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Qm Controlled Approximations

1 · Prerequisites

2 · Summary

This page declares the framework's controlled-approximation models and proves their conditional statements: the variational trial reading of an assigned energy observable, the bounded stationary perturbation of a gapped isolated label, and the semiclassical WKB regime of a one-dimensional stationary equation. It states every approximation with its controls: form domains and spectral lower bounds for the variational bounds, isolated gaps and quantitative smallness for perturbation theory, and smoothness, simple separated turning points and an explicit semiclassical parameter for the WKB regime.

The supporting mathematics comes first. Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent is the exact nondimensionalisation identity that transfers the physical line-model equation, forbidden-region exponent and allowed-region phase into the dimensionless equation carrying the semiclassical parameter h. The declared variational trial reading: assigned energy observable, form domain, trial value, bottom and gap declares the variational reading: a self-adjoint energy observable bounded below, its form domain Q(H) and form qH, the model bottom E0, a bottom gap and the discrete ladder below the essential spectrum. The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster declares the perturbed family H(λ)=H0+λV with a bounded self-adjoint perturbation, the isolated finite-multiplicity label with its gap, the first-order operator P0VP0 and the followed perturbed label of the contour construction. The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading declares the WKB regime model: a compactly supported C5 potential, the reference scales and dimensionless parameter h=ℏ/(ℓ2mE⋆), the turning-point vocabulary and the declared barrier transmission reading. Static finite-level electric-dipole coupling: compressed dipole of the declared two-body Coulomb model in a uniform field adopts the compressed finite-level dipole coupling of the declared Coulomb pair in a uniform static field, with the uncompressed linear potential explicitly excluded.

Variational trial bounds, gap-overlap control and the min-max characterisation of the declared model's discrete eigenvalues proves the trial lower bound qH[u]≥E0, the gap-overlap control ∥(I−P)u∥2≤ε/g for trial values within ε of an isolated bottom, and the min-max characterisation of the model's discrete ladder. Nondegenerate stationary perturbation of a simple gapped label: first- and second-order coefficients and an explicit cubic remainder proves the existence, reality and analyticity of the followed label, the first- and second-order coefficients with the reduced inverse of the full complementary spectral subspace and the explicit cubic remainder bound. Degenerate stationary perturbation: the perturbed eigenvalues stay within 4 lambda^2 v^2/g of the first-order shifts, and no branch relaxation is asserted localises every perturbed eigenvalue within 4λ2v2/g of E+λspec⁡(P0VP0) and states explicitly that no branch selection or relaxation is deduced. WKB approximation on an allowed interval of the declared regime model: explicit Gronwall error bound away from turning points gives the Gronwall error of the WKB wave on an allowed interval away from turning points; Airy connection across a single simple turning point of the declared regime model, with envelope error control proves the Airy connection across a single simple turning point with envelope error control; and Separated smooth-barrier tunnelling: the declared transmission coefficient is exp(-2S/h) up to explicit small-h and barrier-thickness errors proves the separated smooth-barrier transmission law T(h)=e−2S/h(1+O(ε(h)+e−2S/h)) with its physical exponent. What the controlled-approximations page adopts, proves and does not claim: gaps, branch populations, turning points and the static-Stark limitation records what the page adopts, proves and excludes, including the static-Stark limitation and the absence of any empirical record on this page.

3 · Logical flowchart

4 · Definitions, postulates, theorems and proofs

LemmaStatement: AI-adaptedProof: AI-adaptedprecheck passOpen item page →

Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent

Statement

Let ℓ>0 and E⋆>0 be real reference scales, let m>0 and ℏ>0 be real, and define h:=ℏℓ2mE⋆>0. Let I⊆R be a nonempty open interval, let W∈C2(I;R), let λ∈R, and let u:I→C be a function. Then:

(a) u is of class C2 on I and satisfies u′′(ξ)=W(ξ)−λh2 u(ξ)(ξ∈I) if and only if the function ψ:ℓI→C, ψ(x):=u(x/ℓ), is of class C2 on the open interval ℓI={ℓξ:ξ∈I} and satisfies −ℏ22m ψ′′(x)+E⋆W(x/ℓ) ψ(x)=E⋆λ ψ(x)(x∈ℓI);

(b) if a<b are points of I, then each of the following identities holds under its indicated strict-sign hypothesis:

(i) if W(ξ)−λ>0 for every ξ∈[a,b], then 1h∫abW(ξ)−λ dξ=1ℏ∫ℓaℓb2m(E⋆W(x/ℓ)−E⋆λ) dx;

(ii) if λ−W(ξ)>0 for every ξ∈[a,b], then 1h∫abλ−W(ξ) dξ=1ℏ∫ℓaℓb2m(E⋆λ−E⋆W(x/ℓ)) dx.

All square roots here are the nonnegative real square roots of strictly positive numbers. Part (i) is the forbidden-region exponent identity; part (ii) is the allowed-region phase identity.

The identities are statements about the displayed functions and integrals only. The number h is dimensionless because ℏ is in J s and ℓ2mE⋆ is in kg m2 s−1=J s; no physical interpretation, no approximation and no error estimate is asserted here.

Facts & Assumptions

Given: the scales ℓ,E⋆,m,ℏ, the interval I, the functions W,u, the number λ, and the number h>0. For part (b), also take points a<b in I satisfying the strict-sign hypothesis for the part being proved.

[F2]

One-dimensional change of variables. If φ is C1 and injective on a neighbourhood of [a,b] with φ′≠0 there, and f is continuous on an interval containing φ([a,b]), then ∫min⁡φ([a,b])max⁡φ([a,b])f(y) dy=∫abf(φ(ξ))∣φ′(ξ)∣ dξ (In one dimension the compact-Jordan formula is substitution over the unoriented image interval with the absolute derivative).

Proof

technique · direct; differentiate the affine substitution twice by its chain rule and substitute the definition of $h$, then integrate by the one-dimensional change of variables in each strict-sign case

Given: the data of the statement and [F1]-[F2].

1.1F1

[Second derivatives under the substitution] Since ξ↦ℓξ is C1 with derivative ℓ and inverse x↦x/ℓ, the map ψ=u∘(⋅/ℓ) is C2 exactly when u is, and by [F1] applied twice, ψ′(x)=u′(x/ℓ)ℓ,ψ′′(x)=u′′(x/ℓ)ℓ2(x∈ℓI).

1.2givenalgebra

[The scale identity] From the definition of h and W, E⋆>0, h2=ℏ22mℓ2E⋆,hence1h2ℓ2=2mE⋆ℏ2.

1.3F2givenalgebra

[Forbidden-region exponent identity (b)(i)] On [a,b] the function x↦ℓx is C1 and strictly increasing with derivative ℓ>0, and the integrand f+(x):=2m(E⋆W(x/ℓ)−E⋆λ) is continuous on [ℓa,ℓb] because W−λ>0. By [F2] applied to φ(ξ)=ℓξ, ∫ℓaℓbf+(x) dx=ℓ2mE⋆∫abW(ξ)−λ dξ. Dividing by ℏ and using ℓ2mE⋆/ℏ=1/h gives (b)(i).

2.1step 1.1step 1.2algebra

[Forward implication of (a)] Suppose u is C2 with u′′=(W−λ)u/h2 on I. By step 1.1, ψ is C2 on ℓI and ψ′′(x)=u′′(x/ℓ)ℓ2=1ℓ2⋅W(x/ℓ)−λh2 u(x/ℓ)=2mE⋆ℏ2(W(x/ℓ)−λ)ψ(x), by step 1.2. Multiplying by −ℏ2/(2m) and bringing ψ terms to the left gives −(ℏ2/2m)ψ′′+E⋆W(x/ℓ)ψ=E⋆λψ on ℓI.

2.2step 1.1step 1.2algebra

[Converse implication of (a)] Suppose conversely that ψ is C2 with −ℏ22mψ′′+E⋆W(x/ℓ)ψ=E⋆λψ on ℓI. By step 1.1, u(ξ)=ψ(ℓξ) is C2 on I with u′′(ξ)=ℓ2ψ′′(ℓξ); substituting the assumed equation at x=ℓξ gives u′′(ξ)=ℓ2⋅2mℏ2(E⋆W(ξ)−E⋆λ)ψ(ℓξ)=2mℓ2E⋆ℏ2(W(ξ)−λ)u(ξ)=W(ξ)−λh2u(ξ), the last equality by step 1.2.

3.1F2givenalgebra∎

[Allowed-region phase identity (b)(ii)] If instead λ−W>0 on [a,b], then f−(x):=2m(E⋆λ−E⋆W(x/ℓ)) is continuous and real on [ℓa,ℓb]. The same change of variables gives ∫ℓaℓbf−(x) dx=ℓ2mE⋆∫abλ−W(ξ) dξ. Division by ℏ and the same scale identity prove (b)(ii), with the nonnegative real square roots justified by the strict sign hypothesis.

Remarks

  • Role of the lemma. The lemma is the exact bookkeeping that lets the dimensionless equation u′′=(W−λ)u/h2, in which the semiclassical parameter h is explicit, be read as the physical line-model equation with potential E⋆W(⋅/ℓ) at energy E⋆λ. Both the equation and the phase integral transfer exactly; no approximation is involved.
  • Small h. The regime h≪1 is the regime ℏ≪ℓ2mE⋆; the lemma itself makes no smallness assumption, and the error theorems that use smallness state it separately.
LemmaStatement: AI-adaptedProof: AI-adaptedOpen item page →

Finite-rank gapped spectral cluster under a bounded perturbation

Statement

Assume Countable Choice (The Axiom of Countable Choice (ACω)). Let H be an arbitrary complex Hilbert space (Hilbert space) and H0=H0∗ a self-adjoint operator on its exact dense domain D=D(H0) (Symmetric, self-adjoint and essentially self-adjoint operators). Let E∈R be an isolated eigenvalue with dist⁡(E,σ(H0)∖{E})≥g>0, and let its orthogonal spectral projection P0=EH0({E}) have finite rank r≥1. The PVM and gap calculus are those of CC spectral calculus on an arbitrary complex Hilbert space by compatible vector-local Cayley subspaces. Let V=V∗∈B(H) and v=∥V∥≥0 (A bounded linear operator between normed spaces, The operator norm as the least bound and as the unit-sphere or unit-ball supremum). Put Hλ=H0+λV on D, and define Ωv={{λ∈C:∣λ∣<g/(2v)},v>0,C,v=0. For λ∈Ωv write qλ=2∣λ∣v/g<1, Γ={z:∣z−E∣=g/2} oriented counterclockwise, and Δ={z:∣z−E∣<g/2}.

(a) Resolvent and exact domain. Hλ is closed and densely defined on D. Every z∈Γ is a resolvent point, with the convention Rλ(z)=(z−Hλ)−1:H→D of Resolvent and spectrum of an unbounded operator, and Rλ(z)=R0(z)∑k≥0(λVR0(z))k,∥Rλ(z)∥≤2/g1−qλ,∥Rλ(z)−R0(z)∥≤2gqλ1−qλ. The series converges in operator norm uniformly on Γ and locally uniformly in λ∈Ωv.

(b) Finite-rank holomorphic cluster. The norm contour integral Pλ=12πi∮ΓRλ(z) dz is a bounded idempotent of rank exactly r throughout Ωv, with Pλ=0=P0 and ∥Pλ−P0∥≤qλ/(1−qλ). It is holomorphic in operator norm. Its range Mλ=PλH lies in D and is invariant under Hλ, and PλHλ=HλPλ on D. Both HλPλ∈B(H) and Pλ:H→(D,∥x∥+∥H0x∥) are holomorphic in their respective operator norms.

(c) Exactly the enclosed spectrum. Let Aλ=Hλ∣Mλ:Mλ→Mλ. Then σ(Hλ)∩Δ=σ(Aλ)⊂Δ. This is a nonempty finite set of at most r eigenvalues. The restriction of w−Hλ to ker⁡Pλ has a bounded two-sided inverse on its exact domain D∩ker⁡Pλ for every w∈Δ. Consequently all generalized eigenvectors at an enclosed eigenvalue belong to Mλ; their eigenspaces and generalized eigenspaces are those of this finite-dimensional restriction.

(d) Real coupling and zero perturbation. For real λ, Hλ is self-adjoint on D. For real λ∈Ωv, Pλ=EHλ((E−g/2,E+g/2)) is the orthogonal projection on the entire enclosed spectral cluster (Projection valued measure). If v=0, then V=0, Hλ=H0 and Pλ=P0 for every complex coupling, with Aλ=EIM0 and enclosed spectrum {E}.

No separability or arbitrary-index Axiom of Choice is assumed. The claim supplies a cluster and its finite restriction; for r>1 it supplies no ordering or individually holomorphic scalar eigenvalue branches.

Facts & Assumptions

Given: CC; H,H0,D,E,g,P0,r,V,v,Ωv,λ,Γ,Δ as in the statement. Inner products are linear in the first argument. Contour integrals are operator-norm limits of Riemann sums.

[F1]

The CC arbitrary-Hilbert supplier CC spectral calculus on an arbitrary complex Hilbert space by compatible vector-local Cayley subspaces supplies the unique representing PVM, bounded Borel product/adjoint laws, exact square-integrability domains, concentration on the spectrum, spectral support equal to the spectrum and the distance resolvent bound. These are its current Statement and proof steps 4.1–6.2, rather than an AC global spectral decomposition. Its inverse is (H0−z)−1, with multiplier (t−z)−1; the convention here is R0(z)=−(H0−z)−1, with multiplier (z−t)−1. This sign conversion preserves its norm bound and exact range.

[F2]

The operator, domain and inverse conventions are those of Symmetric, self-adjoint and essentially self-adjoint operators, Resolvent and spectrum of an unbounded operator, A bounded linear operator between normed spaces and The operator norm as the least bound and as the unit-sphere or unit-ball supremum. Bounded operator spaces are complete: an operator-norm Cauchy sequence has a pointwise limit in the complete target Hilbert space, which is linear and bounded, and the same uniform Cauchy estimates give operator-norm convergence. If ∥B∥<1 the geometric series ∑k≥0Bk is the inverse of I−B, as multiplication of finite sums leaves the remainder BN+1→0.

