverse of , as multiplication of finite sums leaves the remainder .
On a positively oriented circle about a, the integral of (z-a)^m is zero for every integer m except -1, and is 2 pi i for m=-1 and Cauchy's integral formula on a circle compactly contained in a disc of holomorphy supply scalar circle integrals and the Cauchy formula. Continuous scalar pairings and uniform norm limits give their bounded-operator versions. Finite-dimensional orthonormal bases require only finite Gram–Schmidt (Every finite-dimensional real or complex inner product space has an orthonormal basis); an injective map on an -dimensional space sends a basis to independent vectors, hence a basis, so is surjective; conversely a surjective map has spanning images of a basis, which must be independent. A map on a finite-dimensional Hilbert space is bounded because an orthonormal basis gives , and this applies to its inverse when bijective.
Proof
Given: The data of the statement and [F1]–[F3].
[Gap and correctly ordered Neumann inverse] By [F1], the spectral support of is . For , and every other spectral point has . Thus . The operator is closed on : if and , then , so closedness of gives and ; the domain remains dense. On , . Its first factor has the Neumann inverse [F2], since . Therefore the displayed ordered series gives a two-sided inverse with range exactly , and its geometric estimates give (a). Uniform convergence on the circle and each compact coupling subdisk proves norm holomorphy in ; local inverse Neumann series give holomorphy in on the resolvent set. When this series is constant for all couplings.
[Idempotence from two contours] Fix . Step 1.1 bounds the inverse uniformly on , and another inverse Neumann series gives a resolvent annulus around it. Integrals of a holomorphic operator-valued function over concentric circles in that annulus are independent of radius: differentiating in gives the integral of the periodic derivative of , hence zero. Take an outer circle for and an inner circle for . The inverse equations give , and also commutation of resolvents. In its double integral, the first term integrates in the outer variable to the inner projection integral because ; the second integrates in the inner variable to zero because . Compact continuous integrals can be interchanged by norm Riemann sums. Annular independence identifies both circle integrals with , proving . Resolvent commutation also gives .
[Graph domains, commutation and holomorphy] The identity makes the contour integrand continuous into the complete graph space of the closed . Integrating there proves and . On the other inverse equation gives , so integration gives there. Thus the range and kernel reduce the operator with its domain. The uniform coupling series makes both and norm holomorphic. Since , the pair is holomorphic into and takes values in the closed graph of ; hence is holomorphic as an operator into that graph space. In particular, the finite restriction is well-defined on all of .
[Initial projection and rank throughout the disk] At zero coupling use the sign conversion in [F1]: has multiplier , whose counterclockwise integral divided by is inside and outside. Thus the resolvent contour is the PVM projection on the real interior; its only unperturbed spectral point is , so this is . This evaluation follows by spectral pairings: scalar circle kernels integrate to one inside and zero outside [F3]; norm Riemann sums converge uniformly in the spectral variable, since the spectrum is at distance at least from the circle, allowing interchange with its finite scalar measures. The circle length and step 1.1 give . If bounded idempotents have , then and imply unless ; therefore is injective, and the reverse restriction is also injective. For , the inverse equations give , hence . Choose an integer and compare the finite path , . At each adjacent pair the two injections and finite dimension imply equal rank. Starting with rank proves rank at , even when the direct distance estimate is at least one. If the path is constant.
[All spectral values of the finite restriction are inside] Put , , and . For , resolvent commutation and the inverse equations give on . If with , then by those equations and . The equation and its contour definition give winding number one for , so . In a finite basis of , is invertible exactly when its kernel is zero [F3]; thus every spectral point of is an eigenvalue and lies in . There are at most distinct such points, since eigenvectors for distinct eigenvalues are linearly independent: in a shortest nontrivial relation among them, applying for one term removes that term and leaves a shorter nontrivial relation. There is at least one: otherwise is holomorphic throughout a neighborhood of the closed disk, and the scalar Cauchy formula [F3] makes its contour integral zero entrywise, contradicting its integral and . Here the zero integral follows by applying the Cauchy formula to at .
[Complementary inverse on its exact domain] For define . As in step 3.1 its range lies in . The identity gives on ; its right-hand counterpart gives on . Resolvent commutation shows commutes with . The bounded map therefore maps into and satisfies both inverse equations for on that exact complementary domain. No assertion that is needed. The idempotent splitting is and, since and preserves , its domain splitting is . The complementary domain is dense in , since applying the bounded to approximants from the dense preserves and approximates every vector of .
[Exactly the interior spectrum and generalized eigenspaces] If , then the bounded operator maps into and is a two-sided inverse of by the domain splitting and step 4.2. If , step 4.1 supplies a nonzero eigenvector in , so . This proves , with its nonempty finite character from step 4.1. For such an eigenvalue and an integer , any generalized eigenvector has in the complementary iterated domain, because preserve and commute with . Step 4.2 makes injective on the complement; its powers are then injective on their domains, so forces . Conversely is invariant, so every generalized eigenvector of is a generalized eigenvector of the full operator. This proves (c), including the exact complementary inverse.
[Real coupling, zero branch and assembly] The bounded-perturbation adjoint identity is , : subtract the everywhere-defined bounded term from the adjoint functional to identify exactly the domain of . Thus is self-adjoint for every real . For real , apply [F1] to this operator, again converting to with multiplier . Its spectrum misses the circle by step 1.1, so has positive distance from it by compactness of the circle and openness of the resolvent set. The same uniform scalar-kernel/Riemann-sum evaluation as in step 3.2 identifies with the PVM on the real interior, hence an orthogonal spectral projection on the entire cluster. If , the norm definition gives , all resolvents and projections are constant for every complex coupling, and the exact PVM domain gives ; therefore the restriction is and its spectrum is . Steps 1.1–5.1 give the other assertions for arbitrary under CC, using only a finite path and finite bases; no individually ordered or holomorphic scalar branches have been introduced.
The declared variational trial reading: assigned energy observable, form domain, trial value, bottom and gap
The variational trial reading of a declared system of the framework: a self-adjoint assigned energy observable H bounded below, its form domain Q(H) and form q_H supplied by the cited spectral-form mathematics, the model bottom E(0) = inf sigma(H), an isolated bottom with a declared gap g and its spectral projection, the discrete eigenvalue ladder below the essential spectrum, and the declared vocabulary of trial vector and trial value. The definition asserts nothing about whether the bottom is attained, about any eigenvector, about any laboratory realization or identification, and about any measurement, apparatus or sampling model.
Definition
(a) Framework data. Adopt the state and composition postulate P1, the observable and probability postulate P2 and the autonomous-dynamics postulate P4 (State and composition postulate P1: Hilbert spaces, preparations and composite systems, Observable and probability postulate P2: self-adjoint observables, spectral probability and finite unsharp outcomes, Autonomous dynamics postulate P4: self-adjoint generators and unitary evolution) for a declared system, in the state reading of The state space of the framework: preparations, pure rays and density operators, the sharp observable reading of Assigned sharp observables and the outcome law of the framework and the evolution reading of Assigned energy observable, unitary flow and the two pictures of autonomous evolution; units are those of Dimensions, SI unit conventions and quantity types of the framework. Assume the Axiom of Countable Choice and the Axiom of Choice as the choice hypotheses of the cited mathematical suppliers (The Axiom of Countable Choice (), The Axiom of Choice).
(b) Assigned energy observable. As an additional model assumption of the pair, fix a self-adjoint operator on the declared state space and declare the pair to be the system's sharp energy observable in the sense of Assigned sharp observables and the outcome law of the framework clause (a); this identification of the operator with the energy of the system is an assumption of the model, not a consequence of P1, P2 or P4. Assume is bounded below: there is a real with for every . The spectrum is the set of the cited spectral theorem, and the model bottom is read in joules. An assignment of a concrete material system to the pair is a tested identification in the sense of the preparation and apparatus discipline P7 and is not made here.
(c) Form domain and trial value. Let and be the form domain and the closed semibounded form of Spectral form domain and core of a semibounded operator for the lower bound of clause (b), with the projection-valued measure of and (Spectral theorem for unbounded self-adjoint operators (PVM form), Projection valued measure). The definition uses the facts, proved by that lemma, that does not depend on the choice of the lower bound , that is dense in , and that for . A trial vector of the model is a vector with ; its trial value is , read in joules. For a trial vector that lies in , the trial value is the mean energy of the pure preparation under the observable in the moment reading of Mean, second moment and variance of an assigned observable in a preparation; for a general trial vector in the trial value is the form value and is not asserted to be the mean of any outcome law.
(d) Bottom gap and discrete ladder. If the bottom is an isolated spectral value, declare a gap to be a real with and put for the bottom spectral projection. The discrete spectrum below the essential spectrum is the part of of Discrete and essential spectrum of a self-adjoint operator below , listed with multiplicity in nondecreasing order as , with the convention once the list is exhausted, . The definition asserts neither that is an eigenvalue, nor that any eigenvector exists. The ladder convention does give : the nonempty closed spectrum of the bounded-below operator contains its bottom; if the bottom is discrete, it is the first listed eigenvalue, and otherwise it lies in the essential spectrum, so and the empty below-threshold list is padded by . This equality does not imply that the bottom is attained by an eigenvector.
(e) Scope. Clauses (a)-(d) are a reading of the framework's state, observable and dynamics postulates together with the declared operator ; they assert nothing about whether a preparation attains the trial value, about the behaviour of any preparation under time evolution beyond P4, about equilibration, environmental coupling, measurement or apparatus, and about any measured energy. All spectral statements are statements about the declared operator.