[F3]

On a positively oriented circle about a, the integral of (z-a)^m is zero for every integer m except -1, and is 2 pi i for m=-1 and Cauchy's integral formula on a circle compactly contained in a disc of holomorphy supply scalar circle integrals and the Cauchy formula. Continuous scalar pairings and uniform norm limits give their bounded-operator versions. Finite-dimensional orthonormal bases require only finite Gram–Schmidt (Every finite-dimensional real or complex inner product space has an orthonormal basis); an injective map on an r-dimensional space sends a basis to r independent vectors, hence a basis, so is surjective; conversely a surjective map has r spanning images of a basis, which must be independent. A map B on a finite-dimensional Hilbert space is bounded because an orthonormal basis (ej) gives ∥Bx∥≤∑j∣⟨x,ej⟩∣∥Bej∥≤(∑j∥Bej∥2)1/2∥x∥, and this applies to its inverse when bijective.

Proof

Given: The data of the statement and [F1]–[F3].

1.1givenF1F2algebra

[Gap and correctly ordered Neumann inverse] By [F1], the spectral support of H0 is σ(H0). For z∈Γ, ∣z−E∣=g/2 and every other spectral point t has ∣z−t∣≥∣t−E∣−∣z−E∣≥g/2. Thus ∥R0(z)∥≤2/g. The operator Hλ is closed on D: if xn→x and Hλxn→y, then H0xn→y−λVx, so closedness of H0 gives x∈D and Hλx=y; the domain remains dense. On D, z−Hλ=(I−λVR0(z))(z−H0). Its first factor has the Neumann inverse [F2], since ∥λVR0(z)∥≤qλ<1. Therefore the displayed ordered series gives a two-sided inverse with range exactly D, and its geometric estimates give (a). Uniform convergence on the circle and each compact coupling subdisk proves norm holomorphy in λ; local inverse Neumann series give holomorphy in z on the resolvent set. When v=0 this series is constant for all couplings.

2.1step 1.1F2F3algebra

[Idempotence from two contours] Fix λ∈Ωv. Step 1.1 bounds the inverse uniformly on Γ, and another inverse Neumann series gives a resolvent annulus around it. Integrals of a holomorphic operator-valued function over concentric circles in that annulus are independent of radius: differentiating ∫02πf(E+ρeit)iρeit dt in ρ gives the integral of the periodic t derivative of f(E+ρeit)eit, hence zero. Take an outer circle for z and an inner circle for w. The inverse equations give Rλ(z)Rλ(w)=[Rλ(w)−Rλ(z)]/(z−w), and also commutation of resolvents. In its double integral, the first term integrates in the outer variable to the inner projection integral because ∮dz/(z−w)=2πi; the second integrates in the inner variable to zero because ∮dw/(z−w)=0. Compact continuous integrals can be interchanged by norm Riemann sums. Annular independence identifies both circle integrals with Pλ, proving Pλ2=Pλ. Resolvent commutation also gives PλRλ(z)=Rλ(z)Pλ.

3.1step 1.1step 2.1F2algebra

[Graph domains, commutation and holomorphy] The identity HλRλ(z)=zRλ(z)−I makes the contour integrand continuous into the complete graph space of the closed Hλ. Integrating there proves PλH⊂D and HλPλ=(2πi)−1∮ΓzRλ(z) dz=:Cλ∈B(H). On D the other inverse equation gives Rλ(z)Hλ=zRλ(z)−I, so integration gives PλHλ=Cλ there. Thus the range and kernel reduce the operator with its domain. The uniform coupling series makes both Pλ and Cλ norm holomorphic. Since H0Pλ=Cλ−λVPλ, the pair (Pλ,H0Pλ) is holomorphic into B(H,H⊕H) and takes values in the closed graph of H0; hence Pλ is holomorphic as an operator into that graph space. In particular, the finite restriction Aλ is well-defined on all of Mλ.

3.2step 1.1step 2.1F1F3algebra

[Initial projection and rank throughout the disk] At zero coupling use the sign conversion in [F1]: R0(z) has multiplier (z−t)−1, whose counterclockwise integral divided by 2πi is 1 inside and 0 outside. Thus the resolvent contour is the PVM projection on the real interior; its only unperturbed spectral point is E, so this is P0. This evaluation follows by spectral pairings: scalar circle kernels integrate to one inside and zero outside [F3]; norm Riemann sums converge uniformly in the spectral variable, since the spectrum is at distance at least g/2 from the circle, allowing interchange with its finite scalar measures. The circle length πg and step 1.1 give ∥Pλ−P0∥≤qλ/(1−qλ). If bounded idempotents P,Q have ∥P−Q∥<1, then x∈ran⁡P and Qx=0 imply ∥x∥=∥(P−Q)x∥<∥x∥ unless x=0; therefore Q∣ran⁡P is injective, and the reverse restriction is also injective. For s,t∈[0,1], the inverse equations give Rsλ(z)−Rtλ(z)=(s−t)λRsλ(z)VRtλ(z), hence ∥Psλ−Ptλ∥≤qλ∣s−t∣/(1−qλ)2. Choose an integer N>qλ/(1−qλ)2 and compare the finite path Pjλ/N, 0≤j≤N. At each adjacent pair the two injections and finite dimension imply equal rank. Starting with rank r proves rank r at λ, even when the direct distance estimate is at least one. If qλ=0 the path is constant.

4.1step 2.1step 3.1step 3.2F3algebra

[All spectral values of the finite restriction are inside] Put M=Mλ, A=Aλ, P=Pλ and Q=I−P. For z∈Γ, resolvent commutation and the inverse equations give Rλ(z)∣M=(z−A)−1 on M. If Au=αu with u≠0, then α∉Γ by those equations and Rλ(z)u=(z−α)−1u. The equation Pu=u and its contour definition give winding number one for α, so α∈Δ. In a finite basis of M, w−A is invertible exactly when its kernel is zero [F3]; thus every spectral point of A is an eigenvalue and lies in Δ. There are at most r distinct such points, since eigenvectors for distinct eigenvalues are linearly independent: in a shortest nontrivial relation among them, applying A−αI for one term removes that term and leaves a shorter nontrivial relation. There is at least one: otherwise (z−A)−1 is holomorphic throughout a neighborhood of the closed disk, and the scalar Cauchy formula [F3] makes its contour integral zero entrywise, contradicting its integral IM and r≥1. Here the zero integral follows by applying the Cauchy formula to (z−E)(z−A)−1 at E.

4.2step 2.1step 3.1F2F3constructalgebra

[Complementary inverse on its exact domain] For w∈Δ define B(w)=(2πi)−1∮ΓRλ(z)/(z−w) dz. As in step 3.1 its range lies in D. The identity (w−Hλ)Rλ(z)=I−(z−w)Rλ(z) gives (w−Hλ)B(w)=I−P on H; its right-hand counterpart gives B(w)(w−Hλ)=I−P on D. Resolvent commutation shows B(w) commutes with P,Q. The bounded map BQ(w)=QB(w)Q therefore maps QH into D∩QH and satisfies both inverse equations for w−Hλ on that exact complementary domain. No assertion that B(w)P=0 is needed. The idempotent splitting is H=M⊕QH and, since PH⊂D and P preserves D, its domain splitting is D=M⊕(D∩QH). The complementary domain is dense in QH, since applying the bounded Q to approximants from the dense D preserves D and approximates every vector of QH.

5.1step 3.1step 4.1step 4.2F2algebra

[Exactly the interior spectrum and generalized eigenspaces] If w∈Δ∖σ(A), then the bounded operator (w−A)−1P+BQ(w) maps H into D and is a two-sided inverse of w−Hλ by the domain splitting and step 4.2. If w∈σ(A), step 4.1 supplies a nonzero eigenvector in M, so w∈σ(Hλ). This proves σ(Hλ)∩Δ=σ(A), with its nonempty finite character from step 4.1. For such an eigenvalue α and an integer k≥1, any generalized eigenvector x∈D((Hλ−α)k) has Qx in the complementary iterated domain, because P,Q preserve D and commute with Hλ. Step 4.2 makes Hλ−α injective on the complement; its powers are then injective on their domains, so (Hλ−α)kQx=0 forces Qx=0. Conversely M⊂D is invariant, so every generalized eigenvector of A is a generalized eigenvector of the full operator. This proves (c), including the exact complementary inverse.

6.1step 1.1step 3.1step 3.2step 4.1step 4.2step 5.1F1F2algebra∎

[Real coupling, zero branch and assembly] The bounded-perturbation adjoint identity is D(Hλ∗)=D(H0∗)=D, Hλ∗=H0+λ‾V: subtract the everywhere-defined bounded term from the adjoint functional to identify exactly the domain of H0∗. Thus Hλ is self-adjoint for every real λ. For real λ∈Ωv, apply [F1] to this operator, again converting (Hλ−z)−1 to Rλ(z)=−(Hλ−z)−1 with multiplier (z−t)−1. Its spectrum misses the circle by step 1.1, so has positive distance from it by compactness of the circle and openness of the resolvent set. The same uniform scalar-kernel/Riemann-sum evaluation as in step 3.2 identifies Pλ with the PVM on the real interior, hence an orthogonal spectral projection on the entire cluster. If v=0, the norm definition gives V=0, all resolvents and projections are constant for every complex coupling, and the exact PVM domain gives H0P0=EP0; therefore the restriction is EI and its spectrum is {E}. Steps 1.1–5.1 give the other assertions for arbitrary H under CC, using only a finite path and finite bases; no individually ordered or holomorphic scalar branches have been introduced.

DefinitionDefinition: AI-adaptedProof: Not applicableOpen item page →

The declared variational trial reading: assigned energy observable, form domain, trial value, bottom and gap

Physical scope

The variational trial reading of a declared system of the framework: a self-adjoint assigned energy observable H bounded below, its form domain Q(H) and form q_H supplied by the cited spectral-form mathematics, the model bottom E(0) = inf sigma(H), an isolated bottom with a declared gap g and its spectral projection, the discrete eigenvalue ladder below the essential spectrum, and the declared vocabulary of trial vector and trial value. The definition asserts nothing about whether the bottom is attained, about any eigenvector, about any laboratory realization or identification, and about any measurement, apparatus or sampling model.

Definition

(a) Framework data. Adopt the state and composition postulate P1, the observable and probability postulate P2 and the autonomous-dynamics postulate P4 (State and composition postulate P1: Hilbert spaces, preparations and composite systems, Observable and probability postulate P2: self-adjoint observables, spectral probability and finite unsharp outcomes, Autonomous dynamics postulate P4: self-adjoint generators and unitary evolution) for a declared system, in the state reading of The state space of the framework: preparations, pure rays and density operators, the sharp observable reading of Assigned sharp observables and the outcome law of the framework and the evolution reading of Assigned energy observable, unitary flow and the two pictures of autonomous evolution; units are those of Dimensions, SI unit conventions and quantity types of the framework. Assume the Axiom of Countable Choice and the Axiom of Choice as the choice hypotheses of the cited mathematical suppliers (The Axiom of Countable Choice (ACω), The Axiom of Choice).

(b) Assigned energy observable. As an additional model assumption of the pair, fix a self-adjoint operator H:D(H)⊆H→H on the declared state space H and declare the pair (H,J) to be the system's sharp energy observable in the sense of Assigned sharp observables and the outcome law of the framework clause (a); this identification of the operator with the energy of the system is an assumption of the model, not a consequence of P1, P2 or P4. Assume H is bounded below: there is a real c with ⟨Hu,u⟩≥c∥u∥2 for every u∈D(H). The spectrum σ(H) is the set of the cited spectral theorem, and the model bottom is E0:=inf⁡σ(H)∈[c,+∞), read in joules. An assignment of a concrete material system to the pair (H,H) is a tested identification in the sense of the preparation and apparatus discipline P7 and is not made here.

(c) Form domain and trial value. Let Q(H):=D((H−cI)1/2) and qH be the form domain and the closed semibounded form of Spectral form domain and core of a semibounded operator for the lower bound c of clause (b), with qH[u]=∫Rλ dEu(λ)(u∈Q(H)), E the projection-valued measure of H and Eu(B)=⟨E(B)u,u⟩ (Spectral theorem for unbounded self-adjoint operators (PVM form), Projection valued measure). The definition uses the facts, proved by that lemma, that qH does not depend on the choice of the lower bound c, that D(H) is dense in Q(H), and that qH[u]=⟨Hu,u⟩ for u∈D(H). A trial vector of the model is a vector u∈Q(H) with ∥u∥=1; its trial value is qH[u], read in joules. For a trial vector that lies in D(H), the trial value is the mean energy of the pure preparation [u] under the observable (H,J) in the moment reading of Mean, second moment and variance of an assigned observable in a preparation; for a general trial vector in Q(H)∖D(H) the trial value is the form value and is not asserted to be the mean of any outcome law.

(d) Bottom gap and discrete ladder. If the bottom is an isolated spectral value, declare a gap to be a real g>0 with σ(H)∩(E0,E0+g)=∅, and put P:=E({E0}) for the bottom spectral projection. The discrete spectrum below the essential spectrum is the part of σd(H) of Discrete and essential spectrum of a self-adjoint operator below Λ:=inf⁡σess(H), listed with multiplicity in nondecreasing order as E1≤E2≤⋯, with the convention En:=Λ once the list is exhausted, inf⁡∅=+∞. The definition asserts neither that E0 is an eigenvalue, nor that any eigenvector exists. The ladder convention does give E0=E1: the nonempty closed spectrum of the bounded-below operator contains its bottom; if the bottom is discrete, it is the first listed eigenvalue, and otherwise it lies in the essential spectrum, so Λ=E0 and the empty below-threshold list is padded by E1=Λ. This equality does not imply that the bottom is attained by an eigenvector.

(e) Scope. Clauses (a)-(d) are a reading of the framework's state, observable and dynamics postulates together with the declared operator H; they assert nothing about whether a preparation attains the trial value, about the behaviour of any preparation under time evolution beyond P4, about equilibration, environmental coupling, measurement or apparatus, and about any measured energy. All spectral statements are statements about the declared operator.

DefinitionDefinition: AI-adaptedProof: Not applicableOpen item page →

The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster

Physical scope

The perturbed-family model of a declared system of the framework: a self-adjoint unperturbed energy observable H0, a bounded self-adjoint perturbation V with norm v, the real coupling lambda and the family H(lambda) = H0 + lambda V declared as the model's energy observable at coupling lambda, together with a fixed isolated eigenvalue E of H0 of finite multiplicity with gap g, its spectral projection, the first-order operator P0VP0 on the eigenspace, and the followed perturbed spectral cluster supplied by the contour construction. The definition asserts no time-dependent perturbation, no ramping protocol, no occupation of any branch by a preparation, no measurement and no laboratory identification; all statements are about the declared operator family.