The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster
The perturbed-family model of a declared system of the framework: a self-adjoint unperturbed energy observable H0, a bounded self-adjoint perturbation V with norm v, the real coupling lambda and the family H(lambda) = H0 + lambda V declared as the model's energy observable at coupling lambda, together with a fixed isolated eigenvalue E of H0 of finite multiplicity with gap g, its spectral projection, the first-order operator P0VP0 on the eigenspace, and the followed perturbed spectral cluster supplied by the contour construction. The definition asserts no time-dependent perturbation, no ramping protocol, no occupation of any branch by a preparation, no measurement and no laboratory identification; all statements are about the declared operator family.
Definition
(a) Framework data. Adopt P1, P2 and P4 (State and composition postulate P1: Hilbert spaces, preparations and composite systems, Observable and probability postulate P2: self-adjoint observables, spectral probability and finite unsharp outcomes, Autonomous dynamics postulate P4: self-adjoint generators and unitary evolution) for a declared system, with the state, sharp-observable and evolution readings of Assigned sharp observables and the outcome law of the framework and Assigned energy observable, unitary flow and the two pictures of autonomous evolution; units are those of Dimensions, SI unit conventions and quantity types of the framework. Assume the Axiom of Countable Choice and the Axiom of Choice (The Axiom of Countable Choice (), The Axiom of Choice) as the choice hypotheses of the cited mathematical suppliers.
(b) The perturbed family. As an additional model assumption of the pair, fix a self-adjoint operator on the declared state space, declare to be the unperturbed sharp energy observable, fix a bounded self-adjoint operator (A bounded linear operator between normed spaces) with (The operator norm as the least bound and as the unit-sphere or unit-ball supremum) and fix a real coupling (dimensionless: is read in joules). Declare the perturbed family to be the model's sharp energy observable at coupling . Since is -bounded with -bound (the bound inequality holds with and ), the Kato-Rellich theorem applies and is self-adjoint on for every real (Kato-Rellich theorem, Symmetric, self-adjoint and essentially self-adjoint operators). This self-adjointness is a supplied theorem about the declared operators; the reading of the family as the system's energy is the model assumption.
(c) The gapped label. Fix an isolated eigenvalue of of finite multiplicity with gap and put and (Discrete and essential spectrum of a self-adjoint operator, Projection valued measure, Resolvent and spectrum of an unbounded operator). The definitions used by the pair are those of the cited suppliers:
(i) for real with , the followed spectral cluster is the spectrum of inside , and (counterclockwise) is its rank- orthogonal spectral projection, by Finite-rank gapped spectral cluster under a bounded perturbation. The cluster is a nonempty finite set and is exactly the spectrum of the restriction to . In the simple case only, write for its unique spectral value; this scalar is the followed perturbed label of Contour perturbation projection and is analytic on the valid coupling disk. For no unique scalar label, branch ordering or individual scalar holomorphy is presumed. At the cluster is and its projection is . If , these data are constant for all real couplings, with no radius involving division by .
(ii) the first-order operator is the Hermitian operator on the finite-dimensional eigenspace , whose spectrum is the model's first-order shift data (joules per unit coupling);
(iii) the complementary reduced inverse is a bounded operator with the displayed exact complementary-domain inverse. For every finite multiplicity , including , its existence follows by applying part (c) of Finite-rank gapped spectral cluster under a bounded perturbation at coupling and : since the cluster projection is then , the restriction of to has a bounded two-sided inverse , and . For the same operator is supplied by Simple-level reduced-resolvent coefficients. Its role is to record that the whole complementary spectral subspace, continuum included, contributes to the second-order data.
(d) Scope. Clauses (a)-(c) cover bounded perturbations of a self-adjoint operator and a fixed isolated finite-multiplicity label only. The definition asserts no time-dependent perturbation, no adiabatic ramping of , no statement that a preparation occupies the branch of or of any eigenvalue of , no branch-population or relaxation statement, no measurement and no identification of the model with a laboratory system; the labels are spectral data of the declared family.
The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading
The WKB regime model of a declared spinless one-dimensional massive particle: a compactly supported C^5 potential in the declared line model, declared reference length and energy scales, the nondimensionalised stationary equation with explicit dimensionless semiclassical parameter h, the turning-point, allowed-region and forbidden-region vocabulary, the WKB phase integral and the declared barrier transmission reading. The definition asserts no approximation error (that belongs to the page's theorems), no detector, no wave packet and no laboratory potential; it states the exact nondimensionalisation correspondence proved by the cited lemma.
Definition
(a) Framework data and line model. Adopt P1, P2, P4 and P5 (State and composition postulate P1: Hilbert spaces, preparations and composite systems, Observable and probability postulate P2: self-adjoint observables, spectral probability and finite unsharp outcomes, Autonomous dynamics postulate P4: self-adjoint generators and unitary evolution, Kinematics and massive-particle model postulate P5: Newtonian frames and one-particle operators), the state and observable readings cited there, and the declared effective one-dimensional line model The declared one-dimensional line model: state space, Hamiltonian, bound states and generalized stationary solutions with a mass parameter , spin label , action constant and units from Dimensions, SI unit conventions and quantity types of the framework (The massive spin-s particle model of the framework: state space, operators, units and frame readings). Assume the Axiom of Countable Choice and the Axiom of Choice as the choice hypotheses of the cited mathematical suppliers (The Axiom of Countable Choice (), The Axiom of Choice). Fix a real potential (five times continuously differentiable with compact support); it is real, bounded and measurable, so the line model's assigned energy operator of its clause (c) is defined with domain , acts by , and its stationary equation at energy reads for classically solutions.
(b) Reference scales and nondimensionalisation. As an additional model assumption of the pair fix a reference length (metres) and a reference energy (joules), and put Then is dimensionless with support scaled by , and is dimensionless. By Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent the physical stationary equation of clause (a) at energy is equivalent, under , , to the dimensionless WKB equation on every interval . The exact transfer of the square-root action integrals over a subinterval is, when the indicated strict sign holds throughout , these are respectively clauses (b)(i) and (b)(ii) of Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent. The pair calls the model's semiclassical parameter and calls the semiclassical regime; the physical content of the regime is , and every statement of the page's theorems is an exact statement about the family indexed by , with the error bounds stated at each . For the mathematical small- limit, hold the dimensionless profile and energy fixed and vary the parameter in . A corresponding physical family with fixed is obtained by taking and , with ; the physical width then changes, while the natural action constant does not. A single originally chosen supplies one member of this family.
(c) Turning points, regions and phase. For the data put for the set of turning points. A point is simple when . An open interval is an allowed interval when on (the dimensionless kinetic energy is positive there), a forbidden interval when on . On an allowed interval the model uses the positive scaled momentum with local wavenumber in the coordinate and WKB phase with a declared base point; on a forbidden interval the model uses . The dimensionless forbidden action of a forbidden interval is The WKB exponent is , the physical action in units of . For a barrier whose endpoints are simple turning points, the strict-sign hypothesis of clause (b)(i) fails at those endpoints; apply that clause on and let . Both integrands extend continuously with value zero at the endpoints, so the omitted endpoint integrals tend to zero. The three declared regime hypotheses used by the page are:
(W1) Allowed-interval regularity: on a neighbourhood of and on for some (no turning point in the interval; the interval is allowed);
(W2) Separated simple turning points: has exactly two zeros in , both simple, is positive on and negative on the complement of (equivalently the physical barrier has exactly two simple zeros surrounding a forbidden region and is negative outside);
(W3) Single simple turning point: on an interval the equation has the single zero , it is simple, and on one side and on the other.
(d) Declared barrier transmission reading. Under (W2), because outside its compact support. Choose with and put . The declared scattering solution is the exact solution of the dimensionless equation with boundary conditions Thus there is one incoming wave from the left and none from the right. These data determine unique amplitudes by Two-turn barrier tunnelling error, instantiated with its mass parameter , potential and energy . Define the reference current : the normalized exterior waves have currents . The transmission coefficient is , the ratio of transmitted to incoming reference current. The physical line-model current is a positive common multiple of under clause (b), so its ratio is also . Airy/WKB matching computes this exact boundary-defined quantity; it does not define an additional approximate scattering solution. No detector, wave packet, scattering experiment or measured count is asserted, and this clause does not by itself assert an asymptotic formula for .
(e) Scope. The model concerns a declared spinless massive particle in the declared one-dimensional line model with a compactly supported potential, at a fixed energy, in the nondimensionalised family of clause (b). It asserts nothing about two- or three-dimensional scattering, about singular or non-smooth potentials, about wave packets, detectors or measurements, and about any laboratory realization of the line model, the potential or the energy .
Static finite-level electric-dipole coupling: compressed dipole of the declared two-body Coulomb model in a uniform field
The static finite-level electric-dipole coupling model of the declared two-body Coulomb pair: the relative-coordinate dipole operator with components -q Q_j on their maximal L^2 domains, a declared finite-dimensional subspace of the relative-coordinate space, the compressed Hermitian dipole matrix, the uniform static field value and the bounded interaction -E . D added to the compressed Coulomb energy on the subspace. The postulate is a model assumption for the declared finite-level truncation; it asserts no Maxwell equation or source model, no propagation, no derivation of the truncation or of the field, no semibounded uncompressed model (the common test-domain expectations of H_kappa - E_ext . D are shown unbounded below for every nonzero uniform field), no transition rate and no measured shift.
Postulate
Adopt as a physical assumption of the pair, additional to P1, P2 and P4 and valid only for the declared finite-level model of this clause, the following static electric-dipole coupling. Assume the Axiom of Countable Choice and the Axiom of Choice as the choice hypotheses of the cited mathematical suppliers (The Axiom of Countable Choice (), The Axiom of Choice).
(i) Declared charged pair and relative coordinate. Take the declared two-body Coulomb model of The declared Coulomb and two-body hydrogen model: one-centre operator, relative problem, reduced mass and scope exclusions clause (d): two distinguishable spinless particles with mass parameters and opposite charges and , (coulombs), with the relative coordinate and the centre-of-mass/relative unitary . Work in the relative-coordinate factor of that reading, with Coulomb mass parameter , and with units as in Dimensions, SI unit conventions and quantity types of the framework.
(ii) Dipole operator. Let , , be the coordinate multiplication operators on with maximal domains of Atomic dipole matrix-element domain clause (a); they are self-adjoint and proper densely defined. The model's dipole operator is the triple because the dipole of charges at and at is : it points from the negative to the positive charge, opposite to the declared relative coordinate . Each is self-adjoint on and has unit . This is the dipole of the declared pair in its relative-coordinate reading; no multipole expansion, no field equation and no coupling to the centre-of-mass motion is assumed.
(iii) Finite-level truncation. Fix, as part of the model specification, a declared finite-dimensional subspace of the relative-coordinate space with and , together with an orthonormal basis of . The model declares the compressed dipole matrix on , where is the orthogonal projection onto and the restriction to is read in the declared orthonormal basis; is the finite Hermitian matrix of the dipole component, with unit , and it is bounded with norm at most . The truncation and the basis are model assumptions: they are not derived from the Coulomb model, and they replace the unbounded operator by its compression throughout this pair.
(iv) Static uniform field and interaction operator. The external datum is a uniform static electric field value , read in ; it is prescribed, and no Maxwell equation, source model, propagation or back-reaction is assumed. The finite-level static Stark model is the finite-dimensional operator on where the energy-domain condition of (iii) makes the compression defined, and is the one-centre Coulomb energy operator with mass parameter of the declared model, read on the relative-coordinate factor through the angular/radial identification used by the pair. The interaction term has unit and is bounded Hermitian on , so is a bounded Hermitian matrix and the Kato-Rellich and perturbation statements of the pair apply to it with a bounded perturbation; this identification of the matrix with the model's energy on the truncated subspace is a model assumption.
(v) Scope and explicit exclusion. Clauses (i)-(iv) are adopted model assumptions. They assert nothing about a laboratory atom, field or apparatus; no measured Stark shift is claimed; no transition, absorption or emission rate is defined; and no time dependence of the field is assumed. In particular the postulate deliberately does not treat the uncompressed linear potential as a bounded perturbation of . For , define this composite interaction to be the maximal multiplication operator it agrees with on the common domain and is unbounded because its real multiplier is unbounded. The common operator domain contains . Its lack of a lower bound can be demonstrated without assuming a full energy-form domain: let , , choose a fixed support radius in metres and normalized , and for each length put Then and . On this common test domain define the quadratic expectation With , the Coulomb action and the translation-invariant kinetic expectation give Here because in the relative-coordinate convention. For , the Coulomb integral is finite and at most , the kinetic term is constant, and the other field term apart from is independent of . Therefore as . This proves unboundedness below of the displayed quadratic expectation on the common test domain, so no quadratic form bounded below there can agree with these values; no claim is made about a particular closed-form domain. The uncompressed static-field model is outside the scope of every statement of this pair. Only the compressed finite-level operator of clause (iv) is used.
Variational trial bounds, gap-overlap control and the min-max characterisation of the declared model's discrete eigenvalues
The variational and min-max statements of the declared trial model: every trial value is at least the model bottom E0, a trial value within epsilon of an isolated bottom with gap g forces ground-projection content at least 1 - epsilon/g, and the model's discrete eigenvalues below the essential spectrum are exactly the min-max values over trial subspaces of the form domain. All quantities are readings of the declared operator; no measurement, apparatus, sampling model or laboratory identification is asserted.
Statement
Adopt the framework data and the declared variational trial model of The declared variational trial reading: assigned energy observable, form domain, trial value, bottom and gap: a declared system with self-adjoint assigned energy observable on , bounded below by a real , with model bottom , form domain , form and spectral projection-valued measure ; a trial vector is a unit vector and its trial value is . Assume the Axiom of Countable Choice and the Axiom of Choice (The Axiom of Countable Choice (), The Axiom of Choice) as the choice hypotheses of the cited spectral suppliers. Then:
(a) Trial lower bound. For every trial vector , so every trial value is an upper bound for the model bottom; consequently .
(b) Gap-overlap control. Suppose in addition that the bottom is isolated with gap and let (clause (d) of the model). Then for every trial vector with , , in particular, if , then .
(c) Min-max. Let and let be the discrete eigenvalue ladder of the model clause (d), with after exhaustion and . Then for every integer , with the infimum over an empty set read as ; moreover , and when both outer values are attained, respectively by a span of the first and a span of the first orthonormal eigenvectors.
(d) Consequence for trial subspaces. For every linear subspace of dimension whose supremum is finite, ; for this is clause (a) with a unit vector of .
(e) Reading and scope. All numbers , , are read in joules. For a trial vector in the trial value is the mean energy of the pure preparation in the moment reading of Mean, second moment and variance of an assigned observable in a preparation; for a trial vector in it is a form value and no outcome-law mean is asserted. The theorem asserts nothing about whether the infimum in (a) is attained, about a ground eigenvector, about time evolution, equilibration or environmental coupling, and about any measured energy; it is a statement about the declared operator .
Facts & Assumptions
Given: the declared trial model of The declared variational trial reading: assigned energy observable, form domain, trial value, bottom and gap with its data ; a gap and in clause (b); and the ladder in clause (c); the choice hypotheses.
Spectral data of the model. is self-adjoint with dense domain and its regular projection-valued measure; is the set of real every neighbourhood of which has nonzero spectral projection, the spectrum is contained in because , and (Spectral theorem for unbounded self-adjoint operators (PVM form), Projection valued measure, Discrete and essential spectrum of a self-adjoint operator).
Form and moments. and are independent of the lower bound chosen in the model, is dense in for the form norm, , and for (Spectral form domain and core of a semibounded operator). is a measure of total mass (Projection valued measure).
Supplied trial and gap estimates. Let be a self-adjoint operator on a nonzero complex Hilbert space, bounded below with bottom , let satisfy , put , and let be the form of Spectral form domain and core of a semibounded operator. On the spectral support , and for any lower bound ; since , these inequalities show . Thus for every unit , the supplied theorem gives ; and if then , with when (Spectral form domain and core of a semibounded operator, Spectral theorem for unbounded self-adjoint operators (PVM form), Variational ground gap overlap clauses (a), (b)).
Supplied min-max theorem. Under the Axiom of Choice, for a self-adjoint operator bounded below on a complex Hilbert space, with form domain , form , and the eigenvalue ladder below (equal to after exhaustion), the two min-max formulas of clause (c) hold for every , with infima over empty sets ; if both outer values are attained by spans of the first and first orthonormal eigenvectors (Min-max principle below the essential spectrum).
Proof
Given: the data of the statement and [F1]-[F4].
[Clause (a)] By [F1] the spectrum lies in , so every real has a neighbourhood, namely , with zero spectral projection, and countable subadditivity of the finite measure over the rational intervals contained in gives . Hence is carried by and, for with the finite integral of [F2], since is a trial vector. For the reverse infimum inequality, let . Since , choose with . Choose a bounded open interval containing and contained in . The spectral-support characterization in [F1] gives ; choose a unit vector in its range. Its spectral measure is supported in the bounded set , hence and . Thus the infimum of trial values is exactly , as claimed in (a).
[Clause (b)] The model's clause (b) supplies a self-adjoint bounded below with bottom , and clause (b) of the statement supplies the gap and ; the model's and are those of [F2], which are the ones used by the supplied estimate [F3] with , , , . Applying [F3] gives , hence whenever , and when .
[Clause (c)] The operator is self-adjoint and bounded below, so [F4] applies with ; its form domain and form are and by [F2], its essential spectrum is with , and its eigenvalue ladder below , with the after-exhaustion convention, is exactly the ladder of the model clause (d) by Discrete and essential spectrum of a self-adjoint operator. Hence the two displayed min-max identities and the attainment statement for hold.
[The identification ] For the second min-max formula in [F4] has only , so it gives . Step 1.1 identifies this infimum as , hence and the additional assertion of (c) follows. This argument does not assume that the infimum is attained or that a bottom eigenvector exists.
[Clause (d)] Let have dimension and finite supremum . This particular belongs to the first min-max infimum of step 1.3, so directly; attainment of the inner supremum is unnecessary. If and is any unit spanning vector, the unit vectors of the complex line are with , and the quadratic form satisfies . Thus and reduces the assertion to (a).
[Clause (e)] The units are those of the model: and in joules, so and are read in joules. For , by [F2], which is the mean of the assigned sharp energy observable in the pure preparation by Mean, second moment and variance of an assigned observable in a preparation clause (a); for the value is the form value of [F2] and no outcome-law mean is asserted. No measurement, apparatus or sampling model entered the argument, and every object is a spectral datum of the declared operator .