Definition

(a) Framework data. Adopt P1, P2 and P4 (State and composition postulate P1: Hilbert spaces, preparations and composite systems, Observable and probability postulate P2: self-adjoint observables, spectral probability and finite unsharp outcomes, Autonomous dynamics postulate P4: self-adjoint generators and unitary evolution) for a declared system, with the state, sharp-observable and evolution readings of Assigned sharp observables and the outcome law of the framework and Assigned energy observable, unitary flow and the two pictures of autonomous evolution; units are those of Dimensions, SI unit conventions and quantity types of the framework. Assume the Axiom of Countable Choice and the Axiom of Choice (The Axiom of Countable Choice (ACω), The Axiom of Choice) as the choice hypotheses of the cited mathematical suppliers.

(b) The perturbed family. As an additional model assumption of the pair, fix a self-adjoint operator H0:D(H0)⊆H→H on the declared state space, declare (H0,J) to be the unperturbed sharp energy observable, fix a bounded self-adjoint operator V∈B(H) (A bounded linear operator between normed spaces) with v:=∥V∥<∞ (The operator norm as the least bound and as the unit-sphere or unit-ball supremum) and fix a real coupling λ (dimensionless: λV is read in joules). Declare the perturbed family H(λ):=H0+λV,D(H(λ)):=D(H0), to be the model's sharp energy observable at coupling λ. Since V is H0-bounded with H0-bound 0≤a<1 (the bound inequality holds with a=0 and b=v), the Kato-Rellich theorem applies and H(λ) is self-adjoint on D(H0) for every real λ (Kato-Rellich theorem, Symmetric, self-adjoint and essentially self-adjoint operators). This self-adjointness is a supplied theorem about the declared operators; the reading of the family as the system's energy is the model assumption.

(c) The gapped label. Fix an isolated eigenvalue E∈R of H0 of finite multiplicity r≥1 with gap dist⁡(E,σ(H0)∖{E})≥g>0, and put P0:=EH0({E}) and Q0:=I−P0 (Discrete and essential spectrum of a self-adjoint operator, Projection valued measure, Resolvent and spectrum of an unbounded operator). The definitions used by the pair are those of the cited suppliers:

(i) for real λ with 2∣λ∣v/g<1, the followed spectral cluster is the spectrum of H(λ) inside ∣z−E∣<g/2, and Pλ:=12πi∮∣z−E∣=g/2(z−H(λ))−1 dz (counterclockwise) is its rank-r orthogonal spectral projection, by Finite-rank gapped spectral cluster under a bounded perturbation. The cluster is a nonempty finite set and is exactly the spectrum of the restriction to PλH. In the simple case r=1 only, write Eλ for its unique spectral value; this scalar is the followed perturbed label of Contour perturbation projection and is analytic on the valid coupling disk. For r>1 no unique scalar label, branch ordering or individual scalar holomorphy is presumed. At λ=0 the cluster is {E} and its projection is P0. If v=0, these data are constant for all real couplings, with no radius involving division by v.

(ii) the first-order operator is the Hermitian operator VE:=(P0VP0)∣P0H on the finite-dimensional eigenspace P0H, whose spectrum spec⁡(VE)⊆[−v,v] is the model's first-order shift data (joules per unit coupling);

(iii) the complementary reduced inverse S:=ιQ0(H0∣D(H0)∩Q0H−E)−1Q0 is a bounded operator with the displayed exact complementary-domain inverse. For every finite multiplicity r≥1, including v=0, its existence follows by applying part (c) of Finite-rank gapped spectral cluster under a bounded perturbation at coupling λ=0 and w=E: since the cluster projection is then P0, the restriction of E−H0 to D(H0)∩Q0H has a bounded two-sided inverse RQ(E):Q0H→D(H0)∩Q0H, and S=−ιQ0RQ(E)Q0. For r=1 the same operator is supplied by Simple-level reduced-resolvent coefficients. Its role is to record that the whole complementary spectral subspace, continuum included, contributes to the second-order data.

(d) Scope. Clauses (a)-(c) cover bounded perturbations of a self-adjoint operator and a fixed isolated finite-multiplicity label only. The definition asserts no time-dependent perturbation, no adiabatic ramping of λ, no statement that a preparation occupies the branch of Eλ or of any eigenvalue of VE, no branch-population or relaxation statement, no measurement and no identification of the model with a laboratory system; the labels Eλ are spectral data of the declared family.

DefinitionDefinition: AI-adaptedProof: Not applicableOpen item page →

The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading

Physical scope

The WKB regime model of a declared spinless one-dimensional massive particle: a compactly supported C^5 potential in the declared line model, declared reference length and energy scales, the nondimensionalised stationary equation with explicit dimensionless semiclassical parameter h, the turning-point, allowed-region and forbidden-region vocabulary, the WKB phase integral and the declared barrier transmission reading. The definition asserts no approximation error (that belongs to the page's theorems), no detector, no wave packet and no laboratory potential; it states the exact nondimensionalisation correspondence proved by the cited lemma.

Definition

(a) Framework data and line model. Adopt P1, P2, P4 and P5 (State and composition postulate P1: Hilbert spaces, preparations and composite systems, Observable and probability postulate P2: self-adjoint observables, spectral probability and finite unsharp outcomes, Autonomous dynamics postulate P4: self-adjoint generators and unitary evolution, Kinematics and massive-particle model postulate P5: Newtonian frames and one-particle operators), the state and observable readings cited there, and the declared effective one-dimensional line model The declared one-dimensional line model: state space, Hamiltonian, bound states and generalized stationary solutions with a mass parameter m>0, spin label s=0, action constant ℏ>0 and units from Dimensions, SI unit conventions and quantity types of the framework (The massive spin-s particle model of the framework: state space, operators, units and frame readings). Assume the Axiom of Countable Choice and the Axiom of Choice as the choice hypotheses of the cited mathematical suppliers (The Axiom of Countable Choice (ACω), The Axiom of Choice). Fix a real potential V∈Cc5(R;R) (five times continuously differentiable with compact support); it is real, bounded and measurable, so the line model's assigned energy operator HV of its clause (c) is defined with domain D(HV)=W2,2(R;C), acts by HVf=−ℏ22mD2f+Vf, and its stationary equation at energy E reads −ℏ22m ψ′′+Vψ=Eψ for classically C2 solutions.

(b) Reference scales and nondimensionalisation. As an additional model assumption of the pair fix a reference length ℓ>0 (metres) and a reference energy E⋆>0 (joules), and put W(ξ):=V(ℓξ)E⋆,λ:=EE⋆,h:=ℏℓ2mE⋆. Then W∈Cc5(R;R) is dimensionless with support scaled by ℓ, and h>0 is dimensionless. By Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent the physical stationary equation of clause (a) at energy E is equivalent, under x=ℓξ, ψ(ℓξ)=u(ξ), to the dimensionless WKB equation u′′(ξ)=W(ξ)−λh2 u(ξ),ξ∈I, on every interval I. The exact transfer of the square-root action integrals over a subinterval [xa,xb]=ℓ[a,b] is, when the indicated strict sign holds throughout [a,b], 1ℏ∫xaxb2m(V(x)−E) dx=1h∫abW(ξ)−λ dξif W−λ>0, 1ℏ∫xaxb2m(E−V(x)) dx=1h∫abλ−W(ξ) dξif λ−W>0; these are respectively clauses (b)(i) and (b)(ii) of Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent. The pair calls h the model's semiclassical parameter and calls h≪1 the semiclassical regime; the physical content of the regime is ℏ≪ℓ2mE⋆, and every statement of the page's theorems is an exact statement about the family indexed by h, with the error bounds stated at each h. For the mathematical small-h limit, hold the dimensionless profile W and energy λ fixed and vary the parameter in u′′=(W−λ)u/h2. A corresponding physical family with fixed m,E⋆,ℏ is obtained by taking ℓh=ℏ/(h2mE⋆) and Vh(x)=E⋆W(x/ℓh), with E=E⋆λ; the physical width then changes, while the natural action constant does not. A single originally chosen V,ℓ,E⋆ supplies one member of this family.

(c) Turning points, regions and phase. For the data (W,λ) put τ:={ξ∈R:W(ξ)=λ} for the set of turning points. A point ξ0∈τ is simple when W′(ξ0)≠0. An open interval J is an allowed interval when W(ξ)−λ<0 on J (the dimensionless kinetic energy −(W−λ) is positive there), a forbidden interval when W(ξ)−λ>0 on J. On an allowed interval the model uses the positive scaled momentum p(ξ):=λ−W(ξ)>0 with local wavenumber kh(ξ):=p(ξ)/h in the coordinate ξ and WKB phase θh(ξ):=h−1∫ξrefξp(s) ds with a declared base point; on a forbidden interval the model uses κ(ξ):=W(ξ)−λ>0. The dimensionless forbidden action of a forbidden interval [ξa,ξb] is S:=∫ξaξbW(ξ)−λ dξ=hℏ∫xaxb2m(V(x)−E) dx, The WKB exponent is S/h, the physical action in units of ℏ. For a barrier whose endpoints are simple turning points, the strict-sign hypothesis of clause (b)(i) fails at those endpoints; apply that clause on [ξa+δ,ξb−δ] and let δ↓0. Both integrands extend continuously with value zero at the endpoints, so the omitted endpoint integrals tend to zero. The three declared regime hypotheses used by the page are:

(W1) Allowed-interval regularity: W∈C2 on a neighbourhood of [a,b] and λ−W≥δ>0 on [a,b] for some δ>0 (no turning point in the interval; the interval is allowed);

(W2) Separated simple turning points: W−λ has exactly two zeros ξa<ξb in R, both simple, is positive on (ξa,ξb) and negative on the complement of [ξa,ξb] (equivalently the physical barrier V−E has exactly two simple zeros surrounding a forbidden region and is negative outside);

(W3) Single simple turning point: on an interval [ξ0−r,ξ0+s] the equation W−λ has the single zero ξ0, it is simple, and W−λ<0 on one side and >0 on the other.

(d) Declared barrier transmission reading. Under (W2), λ>0 because W=0 outside its compact support. Choose R>0 with supp⁡W⊂(−R,R) and put p∞:=λ. The declared scattering solution is the exact C2 solution of the dimensionless equation with boundary conditions uh(ξ)=p∞−1/2(eip∞ξ/h+r(h)e−ip∞ξ/h)(ξ≤−R),uh(ξ)=p∞−1/2t(h)eip∞ξ/h(ξ≥R). Thus there is one incoming wave from the left and none from the right. These data determine unique amplitudes by Two-turn barrier tunnelling error, instantiated with its mass parameter 1/2, potential W and energy λ. Define the reference current Jh(u):=hIm⁡(u‾ u′): the normalized exterior waves have currents ±1. The transmission coefficient is T(h):=∣t(h)∣2, the ratio of transmitted to incoming reference current. The physical line-model current is a positive common multiple of Jh under clause (b), so its ratio is also T(h). Airy/WKB matching computes this exact boundary-defined quantity; it does not define an additional approximate scattering solution. No detector, wave packet, scattering experiment or measured count is asserted, and this clause does not by itself assert an asymptotic formula for T(h).

(e) Scope. The model concerns a declared spinless massive particle in the declared one-dimensional line model with a compactly supported C5 potential, at a fixed energy, in the nondimensionalised family of clause (b). It asserts nothing about two- or three-dimensional scattering, about singular or non-smooth potentials, about wave packets, detectors or measurements, and about any laboratory realization of the line model, the potential V or the energy E.

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Static finite-level electric-dipole coupling: compressed dipole of the declared two-body Coulomb model in a uniform field

Physical scope

The static finite-level electric-dipole coupling model of the declared two-body Coulomb pair: the relative-coordinate dipole operator with components -q Q_j on their maximal L^2 domains, a declared finite-dimensional subspace of the relative-coordinate space, the compressed Hermitian dipole matrix, the uniform static field value and the bounded interaction -E . D added to the compressed Coulomb energy on the subspace. The postulate is a model assumption for the declared finite-level truncation; it asserts no Maxwell equation or source model, no propagation, no derivation of the truncation or of the field, no semibounded uncompressed model (the common test-domain expectations of H_kappa - E_ext . D are shown unbounded below for every nonzero uniform field), no transition rate and no measured shift.

Postulate

Adopt as a physical assumption of the pair, additional to P1, P2 and P4 and valid only for the declared finite-level model of this clause, the following static electric-dipole coupling. Assume the Axiom of Countable Choice and the Axiom of Choice as the choice hypotheses of the cited mathematical suppliers (The Axiom of Countable Choice (ACω), The Axiom of Choice).

(i) Declared charged pair and relative coordinate. Take the declared two-body Coulomb model of The declared Coulomb and two-body hydrogen model: one-centre operator, relative problem, reduced mass and scope exclusions clause (d): two distinguishable spinless particles with mass parameters m1,m2>0 and opposite charges −q and +q, q>0 (coulombs), with the relative coordinate r=x1−x2 and the centre-of-mass/relative unitary UΦ. Work in the relative-coordinate factor L2(R3;C) of that reading, with Coulomb mass parameter m=μ:=m1m2/(m1+m2), and with units as in Dimensions, SI unit conventions and quantity types of the framework.

(ii) Dipole operator. Let Qj, j=1,2,3, be the coordinate multiplication operators on L2(R3;C) with maximal domains D(Qj)={ψ:ξjψ∈L2} of Atomic dipole matrix-element domain clause (a); they are self-adjoint and proper densely defined. The model's dipole operator is the triple Dj:=−q Qj(j=1,2,3), because the dipole of charges −q at x1 and +q at x2 is −qx1+qx2=−qr: it points from the negative to the positive charge, opposite to the declared relative coordinate r=x1−x2. Each Dj is self-adjoint on D(Qj) and has unit C m. This is the dipole of the declared pair in its relative-coordinate reading; no multipole expansion, no field equation and no coupling to the centre-of-mass motion is assumed.

(iii) Finite-level truncation. Fix, as part of the model specification, a declared finite-dimensional subspace W⊆D(Hκ)∩D(Q1)∩D(Q2)∩D(Q3) of the relative-coordinate space with D(Hκ)=H2(R3;C) and dim⁡W=d<∞, together with an orthonormal basis of W. The model declares the compressed dipole matrix on W, DjW:=ΠWDj∣W, where ΠW is the orthogonal projection onto W and the restriction to W is read in the declared orthonormal basis; DjW is the finite Hermitian d×d matrix of the dipole component, with unit C m, and it is bounded with norm at most sup⁡ψ∈W,∥ψ∥=1∥Djψ∥. The truncation and the basis are model assumptions: they are not derived from the Coulomb model, and they replace the unbounded operator Dj by its compression throughout this pair.

(iv) Static uniform field and interaction operator. The external datum is a uniform static electric field value Eext∈R3, read in V m−1; it is prescribed, and no Maxwell equation, source model, propagation or back-reaction is assumed. The finite-level static Stark model is the finite-dimensional operator on W HS(Eext):=ΠWHκ∣W−∑j=13Eext,j DjW, where the energy-domain condition of (iii) makes the compression defined, and Hκ=Cμ is the one-centre Coulomb energy operator with mass parameter m=μ of the declared model, read on the relative-coordinate factor through the angular/radial identification used by the pair. The interaction term has unit C m⋅V m−1=J and is bounded Hermitian on W, so HS(Eext) is a bounded Hermitian d×d matrix and the Kato-Rellich and perturbation statements of the pair apply to it with a bounded perturbation; this identification of the matrix with the model's energy on the truncated subspace is a model assumption.

(v) Scope and explicit exclusion. Clauses (i)-(iv) are adopted model assumptions. They assert nothing about a laboratory atom, field or apparatus; no measured Stark shift is claimed; no transition, absorption or emission rate is defined; and no time dependence of the field is assumed. In particular the postulate deliberately does not treat the uncompressed linear potential −Eext⋅D as a bounded perturbation of Hκ. For Eext≠0, define this composite interaction to be the maximal multiplication operator MEψ(r):=qEext⋅r ψ(r),D(ME):={ψ∈L2:(Eext⋅r)ψ∈L2}; it agrees with −∑jEext,jDj on the common domain ⋂jD(Dj) and is unbounded because its real multiplier is unbounded. The common operator domain D(Hκ)∩D(ME) contains Cc∞(R3;C). Its lack of a lower bound can be demonstrated without assuming a full energy-form domain: let Eext≠0, e^=Eext/∣Eext∣, choose a fixed support radius ρ>0 in metres and normalized φ∈Cc∞(B(0,ρ);C), and for each length R>ρ put ψR(r):=φ(r+Re^). Then ψR∈Cc∞(R3;C)⊂D(Hκ)∩D(ME)∩⋂j=13D(Qj) and ∥ψR∥2=1. On this common test domain define the quadratic expectation QEext[ψ]:=⟨Hκψ,ψ⟩+⟨MEψ,ψ⟩. With s=r+Re^, the Coulomb action and the translation-invariant kinetic expectation give QEext[ψR]=ℏ22μ∫∣∇φ(s)∣2ds−κ∫∣φ(s)∣2∣s−Re^∣ds+qEext⋅∫s∣φ(s)∣2ds−qR∣Eext∣. Here −Eext⋅D=qEext⋅r because D=−qr in the relative-coordinate convention. For R>ρ, the Coulomb integral is finite and at most 1/(R−ρ), the kinetic term is constant, and the other field term apart from −qR∣Eext∣ is independent of R. Therefore QEext[ψR]→−∞ as R→∞. This proves unboundedness below of the displayed quadratic expectation on the common test domain, so no quadratic form bounded below there can agree with these values; no claim is made about a particular closed-form domain. The uncompressed static-field model is outside the scope of every statement of this pair. Only the compressed finite-level operator of clause (iv) is used.

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Variational trial bounds, gap-overlap control and the min-max characterisation of the declared model's discrete eigenvalues

Physical scope

The variational and min-max statements of the declared trial model: every trial value is at least the model bottom E0, a trial value within epsilon of an isolated bottom with gap g forces ground-projection content at least 1 - epsilon/g, and the model's discrete eigenvalues below the essential spectrum are exactly the min-max values over trial subspaces of the form domain. All quantities are readings of the declared operator; no measurement, apparatus, sampling model or laboratory identification is asserted.

Statement

Adopt the framework data and the declared variational trial model of The declared variational trial reading: assigned energy observable, form domain, trial value, bottom and gap: a declared system with self-adjoint assigned energy observable H on H, bounded below by a real c, with model bottom E0=inf⁡σ(H), form domain Q(H), form qH and spectral projection-valued measure E; a trial vector is a unit vector u∈Q(H) and its trial value is qH[u]. Assume the Axiom of Countable Choice and the Axiom of Choice (The Axiom of Countable Choice (ACω), The Axiom of Choice) as the choice hypotheses of the cited spectral suppliers. Then:

(a) Trial lower bound. For every trial vector u∈Q(H), qH[u]≥E0, so every trial value is an upper bound for the model bottom; consequently E0=inf⁡{qH[u]:u∈Q(H), ∥u∥=1}.

(b) Gap-overlap control. Suppose in addition that the bottom is isolated with gap g>0 and let P:=E({E0}) (clause (d) of the model). Then for every trial vector u with qH[u]≤E0+ε, ε≥0, ∥(I−P)u∥2≤εg; in particular, if ε<g, then Pu≠0.

(c) Min-max. Let Λ:=inf⁡σess(H) and let E1≤E2≤⋯ be the discrete eigenvalue ladder of the model clause (d), with En:=Λ after exhaustion and inf⁡∅=+∞. Then for every integer n≥1, En=inf⁡L⊆Q(H) lineardim⁡L=n sup⁡u∈L∥u∥=1qH[u]=sup⁡F⊆Q(H) lineardim⁡F≤n−1 inf⁡u∈Q(H)∩F⊥∥u∥=1qH[u], with the infimum over an empty set read as +∞; moreover E1=E0, and when En<Λ both outer values are attained, respectively by a span of the first n and a span of the first n−1 orthonormal eigenvectors.

(d) Consequence for trial subspaces. For every linear subspace L⊆Q(H) of dimension n≥1 whose supremum is finite, En≤sup⁡{qH[u]:u∈L, ∥u∥=1}; for n=1 this is clause (a) with u a unit vector of L.

(e) Reading and scope. All numbers E0, En, qH[u] are read in joules. For a trial vector in D(H) the trial value is the mean energy of the pure preparation in the moment reading of Mean, second moment and variance of an assigned observable in a preparation; for a trial vector in Q(H)∖D(H) it is a form value and no outcome-law mean is asserted. The theorem asserts nothing about whether the infimum in (a) is attained, about a ground eigenvector, about time evolution, equilibration or environmental coupling, and about any measured energy; it is a statement about the declared operator H.

Facts & Assumptions

Given: the declared trial model of The declared variational trial reading: assigned energy observable, form domain, trial value, bottom and gap with its data H,c,E0,Q(H),qH,E; a gap g>0 and P=E({E0}) in clause (b); Λ and the ladder (En) in clause (c); the choice hypotheses.

[F1]

Spectral data of the model. H is self-adjoint with dense domain and E its regular projection-valued measure; σ(H) is the set of real λ every neighbourhood of which has nonzero spectral projection, the spectrum is contained in [E0,+∞) because E0=inf⁡σ(H), and D(H)={u:∫λ2dEu(λ)<∞} (Spectral theorem for unbounded self-adjoint operators (PVM form), Projection valued measure, Discrete and essential spectrum of a self-adjoint operator).

[F2]

Form and moments. Q(H) and qH[u]=∫Rλ dEu(λ) are independent of the lower bound chosen in the model, D(H) is dense in Q(H) for the form norm, qH[u]≥c∥u∥2, and qH[u]=⟨Hu,u⟩ for u∈D(H) (Spectral form domain and core of a semibounded operator). Eu(B)=∥E(B)u∥2 is a measure of total mass ∥u∥2 (Projection valued measure).

[F3]

Supplied trial and gap estimates. Let H′ be a self-adjoint operator on a nonzero complex Hilbert space, bounded below with bottom E0′, let g′>0 satisfy σ(H′)∩(E0′,E0′+g′)=∅, put P′:=EH′({E0′}), and let qH′ be the form of Spectral form domain and core of a semibounded operator. On the spectral support [E0′,∞), ∣t∣≤(t−c)+∣c∣ and t−c≤∣t∣+∣c∣ for any lower bound c; since Eu(R)=∥u∥2<∞, these inequalities show Q(H′)=D(∣H′∣1/2). Thus for every unit u∈Q(H′), the supplied theorem gives qH′[u]−E0′≥g′∥(I−P′)u∥2; and if qH′[u]≤E0′+ε then ∥(I−P′)u∥2≤ε/g′, with P′u≠0 when ε<g′ (Spectral form domain and core of a semibounded operator, Spectral theorem for unbounded self-adjoint operators (PVM form), Variational ground gap overlap clauses (a), (b)).

[F4]

Supplied min-max theorem. Under the Axiom of Choice, for a self-adjoint operator A bounded below on a complex Hilbert space, with form domain Q(A), form qA, ΛA=inf⁡σess(A) and the eigenvalue ladder E1A≤E2A≤⋯ below ΛA (equal to ΛA after exhaustion), the two min-max formulas of clause (c) hold for every n≥1, with infima over empty sets +∞; if EnA<ΛA both outer values are attained by spans of the first n and first n−1 orthonormal eigenvectors (Min-max principle below the essential spectrum).

Proof

technique · direct; read the trial value as a spectral integral over the carrier $[E_{0},+\infty)$ for (a), invoke the supplied gap estimate for (b), instantiate the supplied min-max theorem for (c), and compare trial families for (d)

Given: the data of the statement and [F1]-[F4].

1.1F1F2givenchoosealgebra

[Clause (a)] By [F1] the spectrum lies in [E0,+∞), so every real t<E0 has a neighbourhood, namely (2t−E0,E0), with zero spectral projection, and countable subadditivity of the finite measure Eu over the rational intervals contained in (−∞,E0) gives Eu((−∞,E0))=0. Hence Eu is carried by [E0,+∞) and, for u∈Q(H) with the finite integral of [F2], qH[u]=∫Rλ dEu(λ)=∫[E0,∞)λ dEu(λ)≥E0∫[E0,∞)dEu(λ)=E0∥u∥2=E0, since u is a trial vector. For the reverse infimum inequality, let η>0. Since E0=inf⁡σ(H), choose t∈σ(H) with E0≤t<E0+η/2. Choose a bounded open interval J containing t and contained in (−∞,E0+η). The spectral-support characterization in [F1] gives E(J)≠0; choose a unit vector u in its range. Its spectral measure is supported in the bounded set J, hence u∈Q(H) and qH[u]≤E0+η. Thus the infimum of trial values is exactly E0, as claimed in (a).

1.2F2F3given

[Clause (b)] The model's clause (b) supplies a self-adjoint H bounded below with bottom E0=inf⁡σ(H), and clause (b) of the statement supplies the gap σ(H)∩(E0,E0+g)=∅ and P=E({E0}); the model's Q(H) and qH are those of [F2], which are the ones used by the supplied estimate [F3] with H′=H, E0′=E0, g′=g, P′=P. Applying [F3] gives qH[u]−E0≥g∥(I−P)u∥2, hence ∥(I−P)u∥2≤ε/g whenever qH[u]≤E0+ε, and Pu≠0 when ε<g.

1.3F2F4given

[Clause (c)] The operator H is self-adjoint and bounded below, so [F4] applies with A=H; its form domain and form are Q(H) and qH by [F2], its essential spectrum is σess(H) with Λ=inf⁡σess(H), and its eigenvalue ladder below Λ, with the after-exhaustion convention, is exactly the ladder (En) of the model clause (d) by Discrete and essential spectrum of a self-adjoint operator. Hence the two displayed min-max identities and the attainment statement for En<Λ hold.

2.1F2F4step 1.1step 1.3givenalgebra

[The identification E1=E0] For n=1 the second min-max formula in [F4] has only F={0}, so it gives E1=inf⁡{qH[u]:u∈Q(H),∥u∥=1}. Step 1.1 identifies this infimum as E0, hence E1=E0 and the additional assertion of (c) follows. This argument does not assume that the infimum is attained or that a bottom eigenvector exists.

3.1step 1.3step 2.1F2algebra

[Clause (d)] Let L⊆Q(H) have dimension n and finite supremum s=sup⁡{qH[u]:u∈L,∥u∥=1}. This particular L belongs to the first min-max infimum of step 1.3, so En≤s directly; attainment of the inner supremum is unnecessary. If n=1 and u is any unit spanning vector, the unit vectors of the complex line are αu with ∣α∣=1, and the quadratic form satisfies qH[αu]=∣α∣2qH[u]=qH[u]. Thus s=qH[u] and E1=E0 reduces the assertion to (a).

4.1F2F3given∎

[Clause (e)] The units are those of the model: H and qH in joules, so E0 and En are read in joules. For u∈D(H), qH[u]=⟨Hu,u⟩ by [F2], which is the mean of the assigned sharp energy observable in the pure preparation [u] by Mean, second moment and variance of an assigned observable in a preparation clause (a); for u∈Q(H)∖D(H) the value qH[u] is the form value of [F2] and no outcome-law mean is asserted. No measurement, apparatus or sampling model entered the argument, and every object is a spectral datum of the declared operator H.

Remarks

  • No attained-ground-state hypothesis. Clauses (a) and (c) hold whether or not E0 is an eigenvalue and whether or not the infimum of the trial values is attained; clause (b) states precisely what an isolated bottom with gap g forces. This is the form-domain reading required of the variational bound: the trial vector need not lie in D(H).
  • Choice. The min-max clause cites the published min-max theorem, which assumes the Axiom of Choice; the trial lower bound of clause (a) and the gap estimate of clause (b) are, through their suppliers, Countable-Choice statements in their other dependencies. Consumers that use clause (c) carry the Axiom of Choice.
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Nondegenerate stationary perturbation of a simple gapped label: first- and second-order coefficients and an explicit cubic remainder

Physical scope

The stationary perturbation statement for the declared perturbed-family model with a simple isolated label: self-adjointness of the family for real couplings, existence, uniqueness and reality of the followed label inside the gap contour, the exact first- and second-order energy coefficients with the reduced inverse of the complementary spectral subspace, and the explicit cubic remainder bound on the coupling disk. The theorem concerns spectral data of the declared operator family only; it asserts no ramping protocol, no branch population, no relaxation, no transition rate and no measurement.