Remarks
- No attained-ground-state hypothesis. Clauses (a) and (c) hold whether or not is an eigenvalue and whether or not the infimum of the trial values is attained; clause (b) states precisely what an isolated bottom with gap forces. This is the form-domain reading required of the variational bound: the trial vector need not lie in .
- Choice. The min-max clause cites the published min-max theorem, which assumes the Axiom of Choice; the trial lower bound of clause (a) and the gap estimate of clause (b) are, through their suppliers, Countable-Choice statements in their other dependencies. Consumers that use clause (c) carry the Axiom of Choice.
Nondegenerate stationary perturbation of a simple gapped label: first- and second-order coefficients and an explicit cubic remainder
The stationary perturbation statement for the declared perturbed-family model with a simple isolated label: self-adjointness of the family for real couplings, existence, uniqueness and reality of the followed label inside the gap contour, the exact first- and second-order energy coefficients with the reduced inverse of the complementary spectral subspace, and the explicit cubic remainder bound on the coupling disk. The theorem concerns spectral data of the declared operator family only; it asserts no ramping protocol, no branch population, no relaxation, no transition rate and no measurement.
Statement
Adopt the framework data and the declared perturbed-family model of The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster in the simple-label case: is self-adjoint on , with , on for real , and is an isolated eigenvalue of of multiplicity one with gap at least , . Let be a normalized eigenvector, , let be the reduced inverse of the model clause (c)(iii). In the branch put Then clauses (a)-(e) hold for every real with in this positive-norm branch; clause (f) covers independently of :
(a) is self-adjoint on ; the model's followed label of the contour exists, is the unique spectral value of inside that contour, is real, and its spectral projection is the orthogonal rank-one projection ;
(b) the gauge-fixed eigenvector is analytic in , satisfies and , and
(c) the model's label identity holds, so the deviation of the model's energy label is controlled by the perturbation alone;
(d) the exact coefficients are with , and ; the second-order coefficient involves the whole complementary spectral subspace of through , continuum included;
(e) the cubic remainder obeys so at the bound is and for it is at most ;
(f) if , that is , then , and for every real , and no radius involving division by is used in this branch;
(g) the theorem is conditional on the strict positive gap, on the multiplicity one of and on the boundedness of ; it asserts no unbounded or degenerate perturbation theorem, no time-dependent perturbation, and no statement about which branch of the family a preparation occupies.
Facts & Assumptions
Given: the declared perturbed-family model in the simple-label case; and the reduced inverse as in the statement; a real with ; the Axiom of Countable Choice.
Self-adjointness of bounded perturbations. For a self-adjoint and a symmetric with and -bound less than one, on is self-adjoint (Kato-Rellich theorem).
Contour construction and reality. Under the hypotheses of the contour theorem ( self-adjoint on its exact dense domain, isolated with gap at least and rank-one spectral projection , bounded with , ): is closed and densely defined on with norm-convergent resolvent series on the contour ; the operator is an operator-norm holomorphic rank-one Riesz projection, there is exactly one spectral value of inside , of algebraic multiplicity one with , and for real the operator is self-adjoint and is its orthogonal spectral projection (Contour perturbation projection clauses (a)-(d)).
Coefficients and remainder. Under the hypotheses of [F2] with the reduced inverse of Simple-level reduced-resolvent coefficients and the gauge-fixed : on the complex disk , , , , the identity holds, the coefficients and bounds of clause (d) hold, and the cubic remainder bound of clause (e) holds; for one has , , (Analytic perturbation remainder clauses (a)-(c)).
Model data. The model's clause (c) supplies and exactly as the followed perturbed label and Riesz/spectral projection of the contour theorem, the multiplicity-one hypothesis, the gap at least , the reduced inverse and the reading of as the model's sharp energy observable (The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster).
Proof
Given: the data of the statement and [F1]-[F4].
[Self-adjointness on ] The perturbation is bounded and symmetric with , and the -bound of is because ; hence [F1] gives that on is self-adjoint for every real . This is the self-adjointness assertion of (a).
[Contour, label and projection] In the simple-label case the projection has rank one and the gap hypothesis is , so [F2] applies for every real with ; since gives , the conclusions hold: there is exactly one spectral value of inside , it has algebraic multiplicity one with range , is holomorphic and rank one, and for real the projection is the orthogonal spectral projection at the real value . By [F4] these are exactly the model's followed label and its projection, so clause (a) is proved.
[Gauge-fixed eigenvector, coefficients and remainder] With the identified objects, [F3] applies on the disk : is analytic with the displayed normalization and eigenvector equation, the quantitative bounds , , hold, the label identity of clause (c) holds, and the coefficients, the bounds , , and the cubic remainder bound hold. By [F4] the operator is the model's complementary reduced inverse, so the second-order term involves the whole complementary spectral subspace, continuum included. This proves clauses (b), (c), (d) and (e).
[The branch] If then and the family is constant, ; [F3] clause (c) gives , , for every real without using a radius (no division by occurs). This is clause (f).
[Scope] Every hypothesis used above is one of: the model's bounded self-adjoint perturbation and simple gapped label, the strict positive gap , multiplicity one, and the choice assumption of the spectral suppliers. No unbounded perturbation, degenerate label, time-dependent coupling, ramping protocol, transition rate, branch population or measurement entered the argument; the objects , , are spectral data of the declared family, which is clause (g).
Remarks
- Where the continuum enters. The reduced inverse acts on the whole complementary subspace , so the second-order coefficient automatically includes the contribution of the continuous spectrum of ; the theorem needs no discrete-eigenbasis expansion and no sum over bound states.
- Determinant of the remainder. The bound is a genuine cubic bound on the disk of radius ; no uniformity in beyond that disk is claimed, and the gap enters both the radius and the constant.
Degenerate stationary perturbation: the perturbed eigenvalues stay within 4 lambda^2 v^2/g of the first-order shifts, and no branch relaxation is asserted
The degenerate stationary perturbation statement for the declared perturbed-family model with an isolated finite-multiplicity label: self-adjointness of the family, the bounded reduced inverse on the complementary subspace, and the localisation of every perturbed eigenvalue in the controlled gap window within 4 lambda^2 v^2/g of the set of first-order shifts E + lambda spec(P0VP0). The theorem asserts no exact eigenvalue correspondence, no branch ordering, no instantaneous selection of the lowest branch, no relaxation and no measurement.
Statement
Adopt the framework data and the declared perturbed-family model of The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster with self-adjoint on , , , on for real , and an isolated eigenvalue of of finite multiplicity with gap at least , . Let , , and the first-order operator of the model clause (c)(ii). Assume the Axiom of Countable Choice and the Axiom of Choice as the choice hypotheses of the suppliers. Then for every real with :
(a) is self-adjoint on ;
(b) for every real with , the restricted operator on has a bounded two-sided inverse with ;
(c) every real eigenvalue of with eigenvector and lies within the first-order shift set: where is the spectrum of the Hermitian operator on the -dimensional eigenspace; moreover for every such eigenvector. Every eigenvalue in the model's followed cluster inside lies in this controlled window and therefore obeys the same bound;
(d) first-order content. The eigenvalues of are the model's first-order shifts: the set has at most points, all within of ; the entire followed cluster, and every other eigenvalue in the window of (c), are localised at distance from this set, and no ordering or one-to-one correspondence between the spectral branches and the points of is asserted;
(e) No relaxation or selection. The theorem is a statement about the spectra of the declared family. It asserts no instantaneous transition of any preparation to the branch of the smallest value of , no relaxation to a lowest branch, no equilibration and no measurement; which spectral subspace a preparation occupies is fixed by the preparation and by the evolution postulate P4 of the declared model, not by the label ;
(f) the theorem is conditional on the strict positive gap, on the finite multiplicity of and on the boundedness of ; it asserts nothing about degenerate essential-spectrum labels, gap-closing families, unbounded perturbations or time-dependent couplings.
Facts & Assumptions
Given: the declared perturbed-family model with the isolated label of finite multiplicity , gap , projections , perturbation with , real with , and the choice hypotheses.
Self-adjointness. For a self-adjoint and a symmetric with and -bound less than one, on is self-adjoint (Kato-Rellich theorem).
Supplied degenerate reduction. Under the stated hypotheses on and for every real with : the restricted operator has a bounded two-sided inverse with ; if such a is an eigenvalue with eigenvector , then and and every such eigenvalue satisfies (Degenerate Feshbach error clauses (a)-(c)).
Norm-spectrum extrema. For a bounded self-adjoint operator on a complex Hilbert space, , so ; in particular because for the compression of a bounded self-adjoint operator (Self adjoint norm and spectrum extrema, The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster clause (c)(ii)).
Model data. The model declares as its sharp energy observable at coupling , with the label , projections , first-order operator and coupling range as in its clauses (b) and (c) (The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster).
Distance resolvent bound. On arbitrary Hilbert space under CC, the self-adjoint spectral supplier gives and the exact domain of that inverse (CC spectral calculus on an arbitrary complex Hilbert space by compatible vector-local Cayley subspaces). Neumann inversion of gives a resolvent of whenever the distance is larger than .
Proof
Given: the data of the statement and [F1]-[F5].
[Clause (a)] is bounded and symmetric with and -bound , since ; [F1] gives that on is self-adjoint for every real , in particular for .