Statement

Adopt the framework data and the declared perturbed-family model of The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster in the simple-label case: H0 is self-adjoint on D(H0), V=V∗∈B(H) with v=∥V∥≥0, H(λ)=H0+λV on D(H0) for real λ, and E is an isolated eigenvalue of H0 of multiplicity one with gap at least g>0, dist⁡(E,σ(H0)∖{E})≥g. Let ψ0 be a normalized eigenvector, P0ψ0=ψ0, let S:=ιQ0(H0∣D(H0)∩Q0H−E)−1Q0,Q0=I−P0, be the reduced inverse of the model clause (c)(iii). In the branch v>0 put R:=g8v. Then clauses (a)-(e) hold for every real λ with ∣λ∣<R in this positive-norm branch; clause (f) covers v=0 independently of R:

(a) H(λ) is self-adjoint on D(H0); the model's followed label Eλ of the contour ∣z−E∣=g/2 exists, is the unique spectral value of H(λ) inside that contour, is real, and its spectral projection is the orthogonal rank-one projection Pλ=EH(λ)({Eλ});

(b) the gauge-fixed eigenvector ψ(λ):=Pλψ0⟨Pλψ0,ψ0⟩ is analytic in λ, satisfies ⟨ψ(λ),ψ0⟩=1 and (H0+λV)ψ(λ)=Eλψ(λ), and q:=2∣λ∣v/g≤14,∥Pλ−P0∥≤13,∥ψ(λ)∥≤2;

(c) the model's label identity Eλ=⟨(H0+λV)ψ(λ),ψ0⟩=E+λ⟨Vψ(λ),ψ0⟩ holds, so the deviation λ↦Eλ−E of the model's energy label is controlled by the perturbation alone;

(d) the exact coefficients are E′(0)=⟨Vψ0,ψ0⟩,ψ′(0)=−SVψ0,E′′(0)=−2⟨VSVψ0,ψ0⟩, with ∣E′(0)∣≤v, ∥ψ′(0)∥≤v/g and ∣E′′(0)∣≤2v2/g; the second-order coefficient involves the whole complementary spectral subspace of H0 through S, continuum included;

(e) the cubic remainder obeys ∣Eλ−E−λE′(0)−λ22E′′(0)∣≤Rv (∣λ∣/R)31−∣λ∣/R, so at ∣λ∣=R/2 the bound is g/32 and for ∣λ∣≤R/2 it is at most 128v3∣λ∣3/g2;

(f) if v=0, that is V=0, then Pλ=P0, Eλ=E and ψ(λ)=ψ0 for every real λ, and no radius involving division by v is used in this branch;

(g) the theorem is conditional on the strict positive gap, on the multiplicity one of E and on the boundedness of V; it asserts no unbounded or degenerate perturbation theorem, no time-dependent perturbation, and no statement about which branch of the family a preparation occupies.

Facts & Assumptions

Given: the declared perturbed-family model in the simple-label case; E,g,v,R and the reduced inverse S as in the statement; a real λ with ∣λ∣<R; the Axiom of Countable Choice.

[F1]

Self-adjointness of bounded perturbations. For a self-adjoint A and a symmetric B with D(A)⊆D(B) and A-bound less than one, A+B on D(A) is self-adjoint (Kato-Rellich theorem).

[F2]

Contour construction and reality. Under the hypotheses of the contour theorem (H0 self-adjoint on its exact dense domain, E isolated with gap at least g>0 and rank-one spectral projection P0, V=V∗ bounded with v=∥V∥>0, q=2∣λ∣v/g<1): Hλ=H0+λV is closed and densely defined on D(H0) with norm-convergent resolvent series on the contour Γ={∣z−E∣=g/2}; the operator Pλ=12πi∮ΓRλ(z) dz is an operator-norm holomorphic rank-one Riesz projection, there is exactly one spectral value Eλ of Hλ inside Γ, of algebraic multiplicity one with ran⁡Pλ=ker⁡(Hλ−Eλ), and for real λ the operator Hλ is self-adjoint and Pλ=EHλ({Eλ}) is its orthogonal spectral projection (Contour perturbation projection clauses (a)-(d)).

[F3]

Coefficients and remainder. Under the hypotheses of [F2] with the reduced inverse S of Simple-level reduced-resolvent coefficients and the gauge-fixed ψ(λ): on the complex disk ∣λ∣<R=g/(8v), q=2∣λ∣v/g≤1/4, ∥Pλ−P0∥≤1/3, ∥ψ(λ)∥≤2, the identity Eλ=⟨(H0+λV)ψ(λ),ψ0⟩=E+λ⟨Vψ(λ),ψ0⟩ holds, the coefficients and bounds of clause (d) hold, and the cubic remainder bound of clause (e) holds; for v=0 one has Pλ=P0, Eλ=E, ψ(λ)=ψ0 (Analytic perturbation remainder clauses (a)-(c)).

[F4]

Model data. The model's clause (c) supplies Eλ and Pλ exactly as the followed perturbed label and Riesz/spectral projection of the contour theorem, the multiplicity-one hypothesis, the gap at least g, the reduced inverse S and the reading of H(λ) as the model's sharp energy observable (The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster).

Proof

technique · direct; instantiate the supplied contour construction and the supplied remainder theorem at the model's data, with Kato-Rellich for the self-adjointness of the family

Given: the data of the statement and [F1]-[F4].

1.1F1F4given

[Self-adjointness on D(H0)] The perturbation V is bounded and symmetric with D(H0)⊆D(V)=H, and the H0-bound of V is 0<1 because ∥Vu∥≤v∥u∥; hence [F1] gives that H(λ)=H0+λV on D(H0) is self-adjoint for every real λ. This is the self-adjointness assertion of (a).

1.2F2F4given

[Contour, label and projection] In the simple-label case the projection P0=EH0({E}) has rank one and the gap hypothesis is dist⁡(E,σ(H0)∖{E})≥g, so [F2] applies for every real λ with 2∣λ∣v/g<1; since ∣λ∣<R=g/(8v) gives q=2∣λ∣v/g<1/4<1, the conclusions hold: there is exactly one spectral value Eλ of H(λ) inside ∣z−E∣=g/2, it has algebraic multiplicity one with range ker⁡(H(λ)−Eλ), Pλ is holomorphic and rank one, and for real λ the projection is the orthogonal spectral projection at the real value Eλ. By [F4] these are exactly the model's followed label and its projection, so clause (a) is proved.

1.3F3F4givenalgebra

[Gauge-fixed eigenvector, coefficients and remainder] With the identified objects, [F3] applies on the disk ∣λ∣<R: ψ(λ) is analytic with the displayed normalization and eigenvector equation, the quantitative bounds q≤1/4, ∥Pλ−P0∥≤1/3, ∥ψ(λ)∥≤2 hold, the label identity of clause (c) holds, and the coefficients, the bounds ∣E′(0)∣≤v, ∥ψ′(0)∥≤v/g, ∣E′′(0)∣≤2v2/g and the cubic remainder bound hold. By [F4] the operator S is the model's complementary reduced inverse, so the second-order term involves the whole complementary spectral subspace, continuum included. This proves clauses (b), (c), (d) and (e).

1.4F3given

[The v=0 branch] If V=0 then v=0 and the family is constant, H(λ)=H0; [F3] clause (c) gives Pλ=P0, Eλ=E, ψ(λ)=ψ0 for every real λ without using a radius R (no division by v occurs). This is clause (f).

2.1F1F2F3F4given∎

[Scope] Every hypothesis used above is one of: the model's bounded self-adjoint perturbation and simple gapped label, the strict positive gap g>0, multiplicity one, and the choice assumption of the spectral suppliers. No unbounded perturbation, degenerate label, time-dependent coupling, ramping protocol, transition rate, branch population or measurement entered the argument; the objects Eλ, Pλ, ψ(λ) are spectral data of the declared family, which is clause (g).

Remarks

  • Where the continuum enters. The reduced inverse S acts on the whole complementary subspace Q0H, so the second-order coefficient −2⟨VSVψ0,ψ0⟩ automatically includes the contribution of the continuous spectrum of H0; the theorem needs no discrete-eigenbasis expansion and no sum over bound states.
  • Determinant of the remainder. The bound is a genuine cubic bound on the disk of radius R=g/(8v); no uniformity in λ beyond that disk is claimed, and the gap enters both the radius and the constant.
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Degenerate stationary perturbation: the perturbed eigenvalues stay within 4 lambda^2 v^2/g of the first-order shifts, and no branch relaxation is asserted

Physical scope

The degenerate stationary perturbation statement for the declared perturbed-family model with an isolated finite-multiplicity label: self-adjointness of the family, the bounded reduced inverse on the complementary subspace, and the localisation of every perturbed eigenvalue in the controlled gap window within 4 lambda^2 v^2/g of the set of first-order shifts E + lambda spec(P0VP0). The theorem asserts no exact eigenvalue correspondence, no branch ordering, no instantaneous selection of the lowest branch, no relaxation and no measurement.

Statement

Adopt the framework data and the declared perturbed-family model of The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster with H0 self-adjoint on D(H0), V=V∗∈B(H), v=∥V∥>0, H(λ)=H0+λV on D(H0) for real λ, and an isolated eigenvalue E of H0 of finite multiplicity r≥1 with gap at least g>0, dist⁡(E,σ(H0)∖{E})≥g. Let P0=EH0({E}), Q0=I−P0, and VE:=(P0VP0)∣P0H the first-order operator of the model clause (c)(ii). Assume the Axiom of Countable Choice and the Axiom of Choice as the choice hypotheses of the suppliers. Then for every real λ with ∣λ∣v<g/4:

(a) H(λ) is self-adjoint on D(H0);

(b) for every real z with ∣z−E∣+∣λ∣v≤g/2, the restricted operator Tλ(z):=Q0(H(λ)−z)Q0 on Q0D(H0)=D(H0)∩Q0H has a bounded two-sided inverse B(z):Q0H→Q0D(H0) with ∥B(z)∥≤4/g;

(c) every real eigenvalue z of H(λ) with eigenvector ψ≠0 and ∣z−E∣+∣λ∣v≤g/2 lies within the first-order shift set: dist⁡(z, E+λspec⁡(VE))≤4λ2v2g, where spec⁡(VE)⊆[−v,v] is the spectrum of the Hermitian operator VE on the r-dimensional eigenspace; moreover P0ψ≠0 for every such eigenvector. Every eigenvalue in the model's followed cluster inside ∣z−E∣<g/2 lies in this controlled window and therefore obeys the same bound;

(d) first-order content. The eigenvalues of VE are the model's first-order shifts: the set E+λspec⁡(VE) has at most r points, all within ∣λ∣v of E; the entire followed cluster, and every other eigenvalue in the window of (c), are localised at distance O(λ2v2/g) from this set, and no ordering or one-to-one correspondence between the r spectral branches and the points of spec⁡(VE) is asserted;

(e) No relaxation or selection. The theorem is a statement about the spectra of the declared family. It asserts no instantaneous transition of any preparation to the branch of the smallest value of spec⁡(VE), no relaxation to a lowest branch, no equilibration and no measurement; which spectral subspace a preparation occupies is fixed by the preparation and by the evolution postulate P4 of the declared model, not by the label Eλ;

(f) the theorem is conditional on the strict positive gap, on the finite multiplicity of E and on the boundedness of V; it asserts nothing about degenerate essential-spectrum labels, gap-closing families, unbounded perturbations or time-dependent couplings.

Facts & Assumptions

Given: the declared perturbed-family model with the isolated label E of finite multiplicity r, gap g, projections P0,Q0, perturbation V with v=∥V∥>0, real λ with ∣λ∣v<g/4, and the choice hypotheses.

[F1]

Self-adjointness. For a self-adjoint A and a symmetric B with D(A)⊆D(B) and A-bound less than one, A+B on D(A) is self-adjoint (Kato-Rellich theorem).

[F2]

Supplied degenerate reduction. Under the stated hypotheses on H0,E,g,r,P0,Q0,V,v,λ and for every real z with ∣z−E∣+∣λ∣v≤g/2: the restricted operator Tλ(z) has a bounded two-sided inverse B(z) with ∥B(z)∥≤4/g; if such a z is an eigenvalue with eigenvector ψ≠0, then P0ψ≠0 and [EP0+λP0VP0−λ2P0VQ0B(z)Q0VP0]P0ψ=z P0ψ; and every such eigenvalue satisfies dist⁡(z,E+λspec⁡(VE))≤4λ2v2/g (Degenerate Feshbach error clauses (a)-(c)).

[F3]

Norm-spectrum extrema. For a bounded self-adjoint operator T on a complex Hilbert space, ∥T∥=max⁡{∣min⁡σ(T)∣,∣max⁡σ(T)∣}, so σ(T)⊆[−∥T∥,∥T∥]; in particular spec⁡(VE)⊆[−v,v] because ∥VE∥≤∥V∥=v for the compression of a bounded self-adjoint operator (Self adjoint norm and spectrum extrema, The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster clause (c)(ii)).

[F4]

Model data. The model declares H(λ) as its sharp energy observable at coupling λ, with the label E, projections P0,Q0, first-order operator VE and coupling range as in its clauses (b) and (c) (The declared perturbed-family model: bounded self-adjoint perturbation, isolated gapped label and followed spectral cluster).

[F5]

Distance resolvent bound. On arbitrary Hilbert space under CC, the self-adjoint spectral supplier gives ∥(z−H0)−1∥≤1/dist⁡(z,σ(H0)) and the exact domain of that inverse (CC spectral calculus on an arbitrary complex Hilbert space by compatible vector-local Cayley subspaces). Neumann inversion of I−λV(z−H0)−1 gives a resolvent of H(λ) whenever the distance is larger than ∣λ∣v.

Proof

technique · direct; instantiate Kato-Rellich and the supplied Feshbach reduction at the model's data, and bound the first-order spectrum by the norm-spectrum theorem

Given: the data of the statement and [F1]-[F5].

1.1F1F4given

[Clause (a)] V is bounded and symmetric with D(H0)⊆D(V)=H and H0-bound 0<1, since ∥Vu∥≤v∥u∥; [F1] gives that H(λ)=H0+λV on D(H0) is self-adjoint for every real λ, in particular for ∣λ∣v<g/4.