[Clauses (b) and (c)] With self-adjoint, the hypotheses of [F2] are exactly the model's data: is an isolated eigenvalue of finite multiplicity with gap at least , is its orthogonal spectral projection, is self-adjoint and bounded with norm , and implies in particular that the range of in clause (b) is nonempty (it contains , since ). Hence [F2] supplies the bounded two-sided inverse with , the nonvanishing and the eigenvector reduction, and the localisation inequality for every eigenvalue in that window; the spectrum there is that of the model's . For the full followed cluster, put and let be its real eigenvalue, so by the model's cluster definition. Every other satisfies . If also , [F5] and Neumann inversion would put in the resolvent of , a contradiction. Hence , so and the preceding reduction applies to every cluster eigenvalue. This proves the full claims (b),(c).
[Clause (d)] By [F3] applied to the bounded self-adjoint compression : and , so every point of lies in ; is finite because has dimension , so the set has at most points. The localisation of clause (c) is precisely the statement that each perturbed label lies at distance from that set; no ordering statement is contained in [F2], and none is asserted here. This is (d).
[Clause (e)] The argument used only spectral data of the declared family: self-adjointness of , the reduced inverse on the complementary subspace, and the eigenvector reduction with . No evolution, no coupling ramp, no rate, no environment and no measurement entered the proof. A statement about which spectral subspace of a preparation occupies would require the preparation and the evolution law of P4, which are not used here; in particular the analysis of the label does not force an instantaneous transition to the branch belonging to the smallest element of . This is (e).
[Clause (f)] All hypotheses used are the strict positive gap, the finite multiplicity of , the boundedness of and the coupling range ; none of the excluded configurations entered the arguments of steps 1.1-2.2.
Remarks
- Why the first-order operator, not the full perturbation. The supplied reduction shows that the perturbed labels are localised at the spectrum of the compression , which is the model's first-order shift data; the second-order remainder is bounded uniformly by , independently of the structure of the perturbation inside the eigenspace.
- No branch selection. The statement is the corrected form of the textbook assertion that a degenerate level "immediately" moves to its lowest branch; only the spectral splitting is deduced here. Population of branches is a question about the preparation and its dynamics, not about the eigenvalue asymptotics.
WKB approximation on an allowed interval of the declared regime model: explicit Gronwall error bound away from turning points
The finite-interval WKB error statement for the declared WKB regime model: on a closed interval on which the dimensionless potential stays strictly below the energy (no turning point), any exact solution of the model equation is compared with its leading WKB wave, with the explicit Gronwall-type error bound of the cited theorem. The statement is exact at each value of the semiclassical parameter; it asserts no asymptotic connection across a turning point, no barrier transmission formula, no wave packet and no measurement.
Statement
Adopt the declared WKB regime model of The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading and let its data be as in that model, with hypothesis (W1) on a closed interval : is on a neighbourhood of and for some and all . Put and Let be an exact solution of the dimensionless model equation on , and let be its coefficient curve. Then, with the norm on and all quantities read in the model's units:
(a) for every ;
(b) ;
(c) pointwise wavefunction error. With the leading WKB wave,
(d) the estimate is exact at each fixed ; it degenerates as and therefore excludes turning points by hypothesis (W1). It asserts nothing about connecting asymptotics across a turning point, about barrier transmission or reflection, about packets or detectors, and it makes no claim that the right-hand side is small unless the dimensionless quantity is actually small. The estimate is an error bound of Gronwall type, not an asymptotic expansion, and the physical reading of the interval is in the line model with potential and energy .
Facts & Assumptions
Given: the WKB regime model with its scales and data; hypothesis (W1) on ; the functions ; an exact solution and its coefficient curve ; the Axiom of Countable Choice.
Coefficient representation. The Wronskian and smoothness statements for , and the coefficient definition , are those of Allowed-region WKB coefficient equation clauses (a)-(c). In particular is invertible and , .
Integral and norm facts. A continuously differentiable finite-dimensional vector curve satisfies , and the induced matrix norm satisfies ; these are the fundamental theorem of calculus and the definition of the induced norm (Fundamental theorem of calculus for Banach-valued continuous curves, Bochner-integrable function).
Model instantiation. The model's equation is , which is with on the allowed interval; hypothesis (W1) gives , , and . The correspondence with the physical line model is Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent (The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading clauses (b), (c)).
Proof
Given: the data of the statement and [F1]-[F3].
[Both coefficient relations and their matrix equation] By [F1], is invertible and , so is and satisfies . Differentiating the first component of this identity and comparing it with the second gives . Differentiating the second component, using and , gives . Thus and, since the Wronskian , Each entry of has modulus because and ; the induced matrix norm is the largest column sum, hence .
[Growth bound] Put and . By [F2] and step 1.1, and . Therefore , so , which is clause (a).
[Deviation bound by integration] Again by [F2] and step 1.1, The last integral is by the fundamental theorem of calculus applied to ; this proves clause (b), including the case . This derives the deviation estimate from the growth estimate without subtracting two growth bounds or treating as a homogeneous solution.
[Pointwise wavefunction error] The coefficient representation in [F1] gives Since , its absolute value is at most ; substituting step 3.1 gives exactly clause (c).
[Scope and degeneracy] The hypotheses used are (W1) and on a neighbourhood of : in particular , so and no turning point occurs on the interval. The displayed estimate is exact at each fixed ; its error is small only when the displayed factor is small, which is an additional condition on the model data. The line-model units and physical interval are those of The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading and Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent. This proves clause (d), without asserting a connection across a turning point or a measured quantity.
Remarks
- What "controlled approximation" means here. The theorem does not say that the WKB wave is close to the exact solution; it gives the exact Gronwall factor by which the WKB coefficient can change, so smallness is a checkable hypothesis on and on the dimensionless ratio .
- Turning points are outside the statement. Hypothesis (W1) is exactly the exclusion of turning points; the connection problem across a simple turning point is a separate theorem of this page.
Airy connection across a single simple turning point of the declared regime model, with envelope error control
The single-simple-turning-point connection statement for the declared WKB regime model with forbidden region on the right of the turning point: the two exact solutions matched to the Airy-type decaying and growing branches of the transformed equation, their forbidden-side exponential forms, their allowed-side sine and cosine forms with the phase pi/4 measured from the turning point, the factor two of the decaying-sine connection, and the envelope-times-epsilon absolute error control. The statement concerns the declared one-dimensional model's exact solutions only; it asserts no rectangular walls, no coalescing turning points, no multi-turn resonances, no wave packet and no measurement.
Statement
Adopt the declared WKB regime model of The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading with its data , and assume hypothesis (W3) at a turning point with : on an interval with the function has the single zero , is strictly negative on (allowed side) and strictly positive on (forbidden side). Write, for the two sides, the nonnegative dimensionless phase and exponent measured from the turning point into the allowed and forbidden sides. Letbe the Liouville coordinate. Write for the continuous remainder in the transformed equation and put , . Definewhere is the kernel constant of Stable weighted Airy Volterra connection; boundedness of on the fixed transformed interval gives for some depending only on the fixed data. There are constants and , depending only on (not on ), and , such that for every : (a) Decaying connection. There is an exact solution of the model equation on and a real constant withu_{\mathrm{dec}}(\xi)=C\,(W(\xi)-\lambda)^{-1/4} e^{-\Sigma(\xi)}\bigl(1+\delta_{\mathrm{f}}(\xi)\bigr)\qquad(\xi>\xi_{0}),$$$$u_{\mathrm{dec}}(\xi)=2C\,(\lambda-W(\xi))^{-1/4} \Bigl(\sin\bigl(\theta(\xi)+\tfrac{\pi}{4}\bigr)+\delta_{\mathrm{a}}(\xi)\Bigr) \qquad(\xi<\xi_{0}), where the absolute errors obey, for away from the turning point,(b) Growing connection. There is a second exact solution , linearly independent of , withu_{\mathrm{grow}}(\xi)=C'\,(W(\xi)-\lambda)^{-1/4} e^{+\Sigma(\xi)}\bigl(1+\delta_{\mathrm{f,grow}}(\xi)\bigr)\qquad(\xi>\xi_{0}),$$$$u_{\mathrm{grow}}(\xi)=C'\,(\lambda-W(\xi))^{-1/4} \Bigl(\cos\bigl(\theta(\xi)+\tfrac{\pi}{4}\bigr)+\delta_{\mathrm{a,grow}}(\xi)\Bigr) \qquad(\xi<\xi_{0}), for a real constant , with away from ; (c) Derivative and envelope control. Let and be the Airy functions in Airy envelopes and asymptotic coefficients, let , and put$$ f_h(\zeta):=(1+|\zeta|/h^{2/3})^{-1/4},\qquad \phi_h(\zeta):=\frac{2(\zeta_+)^{3/2}}{3h}.