1.2F2F4F5givenalgebra

[Clauses (b) and (c)] With H(λ) self-adjoint, the hypotheses of [F2] are exactly the model's data: E is an isolated eigenvalue of finite multiplicity r≥1 with gap at least g, P0 is its orthogonal spectral projection, V is self-adjoint and bounded with norm v, and ∣λ∣v<g/4 implies in particular that the range of z in clause (b) is nonempty (it contains z=E, since ∣λ∣v<g/4≤g/2). Hence [F2] supplies the bounded two-sided inverse B(z) with ∥B(z)∥≤4/g, the nonvanishing P0ψ and the eigenvector reduction, and the localisation inequality dist⁡(z,E+λspec⁡P0H(P0VP0))≤4λ2v2/g for every eigenvalue z in that window; the spectrum there is that of the model's VE. For the full followed cluster, put t=∣λ∣v<g/4 and let z be its real eigenvalue, so ∣z−E∣<g/2 by the model's cluster definition. Every other s∈σ(H0)∖{E} satisfies ∣s−z∣≥g−∣z−E∣>g/2>t. If also ∣z−E∣>t, [F5] and Neumann inversion would put z in the resolvent of H(λ), a contradiction. Hence ∣z−E∣≤t, so ∣z−E∣+t≤2t<g/2 and the preceding reduction applies to every cluster eigenvalue. This proves the full claims (b),(c).

2.1F3step 1.2givenalgebra

[Clause (d)] By [F3] applied to the bounded self-adjoint compression VE: ∥VE∥≤∥V∥=v and spec⁡(VE)⊆[−v,v], so every point of E+λspec⁡(VE) lies in [E−∣λ∣v,E+∣λ∣v]; spec⁡(VE) is finite because P0H has dimension r, so the set has at most r points. The localisation of clause (c) is precisely the statement that each perturbed label lies at distance O(λ2v2/g) from that set; no ordering statement is contained in [F2], and none is asserted here. This is (d).

2.2step 1.2F2F3F4given

[Clause (e)] The argument used only spectral data of the declared family: self-adjointness of H(λ), the reduced inverse on the complementary subspace, and the eigenvector reduction with P0ψ≠0. No evolution, no coupling ramp, no rate, no environment and no measurement entered the proof. A statement about which spectral subspace of H(λ) a preparation occupies would require the preparation and the evolution law of P4, which are not used here; in particular the analysis of the label Eλ does not force an instantaneous transition to the branch belonging to the smallest element of spec⁡(VE). This is (e).

3.1F1F2given∎

[Clause (f)] All hypotheses used are the strict positive gap, the finite multiplicity of E, the boundedness of V and the coupling range ∣λ∣v<g/4; none of the excluded configurations entered the arguments of steps 1.1-2.2.

Remarks

  • Why the first-order operator, not the full perturbation. The supplied reduction shows that the perturbed labels are localised at the spectrum of the compression P0VP0, which is the model's first-order shift data; the second-order remainder is bounded uniformly by 4λ2v2/g, independently of the structure of the perturbation inside the eigenspace.
  • No branch selection. The statement is the corrected form of the textbook assertion that a degenerate level "immediately" moves to its lowest branch; only the spectral splitting is deduced here. Population of branches is a question about the preparation and its dynamics, not about the eigenvalue asymptotics.
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WKB approximation on an allowed interval of the declared regime model: explicit Gronwall error bound away from turning points

Physical scope

The finite-interval WKB error statement for the declared WKB regime model: on a closed interval on which the dimensionless potential stays strictly below the energy (no turning point), any exact solution of the model equation is compared with its leading WKB wave, with the explicit Gronwall-type error bound of the cited theorem. The statement is exact at each value of the semiclassical parameter; it asserts no asymptotic connection across a turning point, no barrier transmission formula, no wave packet and no measurement.

Statement

Adopt the declared WKB regime model of The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading and let its data V,m,ℏ,ℓ,E⋆,E,W,λ,h be as in that model, with hypothesis (W1) on a closed interval [a,b]⊂R: W is C2 on a neighbourhood of [a,b] and λ−W(ξ)≥δ>0 for some δ>0 and all ξ∈[a,b]. Put p(ξ):=λ−W(ξ)>0,θ(ξ):=∫aξp(s) ds,q(ξ):=3p′(ξ)24p(ξ)2−p′′(ξ)2p(ξ), and w±(ξ):=p(ξ)−1/2e±iθ(ξ)/h,M(ξ):=(w+(ξ)w−(ξ)w+′(ξ)w−′(ξ)). Let u∈C2([a,b];C) be an exact solution of the dimensionless model equation u′′=(W−λ)u/h2 on [a,b], and let c(ξ)=M(ξ)−1(u(ξ)u′(ξ)) be its coefficient curve. Then, with ∥⋅∥1 the ℓ1 norm on C2 and all quantities read in the model's units:

(a) ∥c(ξ)∥1≤∥c(a)∥1exp⁡(h∫aξ∣q(s)∣/p(s) ds) for every ξ∈[a,b];

(b) ∥c(ξ)−c(a)∥1≤∥c(a)∥1(exp⁡(h∫aξ∣q(s)∣/p(s) ds)−1);

(c) pointwise wavefunction error. With Ψ(ξ):=c+(a)w+(ξ)+c−(a)w−(ξ) the leading WKB wave, ∣u(ξ)−Ψ(ξ)∣≤p(ξ)−1/2∥c(a)∥1(exp⁡(h∫aξ∣q(s)∣p(s) ds)−1);

(d) the estimate is exact at each fixed h; it degenerates as p(ξ)→0 and therefore excludes turning points by hypothesis (W1). It asserts nothing about connecting asymptotics across a turning point, about barrier transmission or reflection, about packets or detectors, and it makes no claim that the right-hand side is small unless the dimensionless quantity h∫ab∣q∣/p is actually small. The estimate is an error bound of Gronwall type, not an asymptotic expansion, and the physical reading of the interval [a,b] is [xa,xb]=ℓ[a,b] in the line model with potential V(ℓξ)=E⋆W(ξ) and energy E⋆λ.

Facts & Assumptions

Given: the WKB regime model with its scales and data; hypothesis (W1) on [a,b]; the functions p,θ,q,w±,M; an exact solution u∈C2([a,b]) and its coefficient curve c; the Axiom of Countable Choice.

[F1]

Coefficient representation. The Wronskian and smoothness statements for w±, and the coefficient definition Mc=(u,u′)T, are those of Allowed-region WKB coefficient equation clauses (a)-(c). In particular M is invertible and u=w+c++w−c−, u′=w+′c++w−′c−.

[F2]

Integral and norm facts. A continuously differentiable finite-dimensional vector curve satisfies c(x)−c(a)=∫axc′(s) ds, and the induced matrix norm satisfies ∥Bc∥1≤∥B∥1∥c∥1; these are the fundamental theorem of calculus and the definition of the induced ℓ1 norm (Fundamental theorem of calculus for Banach-valued continuous curves, Bochner-integrable function).

[F3]

Model instantiation. The model's equation is u′′=(W−λ)u/h2, which is u′′+(p2/h2)u=0 with p=λ−W on the allowed interval; hypothesis (W1) gives p∈C2([a,b]), p>0, and h>0. The correspondence with the physical line model is Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent (The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading clauses (b), (c)).

Proof

technique · direct; derive both coefficient equations from the defining $2\times2$ system, obtain growth and deviation by integration, and then convert the coefficient deviation to a pointwise wavefunction error

Given: the data of the statement and [F1]-[F3].

1.1F1F3givenalgebra

[Both coefficient relations and their matrix equation] By [F1], M∈C1 is invertible and (u,u′)T∈C1, so c=M−1(u,u′)T is C1 and satisfies Mc=(u,u′)T. Differentiating the first component of this identity and comparing it with the second gives w+c+′+w−c−′=0. Differentiating the second component, using u′′=−(p2/h2)u and w±′′+(p2/h2)w±=qw±, gives w+′c+′+w−′c−′=−qu. Thus Mc′=(0,−qu)T and, since the Wronskian W0=−2i/h, c′=−quM−1(0,1)T=qW0(w+w−w−2−w+2−w+w−)c=:Bc. Each entry of B has modulus h∣q∣/(2p) because ∣w+∣=∣w−∣=p−1/2 and ∣W0∣=2/h; the induced ℓ1 matrix norm is the largest column sum, hence ∥B∥1=h∣q∣/p.

2.1step 1.1F2algebra

[Growth bound] Put v(s):=∥B(s)∥1=h∣q(s)∣/p(s) and U(x):=∥c(a)∥1+∫axv(s)∥c(s)∥1 ds. By [F2] and step 1.1, ∥c(x)∥1≤U(x) and U′(x)=v(x)∥c(x)∥1≤v(x)U(x). Therefore ddx(e−∫axvU(x))≤0, so ∥c(x)∥1≤U(x)≤∥c(a)∥1e∫axv, which is clause (a).

3.1step 1.1step 2.1F2algebra

[Deviation bound by integration] Again by [F2] and step 1.1, ∥c(x)−c(a)∥1≤∫axv(s)∥c(s)∥1 ds≤∥c(a)∥1∫axv(s)e∫asv(t) dt ds. The last integral is e∫axv−1 by the fundamental theorem of calculus applied to s↦e∫asv; this proves clause (b), including the case c(a)=0. This derives the deviation estimate from the growth estimate without subtracting two growth bounds or treating c−c(a) as a homogeneous solution.

4.1F1step 3.1algebra

[Pointwise wavefunction error] The coefficient representation in [F1] gives u(x)−Ψ(x)=w+(x)(c+(x)−c+(a))+w−(x)(c−(x)−c−(a)). Since ∣w±(x)∣=p(x)−1/2, its absolute value is at most p(x)−1/2∥c(x)−c(a)∥1; substituting step 3.1 gives exactly clause (c).

5.1step 1.1step 2.1step 3.1step 4.1F3given∎

[Scope and degeneracy] The hypotheses used are (W1) and W∈C2 on a neighbourhood of [a,b]: in particular λ−W≥δ>0, so p≥δ and no turning point occurs on the interval. The displayed estimate is exact at each fixed h; its error is small only when the displayed factor exp⁡(h∫ax∣q∣/p)−1 is small, which is an additional condition on the model data. The line-model units and physical interval [ℓa,ℓb] are those of The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading and Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent. This proves clause (d), without asserting a connection across a turning point or a measured quantity.

Remarks

  • What "controlled approximation" means here. The theorem does not say that the WKB wave is close to the exact solution; it gives the exact Gronwall factor by which the WKB coefficient can change, so smallness is a checkable hypothesis on h and on the dimensionless ratio ∣q∣/p.
  • Turning points are outside the statement. Hypothesis (W1) is exactly the exclusion of turning points; the connection problem across a simple turning point is a separate theorem of this page.
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Airy connection across a single simple turning point of the declared regime model, with envelope error control

Physical scope

The single-simple-turning-point connection statement for the declared WKB regime model with forbidden region on the right of the turning point: the two exact solutions matched to the Airy-type decaying and growing branches of the transformed equation, their forbidden-side exponential forms, their allowed-side sine and cosine forms with the phase pi/4 measured from the turning point, the factor two of the decaying-sine connection, and the envelope-times-epsilon absolute error control. The statement concerns the declared one-dimensional model's exact solutions only; it asserts no rectangular walls, no coalescing turning points, no multi-turn resonances, no wave packet and no measurement.

Statement

Adopt the declared WKB regime model of The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading with its data V,m,ℏ,ℓ,E⋆,W,λ,h, and assume hypothesis (W3) at a turning point ξ0 with W′(ξ0)>0: on an interval [ξ0−r0,ξ0+s0] with r0,s0>0 the function W−λ has the single zero ξ0, is strictly negative on [ξ0−r0,ξ0) (allowed side) and strictly positive on (ξ0,ξ0+s0] (forbidden side). Write, for the two sides, θ(ξ):=1h∫ξξ0λ−W(ξ′) dξ′(ξ<ξ0),Σ(ξ):=1h∫ξ0ξW(ξ′)−λ dξ′(ξ>ξ0),the nonnegative dimensionless phase and exponent measured from the turning point into the allowed and forbidden sides. Letζ(ξ):=sign⁡(ξ−ξ0)[32∣∫ξ0ξ∣W(ξ′)−λ∣ dξ′∣]2/3be the Liouville coordinate. Write R for the continuous remainder in the transformed equation w′′=[ζ/h2+R(ζ)]w and put η−:=ζ(ξ0−r0), η+:=ζ(ξ0+s0). Defineε(h):=Ckerh∫η−η+∣R(v)∣∣v∣+h2/3 dv,where Cker is the kernel constant of Stable weighted Airy Volterra connection; boundedness of R on the fixed transformed interval gives ε(h)≤C1h for some C1>0 depending only on the fixed data. There are constants 0<C0<∞ and 0<Cerr<∞, depending only on W,λ,ξ0,r0,s0 (not on h), and h0>0, such that for every 0<h<h0: (a) Decaying connection. There is an exact solution udec of the model equation u′′=(W−λ)u/h2 on [ξ0−r0,ξ0+s0] and a real constant C≠0 withu_{\mathrm{dec}}(\xi)=C\,(W(\xi)-\lambda)^{-1/4} e^{-\Sigma(\xi)}\bigl(1+\delta_{\mathrm{f}}(\xi)\bigr)\qquad(\xi>\xi_{0}),$$$$u_{\mathrm{dec}}(\xi)=2C\,(\lambda-W(\xi))^{-1/4} \Bigl(\sin\bigl(\theta(\xi)+\tfrac{\pi}{4}\bigr)+\delta_{\mathrm{a}}(\xi)\Bigr) \qquad(\xi<\xi_{0}), where the absolute errors obey, for ξ≠ξ0 away from the turning point,∣δf(ξ)∣≤C0(ε(h)+h/∣ζ(ξ)∣3/2),∣δa(ξ)∣≤C0(ε(h)+h/∣ζ(ξ)∣3/2),(b) Growing connection. There is a second exact solution ugrow, linearly independent of udec, withu_{\mathrm{grow}}(\xi)=C'\,(W(\xi)-\lambda)^{-1/4} e^{+\Sigma(\xi)}\bigl(1+\delta_{\mathrm{f,grow}}(\xi)\bigr)\qquad(\xi>\xi_{0}),$$$$u_{\mathrm{grow}}(\xi)=C'\,(\lambda-W(\xi))^{-1/4} \Bigl(\cos\bigl(\theta(\xi)+\tfrac{\pi}{4}\bigr)+\delta_{\mathrm{a,grow}}(\xi)\Bigr) \qquad(\xi<\xi_{0}), for a real constant C′≠0, with ∣δf,grow(ξ)∣,∣δa,grow(ξ)∣≤C0(ε(h)+h/∣ζ(ξ)∣3/2) away from ξ0; (c) Derivative and envelope control. Let Ah(ζ):=A(ζ/h2/3) and Bh(ζ):=B(ζ/h2/3) be the Airy functions in Airy envelopes and asymptotic coefficients, let a(ξ):=(ζ′(ξ))−1/2, and put$$ f_h(\zeta):=(1+|\zeta|/h^{2/3})^{-1/4},\qquad \phi_h(\zeta):=\frac{2(\zeta_+)^{3/2}}{3h}.