e_h^-(\zeta):=f_h(\zeta)e^{-\phi_h(\zeta)},\quad d_h^-(\zeta):=h^{-2/3}f_h(\zeta)^{-1}e^{-\phi_h(\zeta)},\quad e_h^+(\zeta):=f_h(\zeta)e^{\phi_h(\zeta)},\quad d_h^+(\zeta):=h^{-2/3}f_h(\zeta)^{-1}e^{\phi_h(\zeta)}. For each transformed coordinate $\eta\in\zeta([\xi_0-r_0,\xi_0+s_0])$, define $w_{\mathrm{dec}}(\eta):=u_{\mathrm{dec}}(\zeta^{-1}(\eta))/a(\zeta^{-1}(\eta))$ and $w_{\mathrm{grow}}(\eta):=u_{\mathrm{grow}}(\zeta^{-1}(\eta))/a(\zeta^{-1}(\eta))$. For the solutions chosen as in the proof, the following transformed derivative error bounds hold on the full transformed interval, with an error constant $C_{\mathrm{err}}$ depending only on the fixed data and not on $h$: $ |w_{\mathrm{dec}}'-A_h'|\le C_{\mathrm{err}} d_h^-(e^{\varepsilon(h)}-1),\qquad |w_{\mathrm{grow}}'-B_h'|\le C_{\mathrm{err}} d_h^+(e^{\varepsilon(h)}-1). $ Here $\varepsilon(h):=\varepsilon_h$ is the control parameter of [F3] and satisfies $\varepsilon(h)\le C_1h$; the corresponding value errors are bounded by $C_{\mathrm{err}}e_h^-(e^{\varepsilon(h)}-1)$ and $C_{\mathrm{err}}e_h^+(e^{\varepsilon(h)}-1)$. Here primes on $w_{\mathrm{dec}},w_{\mathrm{grow}},A_h,B_h$ denote $\eta$-derivatives, and primes on $a,\zeta$ denote $\xi$-derivatives. Consequently, |u_{\mathrm{dec}}'(\xi)-a'(\xi)A_h(\zeta(\xi))-a(\xi)\zeta'(\xi)A_h'(\zeta(\xi))|\le C_{\mathrm{err}}\bigl(|a'(\xi)|e_h^-(\zeta(\xi))+|a(\xi)|\zeta'(\xi)d_h^-(\zeta(\xi))\bigr)(e^{\varepsilon(h)}-1), $$$$ |u_{\mathrm{grow}}'(\xi)-a'(\xi)B_h(\zeta(\xi))-a(\xi)\zeta'(\xi)B_h'(\zeta(\xi))|\le C_{\mathrm{err}}\bigl(|a'(\xi)|e_h^+(\zeta(\xi))+|a(\xi)|\zeta'(\xi)d_h^+(\zeta(\xi))\bigr)(e^{\varepsilon(h)}-1).For $\rho(\xi):=W(\xi)-\lambda>0$ on the forbidden side and $p(\xi):=\sqrt{\lambda-W(\xi)}>0$ on the allowed side, the scaled slope forms on every compact section bounded away from $\xi_0$ areh\rho(\xi)^{-1/4}u_{\mathrm{dec}}'(\xi)=C e^{-\Sigma(\xi)}\bigl(-1+\delta_{\mathrm{f,dec}}^{(1)}(\xi)\bigr),\qquad h\rho(\xi)^{-1/4}u_{\mathrm{grow}}'(\xi)=C'e^{\Sigma(\xi)}\bigl(1+\delta_{\mathrm{f,grow}}^{(1)}(\xi)\bigr),hp(\xi)^{-1/2}u_{\mathrm{dec}}'(\xi)=2C\bigl(-\cos(\theta(\xi)+\tfrac{\pi}{4})+\delta_{\mathrm{a,dec}}^{(1)}(\xi)\bigr),\qquad hp(\xi)^{-1/2}u_{\mathrm{grow}}'(\xi)=C'\bigl(\sin(\theta(\xi)+\tfrac{\pi}{4})+\delta_{\mathrm{a,grow}}^{(1)}(\xi)\bigr).$$ Each new slope error is absolute and satisfies ; in particular no relative error at a sine or cosine zero is asserted.
(d) Content of the connection. The factors in the decaying allowed-side form of (a) and in the growing allowed-side form of (b) are the amplitude relations of the exact Airy pair: the forbidden-side data determine the constants and , and the allowed-side oscillations are the sine and cosine forms with phase measured from the turning point into the allowed region. The statement excludes rectangular walls, coalescing or multiple turning points, multi-turn resonances and barrier-top uniformity; it asserts no transmission or reflection coefficient (that is a separate statement requiring hypothesis (W2)), no wave packet, no detector and no measured value; the errors are absolute and blow up as the turning point is approached, as displayed by the term.
Facts & Assumptions
Given: the WKB regime model with its data; hypothesis (W3) with ; the functions ; the Axiom of Countable Choice.
Liouville transformation. For near with a single simple zero of at , , the substitution , , transforms the model equation into on the transformed interval, with continuous and bounded, , with , and constants depending only on and the interval (Liouville turning-point transformation clauses (a)-(c)).
Airy asymptotics and envelopes. The entire Airy functions of Airy contour and Fresnel normalization and Airy envelopes and asymptotic coefficients satisfy , for with , the exponential asymptotics and , the Wronskian , and envelope bounds with and (Airy contour and Fresnel normalization clauses (c), (d), Airy envelopes and asymptotic coefficients clauses (a)-(c)).
Stable Volterra connection. Put and , and use , , and . The decaying envelopes are and , while the growing envelopes are and . The stable control parameter is , with constants depending only on the fixed equation and interval. The solution with terminal Airy data at the right endpoint satisfies and ; the growing branch with Airy data at satisfies the analogous value and derivative bounds with . The connection between the forbidden-side exponential forms and the allowed-side oscillatory forms carries the absolute error bounded by the respective value and derivative envelopes times (Stable weighted Airy Volterra connection clauses (a)-(c), including its Facts & Assumptions (F3)).
Allowed-region transfer on the oscillatory side. On a closed subinterval of the allowed side bounded away from , the exact solutions are compared with their leading WKB waves by WKB explicit error, with the Gronwall factor of that theorem; the side's scaled momentum is and its local wavenumber in is (The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading clause (c)).
Model identification. The physical potential and energy are , , and the model equation is , so the equation, turning points and functions have the displayed dimensionless data (The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading clauses (b), (c)). For either allowed or forbidden action from to a fixed point on the corresponding side, apply Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent clause (b)(i) or (b)(ii) after removing a -neighborhood of . The square-root integrand extends continuously with value zero at the simple turning point, so letting gives the same physical-to-dimensionless identity for the displayed phase and exponent.
Proof
Given: the data of the statement and [F1]-[F5].
[Transformed equation] By [F1] applied to (with of the sign of because and is the single zero) the model equation is equivalent to under , with exactly the displayed Liouville variable and ; all constants depend only on the model's data and the interval.
[Matched solutions and forbidden forms] By [F3], take with Airy data at the right endpoint and with Airy data at ; put and similarly for the growing branch. These are exact solutions by [F1]. On the forbidden side, and . Thus [F2] and the value bounds of [F3] give the forbidden forms with and ; the relative forbidden errors are bounded by a constant times on the stated matching sections. These constants are nonzero for each , while the error constants depend only on the fixed data.
[Independence for sufficiently small h] At , [F3] gives and , since and and . The growing data there are exactly , with and by [F2]. Consequently their Wronskian at zero is , nonzero when is sufficiently small because . Its derivative is zero for the common equation , so it is nonzero throughout. The invertible Liouville transformation preserves independence. Choose small enough for this and the supplied estimates.
[Allowed forms with additive errors] For , and . The Airy formulas of [F2] therefore give and . Adding the envelope-controlled differences of [F3] yields exactly the additive errors of (a),(b), including at sine or cosine zeros. If needed [F4] transports the data across any further fixed allowed matching section and adds its controlled error. The amplitudes are and ; no relative error at an oscillatory zero is asserted.
[Derivative bounds] For the decaying branch use the envelopes of the Statement; for the growing branch use . The chain rule gives, with or respectively, . The value and derivative bounds of [F3] therefore yield the two displayed transformed derivative error inequalities. To convert the Airy references to the slopes in the Statement, use and differentiate only the explicit leading amplitudes: on the forbidden side, ; on the allowed side, and . At each fixed section away from , are bounded below, so the amplitude-derivative terms are ; [F2]'s Airy derivative expansions and the transformed derivative estimates supply the remaining absolute errors , including at oscillatory zeros. No derivative of an unspecified error term is taken.
[Scope and identifications] The only hypotheses used are (W3), the local regularity of and the single simple zero at , which are exactly the hypotheses of [F1]-[F4]; no further turning point, no wall and no resonance condition was used. The physical phase integrals and the correspondence with the line model are those of [F5], and the units are the model's. This proves clause (d).
Remarks
- Orientation. The phase and exponent are both measured from the turning point outward into the respective region; with this convention the decaying solution's allowed-side form is the sine with , and the growing solution's is the cosine, exactly as in the Airy asymptotics of [F2]. Replacing the signed phase by interchanges the leading forms because and . A coordinate reflection with the outward nonnegative phase convention retains the same sine and cosine assignments.
- Use on this page. The barrier-transmission theorem of this page uses the decaying connection on both sides of a separated barrier; the error control of clause (c) is what makes the two matching errors comparable.
Separated smooth-barrier tunnelling: the declared transmission coefficient is exp(-2S/h) up to explicit small-h and barrier-thickness errors
The separated smooth-barrier transmission statement for the declared WKB regime model: the declared transmission coefficient equals the exponential of minus twice the barrier WKB exponent per unit h, with the quantitative small-h and exponentially small correction bound of the cited theorem, and the physical exponent is (1/hbar) times the classical action integral over the forbidden region. The statement is conditional on a fixed compactly supported C^5 barrier with exactly two separated simple turning points; it excludes rectangular walls, coalescing turning points, barrier-top uniformity and resonant multiwell interference, and it asserts no detector, wave packet or measured transmission.
Statement
Adopt the declared WKB regime model of The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading with its data and assume hypothesis (W2): has exactly two zeros on , both simple, is strictly positive on and strictly negative on . Put and let be the model's declared transmission coefficient of its clause (d). Then there are , an for , and a constant , both depending only on the model's barrier data and the fixed matching sections, such that whenever the denominator is positive; consequently In the physical variables of the line model, where and , one has by Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent clause (b) so the displayed leading factor is , the exponential of minus twice the classical action integral of the forbidden region in units of . The statement is conditional on the fixed compactly supported barrier with two separated simple turning points; rectangular walls, coalescing turning points, barrier-top uniformity and resonant multiwell interference are excluded, and is the declared scattering-current ratio of the model, not a detector response or a measured count; no wave packet, preparation, apparatus or sampling model is asserted. In particular, for each fixed barrier,
Facts & Assumptions
Given: the WKB regime model and hypothesis (W2); the exponent ; the declared transmission coefficient of the model clause (d); the Axiom of Countable Choice.
Exact local connection data. Under (W3), the one-turn theorem supplies real exact decaying and growing solutions, normalized by dividing by their nonzero forbidden-side constants. On each fixed section away from the turn, their allowed-side values are respectively and , their forbidden-side values are respectively and , and the corresponding derivative estimates have the same control after scaling the derivative by . Here on the allowed side, on the forbidden side, and is the action from the turn divided by . This is Airy connection across a single simple turning point of the declared regime model, with envelope error control clauses (a)-(c), with reflection at a turn whose derivative is negative.
Exterior and interior coordinates. The potential profile is zero on neighborhoods of and , so there. At a fixed interior point , and the scaled state satisfies , where . These are algebraic identities.
Physical exponent identity. The exact nondimensionalisation lemma gives on compact subintervals strictly inside the forbidden interval; the identity extends to the turning endpoints by continuity of the square-root integrands (Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent clause (b)).
Proof
Given: the data of the statement and [F1]-[F3].
Throughout this proof, for scalars, vectors or matrices means a quantity whose absolute value or stated norm is bounded by as , where depends only on the fixed barrier data and the fixed sections, not on .
[Hypothesis matching] Under (W2), has one simple zero with positive derivative and one simple zero with negative derivative. Since is compactly supported and outside , ; choose with , so the fixed exterior points and lie in allowed intervals and near them. Fix the interior point . The intervals and contain respectively only the left and right simple turning point, so [F1] applies on each, with reflection of the coordinate on the right.
[Physical exponent] For , the closed interval lies strictly inside the forbidden region, so there and [F3] applies. Both square-root integrands extend continuously to the turning endpoints with value zero. Letting , the omitted endpoint integrals tend to zero because their integrands are continuous and bounded on compact intervals. Thus with , , as in the Statement.
[Exact scattering amplitudes and current ratio] Put and define for and for , extending each to by its Cauchy data. The first-order system for has continuous bounded coefficients on this compact interval for each fixed ; its Picard iterates converge uniformly, with the th iterate bounded by , and the same estimate proves uniqueness. Hence are exact solutions. Because is real, . The exterior waves have currents , , and . Thus at the left exterior there are unique coefficients with ; direct expansion of the two plane-wave currents cancels their cross terms and gives , so . The model's unique unit-incoming solution is , with and , hence . Also , so . This derives the exact normalization and the current-ratio formula used in clause (d) of the WKB model.
[Exterior-to-turning-point basis conversion] Let on the allowed sides, , , and define the outward phases [F1, algebra] so . Divide the exact local decaying and growing solutions from [F1] by their nonzero forbidden-side constants and call them . At , put . The fixed-section value and derivative errors in [F1] are : there is fixed, , and . The Airy derivative asymptotics and chain rule give for the normalized allowed-side forms because the amplitude derivative contributes only at a fixed section. Hence, after the displayed scaling of , The exact exterior outgoing plane wave satisfies for some , since it has the same constant amplitude and phase derivative there. The leading basis matrix and its determinant are and . Since the entries of are uniformly bounded and the exact matrix is , for all sufficiently small it is invertible with uniformly bounded inverse; solving its exact two-component system yields coefficients . Equality of Cauchy data and ODE uniqueness then give This derives the incoming/outgoing coefficient formulas from the explicit matrices.
[Interior Wronskian] Put on the barrier and [step 1.4, F1, F2, algebra] Both are positive. At use the common state . The normalized forbidden-side value and slope forms of [F1] give Indeed and at the fixed point. Differentiating only the explicit leading forbidden envelopes gives The last terms are because and is fixed there; the derivative error from [F1] has the same scaled order. Thus the value and slope vector errors above are indeed without differentiating an unspecified error term. Since , expand it using the exact identities of step 1.4. The determinant is . The leading vectors in each mixed determinant coincide, so those terms are and ; relative to these are at most and . The term is . After including the coefficients from step 1.4 and the phases , this yields All constants depend only on the fixed barrier data and sections; no exponentially ill-conditioned matrix is inverted.
[Quantitative transmission error] Write the relative error in step 2.1 as ; then with and after enlarging a fixed constant. Because , , so whenever , [step 1.3, step 2.1, algebra] Choose with large enough to dominate the fixed matching errors in steps 1.4-2.1; after increasing as needed, this is the quantitative bound of the Statement with . It implies and for the fixed barrier.
[Scope] The proof uses only the declared smooth compactly supported profile, its two separated simple turning points, the local Airy connections and the exact boundary-defined scattering solution. It uses no rectangular wall, coalescing or multiple turn, barrier-top uniformity, resonant multiwell, wave packet, detector, apparatus or sampling assumption. Thus the claimed exclusions and scope hold.
Remarks
- Convention note. The cited tunnelling theorem is stated in the nondimensional convention standard in this run's controlled-dynamics mathematics, in which the second-order equation carries the small parameter and the factors are numerical; the identification of [F3] makes that convention exact for the model's dimensionless equation. The physical exponent identity of the statement is then supplied by the nondimensionalisation lemma and involves no approximation.
- The exponential is only the leading factor. The statement controls the correction by ; in particular the prefactor of the exponential is for a smooth barrier, and no statement about rectangular profiles (whose prefactor can differ) is made.
What the controlled-approximations page adopts, proves and does not claim: gaps, branch populations, turning points and the static-Stark limitation
A scope and status record for the controlled-approximations page: the adopted model clauses, the proved conditional statements with their gap, smoothness and boundedness hypotheses, the explicit exclusions (equilibration and branch selection, unbounded and static-field perturbations, rectangular and coalescing turning-point configurations, detectors and measurements), and the absence of any empirical record on this page.
Remarks
-
Adopted model clauses. The page declares three models: the variational trial model The declared variational trial reading: assigned energy observable, form domain, trial value, bottom and gap (a self-adjoint energy observable bounded below, its form domain and trial value), the perturbed family The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster (a bounded self-adjoint perturbation of a gapped isolated label) and the WKB regime model The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading (the nondimensionalised one-dimensional stationary equation with a declared semiclassical parameter and a compactly supported potential), plus the static finite-level dipole coupling Static finite-level electric-dipole coupling: compressed dipole of the declared two-body Coulomb model in a uniform field. Each declaration is a model assumption; none is derived from P1-P7.
-
What is proved. Conditional on those declarations the page proves: the trial lower bound, the gap-overlap control and the min-max characterisation of the discrete ladder (Variational trial bounds, gap-overlap control and the min-max characterisation of the declared model's discrete eigenvalues); the nondegenerate perturbation expansion with explicit cubic remainder (Nondegenerate stationary perturbation of a simple gapped label: first- and second-order coefficients and an explicit cubic remainder); the degenerate first-order splitting localisation within (Degenerate stationary perturbation: the perturbed eigenvalues stay within 4 lambda^2 v^2/g of the first-order shifts, and no branch relaxation is asserted); the allowed-region WKB Gronwall error (WKB approximation on an allowed interval of the declared regime model: explicit Gronwall error bound away from turning points); the single simple-turning-point Airy connection with envelope errors (Airy connection across a single simple turning point of the declared regime model, with envelope error control); and the separated smooth-barrier transmission asymptotics (Separated smooth-barrier tunnelling: the declared transmission coefficient is exp(-2S/h) up to explicit small-h and barrier-thickness errors). Every one of these statements carries its hypotheses explicitly: the gap , the boundedness of the perturbation, the smoothness of , the separation of the turning points, and the value of the semiclassical parameter.
-
No attained ground state is assumed. The variational statements use the form domain and the declared spectral lower bound; they do not assume that the bottom is an eigenvalue, that a ground eigenvector exists, or that the trial infimum is attained. The gap-overlap clause is the only place where an isolated bottom is used, and it states exactly the overlap forced by a trial value within of the bottom.
-
No branch population or equilibration. The perturbation theorems locate spectral labels of the declared families; they assert no instantaneous transition of a preparation to the branch with the smallest first-order shift, no relaxation to a lowest branch and no equilibration. The motivating textbook conjecture of a jump to the lowest branch is not imported. For each fixed coupling , P4 assigns the autonomous flow ; it commutes with the spectral projections of that fixed operator, so their populations are fixed by the initial preparation. The textbook conjecture instead concerns a time ramp : P4 supplies no propagator for that ramp and gives no conservation law for its instantaneous spectral-branch populations (Autonomous dynamics postulate P4: self-adjoint generators and unitary evolution clauses (ii), (iv)). Such a question requires separately specified driven dynamics; an equilibration statement would require a separately declared environment or dissipation model, which this page does not supply.