Definethedecayingandgrowingenvelopesby

e_h^-(\zeta):=f_h(\zeta)e^{-\phi_h(\zeta)},\quad d_h^-(\zeta):=h^{-2/3}f_h(\zeta)^{-1}e^{-\phi_h(\zeta)},\quad e_h^+(\zeta):=f_h(\zeta)e^{\phi_h(\zeta)},\quad d_h^+(\zeta):=h^{-2/3}f_h(\zeta)^{-1}e^{\phi_h(\zeta)}. For each transformed coordinate $\eta\in\zeta([\xi_0-r_0,\xi_0+s_0])$, define $w_{\mathrm{dec}}(\eta):=u_{\mathrm{dec}}(\zeta^{-1}(\eta))/a(\zeta^{-1}(\eta))$ and $w_{\mathrm{grow}}(\eta):=u_{\mathrm{grow}}(\zeta^{-1}(\eta))/a(\zeta^{-1}(\eta))$. For the solutions chosen as in the proof, the following transformed derivative error bounds hold on the full transformed interval, with an error constant $C_{\mathrm{err}}$ depending only on the fixed data and not on $h$: $ |w_{\mathrm{dec}}'-A_h'|\le C_{\mathrm{err}} d_h^-(e^{\varepsilon(h)}-1),\qquad |w_{\mathrm{grow}}'-B_h'|\le C_{\mathrm{err}} d_h^+(e^{\varepsilon(h)}-1). $ Here $\varepsilon(h):=\varepsilon_h$ is the control parameter of [F3] and satisfies $\varepsilon(h)\le C_1h$; the corresponding value errors are bounded by $C_{\mathrm{err}}e_h^-(e^{\varepsilon(h)}-1)$ and $C_{\mathrm{err}}e_h^+(e^{\varepsilon(h)}-1)$. Here primes on $w_{\mathrm{dec}},w_{\mathrm{grow}},A_h,B_h$ denote $\eta$-derivatives, and primes on $a,\zeta$ denote $\xi$-derivatives. Consequently, |u_{\mathrm{dec}}'(\xi)-a'(\xi)A_h(\zeta(\xi))-a(\xi)\zeta'(\xi)A_h'(\zeta(\xi))|\le C_{\mathrm{err}}\bigl(|a'(\xi)|e_h^-(\zeta(\xi))+|a(\xi)|\zeta'(\xi)d_h^-(\zeta(\xi))\bigr)(e^{\varepsilon(h)}-1), $$$$ |u_{\mathrm{grow}}'(\xi)-a'(\xi)B_h(\zeta(\xi))-a(\xi)\zeta'(\xi)B_h'(\zeta(\xi))|\le C_{\mathrm{err}}\bigl(|a'(\xi)|e_h^+(\zeta(\xi))+|a(\xi)|\zeta'(\xi)d_h^+(\zeta(\xi))\bigr)(e^{\varepsilon(h)}-1).For $\rho(\xi):=W(\xi)-\lambda>0$ on the forbidden side and $p(\xi):=\sqrt{\lambda-W(\xi)}>0$ on the allowed side, the scaled slope forms on every compact section bounded away from $\xi_0$ areh\rho(\xi)^{-1/4}u_{\mathrm{dec}}'(\xi)=C e^{-\Sigma(\xi)}\bigl(-1+\delta_{\mathrm{f,dec}}^{(1)}(\xi)\bigr),\qquad h\rho(\xi)^{-1/4}u_{\mathrm{grow}}'(\xi)=C'e^{\Sigma(\xi)}\bigl(1+\delta_{\mathrm{f,grow}}^{(1)}(\xi)\bigr),hp(\xi)^{-1/2}u_{\mathrm{dec}}'(\xi)=2C\bigl(-\cos(\theta(\xi)+\tfrac{\pi}{4})+\delta_{\mathrm{a,dec}}^{(1)}(\xi)\bigr),\qquad hp(\xi)^{-1/2}u_{\mathrm{grow}}'(\xi)=C'\bigl(\sin(\theta(\xi)+\tfrac{\pi}{4})+\delta_{\mathrm{a,grow}}^{(1)}(\xi)\bigr).$$ Each new slope error is absolute and satisfies ∣δf,dec(1)∣,∣δf,grow(1)∣,∣δa,dec(1)∣,∣δa,grow(1)∣≤C0(ε(h)+h/∣ζ(ξ)∣3/2); in particular no relative error at a sine or cosine zero is asserted.

(d) Content of the connection. The factors 2 in the decaying allowed-side form of (a) and 1 in the growing allowed-side form of (b) are the amplitude relations of the exact Airy pair: the forbidden-side data determine the constants C and C′, and the allowed-side oscillations are the sine and cosine forms with phase π/4 measured from the turning point into the allowed region. The statement excludes rectangular walls, coalescing or multiple turning points, multi-turn resonances and barrier-top uniformity; it asserts no transmission or reflection coefficient (that is a separate statement requiring hypothesis (W2)), no wave packet, no detector and no measured value; the errors are absolute and blow up as the turning point is approached, as displayed by the h/∣ζ∣3/2 term.

Facts & Assumptions

Given: the WKB regime model with its data; hypothesis (W3) with W′(ξ0)>0; the functions θ,Σ,ζ; the Axiom of Countable Choice.

[F1]

Liouville transformation. For W∈C5 near ξ0 with a single simple zero of q:=W−λ at ξ0, q′(ξ0)>0, the substitution ζ=ζ(ξ), a=(ζ′)−1/2, u=a w(ζ) transforms the model equation into w′′(ζ)=[ζ/h2+R(ζ)]w(ζ) on the transformed interval, with R continuous and bounded, ζ∈C4, ζ′>0 with min⁡ζ′>0, and constants depending only on q and the interval (Liouville turning-point transformation clauses (a)-(c)).

[F2]

Airy asymptotics and envelopes. The entire Airy functions A,B of Airy contour and Fresnel normalization and Airy envelopes and asymptotic coefficients satisfy A(−Z)=π−1/2Z−1/4(sin⁡Θ+O(Z−3/2)), B(−Z)=π−1/2Z−1/4(cos⁡Θ+O(Z−3/2)) for Z→+∞ with Θ=2Z3/2/3+π/4, the exponential asymptotics A(Z)=12π−1/2Z−1/4e−2Z3/2/3(1+O(Z−3/2)) and B(Z)=π−1/2Z−1/4e2Z3/2/3(1+O(Z−3/2)), the Wronskian AB′−A′B=π−1, and envelope bounds with p(Z)=1+∣Z∣ and S(Z)=23(Z+)3/2 (Airy contour and Fresnel normalization clauses (c), (d), Airy envelopes and asymptotic coefficients clauses (a)-(c)).

[F3]

Stable Volterra connection. Put η−:=ζ(ξ0−r0) and η+:=ζ(ξ0+s0), and use Ah(η)=A(η/h2/3), Bh(η)=B(η/h2/3), fh(η)=(1+∣η∣/h2/3)−1/4 and ϕh(η)=2max⁡{η,0}3/2/(3h). The decaying envelopes are eh−=fhe−ϕh and dh−=h−2/3fh−1e−ϕh, while the growing envelopes are eh+=fheϕh and dh+=h−2/3fh−1eϕh. The stable control parameter is εh:=Ckerh∫η−η+∣R(v)∣/∣v∣+h2/3 dv≤C1h, with constants depending only on the fixed equation and interval. The solution with terminal Airy data (Ah,Ah′) at the right endpoint satisfies ∣w−Ah∣≤CAeh−(eεh−1) and ∣w′−Ah′∣≤CAdh−(eεh−1); the growing branch with Airy data (Bh,Bh′) at η=0 satisfies the analogous value and derivative bounds with eh+,dh+. The connection between the forbidden-side exponential forms and the allowed-side oscillatory forms carries the absolute error bounded by the respective value and derivative envelopes times C(εh+h/∣η∣3/2) (Stable weighted Airy Volterra connection clauses (a)-(c), including its Facts & Assumptions (F3)).

[F4]

Allowed-region transfer on the oscillatory side. On a closed subinterval of the allowed side bounded away from ξ0, the exact solutions are compared with their leading WKB waves by WKB explicit error, with the Gronwall factor of that theorem; the side's scaled momentum is p=λ−W and its local wavenumber in ξ is p/h (The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading clause (c)).

[F5]

Model identification. The physical potential and energy are V(ℓξ)=E⋆W(ξ), E=E⋆λ, and the model equation is u′′=(W−λ)u/h2, so the equation, turning points and functions θ,Σ have the displayed dimensionless data (The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading clauses (b), (c)). For either allowed or forbidden action from ξ0 to a fixed point on the corresponding side, apply Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent clause (b)(i) or (b)(ii) after removing a δ-neighborhood of ξ0. The square-root integrand extends continuously with value zero at the simple turning point, so letting δ↓0 gives the same physical-to-dimensionless identity for the displayed phase and exponent.

Proof

technique · direct; push the model equation through the Liouville transformation, bound the two Airy-matched exact solutions by the stable Volterra estimates, and read the allowed-side sine and cosine forms from the Airy asymptotics with the same constants

Given: the data of the statement and [F1]-[F5].

1.1F1F5given

[Transformed equation] By [F1] applied to q=W−λ (with q of the sign of ξ−ξ0 because W′(ξ0)>0 and ξ0 is the single zero) the model equation is equivalent to w′′=[ζ/h2+R]w under u=a w∘ζ, with ζ exactly the displayed Liouville variable and a=(ζ′)−1/2>0; all constants depend only on the model's data and the interval.

1.2F1F2F3algebra

[Matched solutions and forbidden forms] By [F3], take wdec with Airy data (Ah,Ah′) at the right endpoint and wgrow with Airy data (Bh,Bh′) at ζ=0; put udec(ξ)=a(ξ)wdec(ζ(ξ)) and similarly for the growing branch. These are exact solutions by [F1]. On the forbidden side, 2ζ3/2/(3h)=Σ(ξ) and a(ξ)=ζ1/4(W−λ)−1/4. Thus [F2] and the value bounds of [F3] give the forbidden forms with C=12π−1/2h1/6 and C′=π−1/2h1/6; the relative forbidden errors are bounded by a constant times ε(h)+h/∣ζ∣3/2 on the stated matching sections. These constants are nonzero for each h>0, while the error constants depend only on the fixed data.

2.1F1F2F3step 1.2algebra

[Independence for sufficiently small h] At ζ=0, [F3] gives wdec−Ah=O(ε(h)) and wdec′−Ah′=O(h−2/3ε(h)), since eh(0)=1 and dh(0)=h−2/3 and eε(h)−1=O(ε(h)). The growing data there are exactly Bh(0),Bh′(0), with Bh(0)=O(1) and Bh′(0)=O(h−2/3) by [F2]. Consequently their Wronskian at zero is h−2/3[π−1+O(ε(h))], nonzero when h is sufficiently small because ε(h)≤C1h. Its derivative is zero for the common equation w′′=(ζ/h2+R)w, so it is nonzero throughout. The invertible Liouville transformation preserves independence. Choose h0 small enough for this and the supplied estimates.

2.2step 1.2F1F2F3F4algebra

[Allowed forms with additive errors] For ξ<ξ0, 2∣ζ∣3/2/(3h)=θ(ξ) and a(ξ)=∣ζ∣1/4(λ−W)−1/4. The Airy formulas of [F2] therefore give aAh=2C(λ−W)−1/4[sin⁡(θ+π/4)+O(h/∣ζ∣3/2)] and aBh=C′(λ−W)−1/4[cos⁡(θ+π/4)+O(h/∣ζ∣3/2)]. Adding the envelope-controlled differences of [F3] yields exactly the additive errors δa,δa,grow of (a),(b), including at sine or cosine zeros. If needed [F4] transports the data across any further fixed allowed matching section and adds its controlled error. The amplitudes are 2C and C′; no relative error at an oscillatory zero is asserted.

2.3step 1.2F1F2F3algebra

[Derivative bounds] For the decaying branch use the envelopes eh−,dh− of the Statement; for the growing branch use eh+,dh+. The chain rule gives, with w0=Ah or Bh respectively, u′−(a w0∘ζ)′=a′(w−w0)∘ζ+aζ′(w′−w0′)∘ζ. The value and derivative bounds of [F3] therefore yield the two displayed transformed derivative error inequalities. To convert the Airy references to the slopes in the Statement, use ζ(ζ′)2=W−λ and differentiate only the explicit leading amplitudes: on the forbidden side, hρ−1/4(ρ−1/4e±Σ)′=e±Σ(±1−hρ′/(4ρ3/2)); on the allowed side, hp−1/2(p−1/2sin⁡(θ+π/4))′=−cos⁡(θ+π/4)−hp′sin⁡(θ+π/4)/(2p2) and hp−1/2(p−1/2cos⁡(θ+π/4))′=sin⁡(θ+π/4)−hp′cos⁡(θ+π/4)/(2p2). At each fixed section away from ξ0, ρ,p,∣ζ∣ are bounded below, so the amplitude-derivative terms are O(h); [F2]'s Airy derivative expansions and the transformed derivative estimates supply the remaining absolute errors C0(ε(h)+h/∣ζ∣3/2), including at oscillatory zeros. No derivative of an unspecified error term is taken.

3.1step 1.1step 2.2step 2.3F5given∎

[Scope and identifications] The only hypotheses used are (W3), the local C5 regularity of W and the single simple zero at ξ0, which are exactly the hypotheses of [F1]-[F4]; no further turning point, no wall and no resonance condition was used. The physical phase integrals and the correspondence with the line model are those of [F5], and the units are the model's. This proves clause (d).