-
Turning points and barriers. The allowed-region error excludes turning points by hypothesis; the connection theorem treats a single simple turning point and does not produce a transmission coefficient; the barrier theorem assumes exactly two separated simple turning points of a compactly supported barrier and excludes rectangular walls, coalescing turning points, barrier-top uniformity and resonant multiwell interference. The declared transmission coefficient is a matching datum of the model, not a detector response.
-
The static-Stark limitation. For , the uncompressed static perturbation of a Coulomb model by a uniform field is the unbounded multiplication term . The common-test-domain calculation in Static finite-level electric-dipole coupling: compressed dipole of the declared two-body Coulomb model in a uniform field translates a normalized fixed to , where . Its kinetic expectation is constant, its Coulomb integral is bounded by , and the linear term contains ; hence the operator expectations tend to on the explicit common test domain. No quadratic form bounded below there can agree with those values, although no particular closed-form domain is asserted. No bounded-perturbation theorem of this page applies to that nonzero-field interaction. At , the maximal interaction is the bounded zero operator on ; is not defined, and the preceding translation argument and bounded-perturbation exclusion do not apply. This page covers only the compressed finite-level operator of Static finite-level electric-dipole coupling: compressed dipole of the declared two-body Coulomb model in a uniform field, and it states no eigenvalue theorem for the uncompressed model.
-
Empirical status. No experiment, reported observation, measured shift, splitting, transmission or count appears on this page; no apparatus, calibration, sampling or uncertainty record is supplied. The statements are conditional predictions of the declared models. A comparison with data would test the combined assumptions -- preparation, isolation, parameter identification, truncation, field description and detection response -- under the preparation and apparatus discipline P7 (Preparation and apparatus postulate P7: declared preparations, isolation and sampling assumptions); agreement would be evidence about that combination, not a deductive proof of the model, and a discrepancy would require the auxiliary assumptions to be examined before the model is rejected.
5 · Examples, experiments and counterexamples
None yet.
Sources
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 11.6 printed pages 253-254 (PDF pages 261-262): the WKBJ equation d^2 psi/dx^2 = -k^2 psi with k^2 = 2m(E-V)/hbar^2 and the phase phi(x) = int k dx
- R. Fitzpatrick, Quantum Mechanics (University of Texas at Austin, author-hosted course text), Section 5.4 'WKB Approximation' printed and PDF pages 70-72 (the one-dimensional WKB solution with the local wavenumber and the phase integral, in the same reduced equation)
- G. Teschl, Mathematical Methods in Quantum Mechanics, 1st edition 2009, Section 6.6: contour perturbation; finite-rank extension proved locally here
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 9.2 printed page 212 (PDF page 220): Rayleigh's theorem, the upper bound <H> >= E0 for any state and the variational principle for a trial wavefunction
- B. Zwiebach, MIT 8.05 Quantum Physics II (Fall 2013), Chapter 1 'Wave Mechanics', Section 5 printed pages 19-21 (PDF pages 18-20): the trial-wavefunction upper bound E_gs <= <H>_psi (5.13) and the unnormalised functional F[psi] (5.20)
- G. Teschl, Mathematical Methods in Quantum Mechanics, 1st edition 2009, Section 4.3 printed pages 117-119 (PDF pages 129-131): the min-max theorem below the essential spectrum and the form-domain reading of the trial family
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 9.1 printed pages 203-211 (PDF pages 211-219): time-independent perturbation theory, the first- and second-order energy shifts, the quadratic Stark effect and the degenerate-subspace diagonalisation of the perturbation (9.4)-(9.18)
- G. Teschl, Mathematical Methods in Quantum Mechanics, 1st edition 2009, Chapter 6 printed pages 133-159 (PDF pages 145-171): relatively bounded operators, the Kato-Rellich theorem (Theorem 6.4) and norm resolvent convergence for bounded perturbations
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 11.6 printed pages 253-254 (PDF pages 261-262): the WKBJ equation with k^2 = 2m(E-V)/hbar^2, the phase phi = int k dx, the slowly varying condition and the flux-conserving WKBJ wavefunction
- R. Fitzpatrick, Quantum Mechanics (University of Texas at Austin, author-hosted course text), Sections 5.4-5.6 printed and PDF pages 70-75: 5.4 WKB Approximation pp. 70-72, 5.5 Cold Emission pp. 72-73, 5.6 Alpha Decay pp. 73-75 (WKB wavefunctions in allowed and forbidden regions, turning points and barrier transmission)
- G. Teschl, Mathematical Methods in Quantum Mechanics, 1st edition 2009, Section 9.7 printed pages 214-220 (PDF pages 226-232): the spectra and relative bounds and spectra of one-dimensional Schrodinger operators (background only; no Airy connection or barrier-transmission theorem)
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 9.1.1 printed pages 205-206 (PDF pages 213-214): the energy change delta E = e(Phi(xp)-Phi(xe)) of the atom in an external field, the long-wavelength reduction delta E = er.E (9.13) and the perturbing term Delta = eEz (9.14)
- B. Zwiebach, MIT 8.05 Quantum Physics II (Fall 2013), Chapter 7 'Two State Systems', Section 5 'Ammonia molecule in an electric field' printed and PDF pages 11-16: the energy E = -mu.E of a dipole in an electric field (5.1), the two-state ammonia Hamiltonian H = E0 I - Delta sigma1 + muE sigma3 (5.2) and the exact eigenvalues E0 +/- sqrt(mu^2 E^2 + Delta^2) (5.3)
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 9.2 printed pages 212-213 (PDF pages 220-221): Rayleigh's theorem, the bound <H> >= E0 and the variational principle with a parameter-dependent trial wavefunction
- B. Zwiebach, MIT 8.05 Quantum Physics II (Fall 2013), Chapter 1 'Wave Mechanics', Section 5 printed pages 19-21 (PDF pages 18-20): E_gs <= <H>_psi for a normalised trial wavefunction (5.13) and the functional F[psi] (5.20)
- G. Teschl, Mathematical Methods in Quantum Mechanics, 1st edition 2009, Section 4.3 printed pages 117-119 (PDF pages 129-131): the min-max theorem (Theorem 4.10) with the form-domain remark, and Section 4.4 printed pages 119-121 (PDF pages 131-133): eigenspace estimates
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 9.1 printed pages 203-205 (PDF pages 211-213): the perturbative expansions (9.2)-(9.11), the first-order shift E_b = <E0|Delta|E0> (9.6) and the second-order shift (9.11), derived under the non-degeneracy assumption
- G. Teschl, Mathematical Methods in Quantum Mechanics, 1st edition 2009, Section 6.6 printed pages 153-159 (PDF pages 165-171): strong and norm resolvent convergence and the analytic perturbation consequences for bounded perturbations
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 9.1.2 printed pages 206-208 (PDF pages 214-216): the failure of the non-degenerate expansion at a degenerate level, the diagonalisation of the perturbation eEz within the four-dimensional n=2 subspace and the eigenvalues +/-3eEa0 and 0
- G. Teschl, Mathematical Methods in Quantum Mechanics, 1st edition 2009, Section 6.6 printed pages 153-159 (PDF pages 165-171): resolvent convergence, perturbed spectral projections and the localisation of perturbed eigenvalues for bounded perturbations
- R. Fitzpatrick, Quantum Mechanics (University of Texas at Austin, author-hosted course text), Section 5.4 'WKB Approximation' printed and PDF pages 70-72 (the WKB function in the classically allowed region, the amplitude condition and the validity discussion)
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 11.6 printed pages 253-254 (PDF pages 261-262): the slowly varying amplitude equation d ln S/dx = -(1/2) d ln k/dx, its integral and the flux-conserving WKBJ wavefunction (11.40)
- F. W. J. Olver, Asymptotics and Special Functions (1974), Chapter 11 (connection formulas and error bounds for Airy-type equations; standard monograph), consulted through the NIST DLMF survey of Airy asymptotics
- NIST Digital Library of Mathematical Functions, Section 9.7 'Asymptotic Expansions' (oscillatory and exponential Airy asymptotics with the phase pi/4 and envelope bounds)
- NIST Digital Library of Mathematical Functions, Section 9.2 'Differential Equation' (Airy's equation and the standard solutions Ai, Bi)
- R. Fitzpatrick, Quantum Mechanics (University of Texas at Austin, author-hosted course text), Sections 5.3-5.6 printed and PDF pages 64-75: 5.3 Square Potential Barrier p. 64, 5.4 WKB Approximation p. 70, 5.5 Cold Emission p. 72, 5.6 Alpha Decay p. 73 (barrier penetration and the WKB tunnelling exponent)
- F. W. J. Olver, Asymptotics and Special Functions (1974), Chapter 11 (connection formulas and barrier penetration for second-order equations with two turning points; standard monograph), consulted through the NIST DLMF Airy survey
- J. Binney and D. Skinner, The Physics of Quantum Mechanics, Section 9.1.2 printed pages 206-208 (PDF pages 214-216): the degenerate-subspace diagonalisation of the perturbation, together with the conjecture that the system 'jumps' to the lowest branch, which is not imported as a deduction
- G. Teschl, Mathematical Methods in Quantum Mechanics, 1st edition 2009, Section 4.3 printed pages 117-119 (PDF pages 129-131) and Section 6.6 printed pages 153-159 (PDF pages 165-171): the min-max theorem and the bounded-perturbation resolvent estimates on which the page's conditional statements rest