Remarks

  • Orientation. The phase θ and exponent Σ are both measured from the turning point outward into the respective region; with this convention the decaying solution's allowed-side form is the sine with +π/4, and the growing solution's is the cosine, exactly as in the Airy asymptotics of [F2]. Replacing the signed phase θ by −θ interchanges the leading forms because sin⁡(−θ+π/4)=cos⁡(θ+π/4) and cos⁡(−θ+π/4)=sin⁡(θ+π/4). A coordinate reflection with the outward nonnegative phase convention retains the same sine and cosine assignments.
  • Use on this page. The barrier-transmission theorem of this page uses the decaying connection on both sides of a separated barrier; the error control of clause (c) is what makes the two matching errors comparable.
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Separated smooth-barrier tunnelling: the declared transmission coefficient is exp(-2S/h) up to explicit small-h and barrier-thickness errors

Physical scope

The separated smooth-barrier transmission statement for the declared WKB regime model: the declared transmission coefficient equals the exponential of minus twice the barrier WKB exponent per unit h, with the quantitative small-h and exponentially small correction bound of the cited theorem, and the physical exponent is (1/hbar) times the classical action integral over the forbidden region. The statement is conditional on a fixed compactly supported C^5 barrier with exactly two separated simple turning points; it excludes rectangular walls, coalescing turning points, barrier-top uniformity and resonant multiwell interference, and it asserts no detector, wave packet or measured transmission.

Statement

Adopt the declared WKB regime model of The declared WKB regime model: nondimensionalised line equation, turning points, phase integrals and the declared barrier transmission reading with its data V,m,ℏ,ℓ,E⋆,W,λ,h and assume hypothesis (W2): W−λ has exactly two zeros ξa<ξb on R, both simple, is strictly positive on (ξa,ξb) and strictly negative on R∖[ξa,ξb]. Put S:=∫ξaξbW(ξ)−λ dξ>0, and let T(h) be the model's declared transmission coefficient of its clause (d). Then there are h0>0, an ε(h)≤C1h for 0<h<h0, and a constant 0≤C0<∞, both depending only on the model's barrier data (W,λ,ℓ,E⋆) and the fixed matching sections, such that ∣T(h) e2S/h−1∣≤C0[ε(h)+e−2S/h]1−C0[ε(h)+e−2S/h] whenever the denominator is positive; consequently T(h)=e−2S/h(1+O(ε(h)+e−2S/h)). In the physical variables of the line model, where V(ℓξ)=E⋆W(ξ) and E=E⋆λ, one has by Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent clause (b) Sh=1ℏ∫xaxb2m(V(x)−E) dx,xa=ℓξa, xb=ℓξb, so the displayed leading factor is e−2S/h=exp⁡(−2ℏ∫xaxb2m(V−E) dx), the exponential of minus twice the classical action integral of the forbidden region in units of ℏ. The statement is conditional on the fixed compactly supported C5 barrier with two separated simple turning points; rectangular walls, coalescing turning points, barrier-top uniformity and resonant multiwell interference are excluded, and T(h) is the declared scattering-current ratio of the model, not a detector response or a measured count; no wave packet, preparation, apparatus or sampling model is asserted. In particular, for each fixed barrier, lim⁡h↓0T(h) e2S/h=1.

Facts & Assumptions

Given: the WKB regime model and hypothesis (W2); the exponent S; the declared transmission coefficient T(h) of the model clause (d); the Axiom of Countable Choice.

[F1]

Exact local connection data. Under (W3), the one-turn theorem supplies real exact decaying and growing solutions, normalized by dividing by their nonzero forbidden-side constants. On each fixed section away from the turn, their allowed-side values are respectively 2p−1/2(sin⁡Θ+O(h)) and p−1/2(cos⁡Θ+O(h)), their forbidden-side values are respectively ρ−1/4e−A(1+O(h)) and ρ−1/4eA(1+O(h)), and the corresponding derivative estimates have the same O(h) control after scaling the derivative by h. Here p=λ−W on the allowed side, ρ=W−λ on the forbidden side, and A is the action from the turn divided by h. This is Airy connection across a single simple turning point of the declared regime model, with envelope error control clauses (a)-(c), with reflection at a turn whose derivative is negative.

[F2]

Exterior and interior coordinates. The potential profile W is zero on neighborhoods of ξ−=−L and ξ+=L, so p∞=λ>0 there. At a fixed interior point ξ0∈(ξa,ξb), ρ(ξ0)=W(ξ0)−λ>0 and the scaled state Y0(u)=(ρ(ξ0)1/4u(ξ0),hρ(ξ0)−1/4u′(ξ0))T satisfies det⁡(Y0(u),Y0(v))=hW(u,v), where W(u,v):=uv′−u′v. These are algebraic identities.

[F3]

Physical exponent identity. The exact nondimensionalisation lemma gives S/h=ℏ−1∫xaxb2m(V(x)−E) dx on compact subintervals strictly inside the forbidden interval; the identity extends to the turning endpoints by continuity of the square-root integrands (Nondimensionalisation of the one-dimensional stationary equation and of the WKB exponent clause (b)).

Proof

technique · direct; match the exact exterior waves to explicitly displayed Airy bases at both turning points, expand their interior Wronskian without inverting exponentially separated columns, and then convert its modulus to the transmitted current ratio

Given: the data of the statement and [F1]-[F3].

Throughout this proof, O(h) for scalars, vectors or matrices means a quantity whose absolute value or stated norm is bounded by Ch as h↓0, where C depends only on the fixed barrier data and the fixed sections, not on h.

1.1F1givenalgebra

[Hypothesis matching] Under (W2), W−λ has one simple zero ξa with positive derivative and one simple zero ξb with negative derivative. Since W is compactly supported and W−λ<0 outside [ξa,ξb], λ>0; choose L with supp⁡W⊂(−L,L), so the fixed exterior points ξ−=−L and ξ+=L lie in allowed intervals and W=0 near them. Fix the interior point ξ0=(ξa+ξb)/2. The intervals [ξ−,ξ0] and [ξ0,ξ+] contain respectively only the left and right simple turning point, so [F1] applies on each, with reflection of the coordinate on the right.

1.2F3givenalgebra

[Physical exponent] For 0<δ<(ξb−ξa)/2, the closed interval [ξa+δ,ξb−δ] lies strictly inside the forbidden region, so W−λ>0 there and [F3] applies. Both square-root integrands extend continuously to the turning endpoints with value zero. Letting δ↓0, the omitted endpoint integrals tend to zero because their integrands are continuous and bounded on compact intervals. Thus Sh=1h∫ξaξbW−λ dξ=1ℏ∫xaxb2m(E⋆W(x/ℓ)−E⋆λ) dx=1ℏ∫xaxb2m(V(x)−E) dx, with xa=ℓξa, xb=ℓξb, as in the Statement.

1.3givenalgebra

[Exact scattering amplitudes and current ratio] Put p∞=λ and define fL(ξ)=p∞−1/2e−ip∞ξ/h for ξ≤−L and fR(ξ)=p∞−1/2eip∞ξ/h for ξ≥L, extending each to [−L,L] by its Cauchy data. The first-order system for (u,u′) has continuous bounded coefficients on this compact interval for each fixed h>0; its Picard iterates converge uniformly, with the nth iterate bounded by Mn(2L)n/n!, and the same estimate proves uniqueness. Hence fL,fR are exact solutions. Because W−λ is real, Jh′=hIm⁡(∣u′∣2+(W−λ)∣u∣2/h2)=0. The exterior waves have currents Jh(fR)=1, Jh(fL)=−1, and W(fL,fL‾)=2i/h. Thus at the left exterior there are unique coefficients Ain,Aout with fR=AinfL‾+AoutfL; direct expansion of the two plane-wave currents cancels their cross terms and gives Jh(fR)=∣Ain∣2−∣Aout∣2=1, so Ain≠0. The model's unique unit-incoming solution is fR/Ain, with t=1/Ain and r=Aout/Ain, hence T=∣Ain∣−2. Also W(fL,fR)=AinW(fL,fL‾), so Ain=hW(fL,fR)/(2i). This derives the exact normalization and the current-ratio formula used in clause (d) of the WKB model.

1.4F1algebra

[Exterior-to-turning-point basis conversion] Let p(ξ)=λ−W(ξ) on the allowed sides, σ−=−1, σ+=1, and define the outward phases [F1, algebra] Θ−(ξ)=1h∫ξξap(s) ds+π4,Θ+(ξ)=1h∫ξbξp(s) ds+π4, so Θj′=σjp/h. Divide the exact local decaying and growing solutions from [F1] by their nonzero forbidden-side constants and call them dj,gj. At ξj∈{ξ−,ξ+}, put Yj(u)=(p∞1/2u(ξj),hp∞−1/2u′(ξj))T. The fixed-section value and derivative errors in [F1] are O(h): there ζj(ξj)≠0 is fixed, εh≤Ch, and h/∣ζj(ξj)∣3/2=O(h). The Airy derivative asymptotics and chain rule u′=a′w+aζ′w′ give for the normalized allowed-side forms hp−1/2gj′=−σjsin⁡Θj+O(h),hp−1/2dj′=2σjcos⁡Θj+O(h), because the amplitude derivative contributes only hp−1/2(p−1/2)′=O(h) at a fixed section. Hence, after the displayed scaling of u′, Yj(gj)=(cos⁡Θj−σjsin⁡Θj)+O(h),Yj(dj)=2(sin⁡Θjσjcos⁡Θj)+O(h). The exact exterior outgoing plane wave satisfies Yj(fj)=γj(eiΘj,iσjeiΘj)T for some ∣γj∣=1, since it has the same constant amplitude and phase derivative there. The leading basis matrix and its determinant are Mj0=(cos⁡Θj2sin⁡Θj−σjsin⁡Θj2σjcos⁡Θj),det⁡Mj0=2σj, and Mj0(1,i/2)T=(eiΘj,iσjeiΘj)T. Since the entries of (Mj0)−1 are uniformly bounded and the exact matrix is Mj=Mj0+O(h), for all sufficiently small h it is invertible with uniformly bounded inverse; solving its exact two-component system yields coefficients (αj,βj)=γj(1,i/2)T+O(h). Equality of Cauchy data and ODE uniqueness then give fL=γL[(1+O(h))ga+(i/2+O(h))da],fR=γR[(1+O(h))gb+(i/2+O(h))db]. This derives the incoming/outgoing coefficient formulas from the explicit matrices.

2.1step 1.4F1F2algebra

[Interior Wronskian] Put ρ(ξ)=W(ξ)−λ>0 on the barrier and [step 1.4, F1, F2, algebra] Aa=1h∫ξaξ0ρ dξ,Ab=1h∫ξ0ξbρ dξ,A=Aa+Ab=S/h. Both Aa,Ab are positive. At ξ0 use the common state Y0(u)=(ρ(ξ0)1/4u(ξ0),hρ(ξ0)−1/4u′(ξ0))T. The normalized forbidden-side value and slope forms of [F1] give Y0(ga)=eAa[(1,1)T+O(h)],Y0(da)=e−Aa[(1,−1)T+O(h)], Y0(gb)=eAb[(1,−1)T+O(h)],Y0(db)=e−Ab[(1,1)T+O(h)]. Indeed Aa′=ρ/h and Ab′=−ρ/h at the fixed point. Differentiating only the explicit leading forbidden envelopes gives hρ−1/4(ρ−1/4e±Aa)′=e±Aa(±1−hρ′4ρ3/2),hρ−1/4(ρ−1/4e±Ab)′=e±Ab(∓1−hρ′4ρ3/2). The last terms are O(h) because ρ(ξ0)>0 and ρ′ is fixed there; the derivative error from [F1] has the same scaled order. Thus the value and slope vector errors above are indeed O(h) without differentiating an unspecified error term. Since det⁡(Y0(u),Y0(v))=hW(u,v), expand it using the exact identities of step 1.4. The gagb determinant is −2eA(1+O(h)). The leading vectors in each mixed determinant coincide, so those terms are O(h)eAa−Ab and O(h)e−Aa+Ab; relative to eA these are at most O(h)e−2Ab and O(h)e−2Aa. The dadb term is O(e−A). After including the coefficients from step 1.4 and the phases ∣γLγR∣=1, this yields hW(fL,fR)=−2γLγReA[1+O(h)+O(e−2A)]. All constants depend only on the fixed barrier data and sections; no exponentially ill-conditioned matrix is inverted.

3.1step 1.3step 2.1algebra

[Quantitative transmission error] Write the relative error in step 2.1 as δh=O(h+e−2A); then ∣Ain∣2e−2A=∣1+δh∣2=1+ηh with ηh∈R and ∣ηh∣≤C0[h+e−2A] after enlarging a fixed constant. Because T=∣Ain∣−2, Te2A=(1+ηh)−1, so whenever 1−C0[h+e−2A]>0, [step 1.3, step 2.1, algebra] ∣Te2A−1∣≤C0[h+e−2A]1−C0[h+e−2A]. Choose ε(h)=C1h with C1 large enough to dominate the fixed matching errors in steps 1.4-2.1; after increasing C0 as needed, this is the quantitative bound of the Statement with A=S/h. It implies T=e−2S/h(1+O(ε(h)+e−2S/h)) and lim⁡h↓0Te2S/h=1 for the fixed barrier.

4.1F1step 1.3step 2.1given∎

[Scope] The proof uses only the declared smooth compactly supported profile, its two separated simple turning points, the local Airy connections and the exact boundary-defined scattering solution. It uses no rectangular wall, coalescing or multiple turn, barrier-top uniformity, resonant multiwell, wave packet, detector, apparatus or sampling assumption. Thus the claimed exclusions and scope hold.

Remarks

  • Convention note. The cited tunnelling theorem is stated in the nondimensional convention standard in this run's controlled-dynamics mathematics, in which the second-order equation carries the small parameter h and the factors m,ℏ are numerical; the identification of [F3] makes that convention exact for the model's dimensionless equation. The physical exponent identity of the statement is then supplied by the nondimensionalisation lemma and involves no approximation.
  • The exponential is only the leading factor. The statement controls the correction by ε(h)+e−2S/h; in particular the prefactor of the exponential is 1+O(ε) for a smooth barrier, and no statement about rectangular profiles (whose prefactor can differ) is made.
RemarkRemark: AI-adaptedProof: Not applicableOpen item page →

What the controlled-approximations page adopts, proves and does not claim: gaps, branch populations, turning points and the static-Stark limitation

Physical scope

A scope and status record for the controlled-approximations page: the adopted model clauses, the proved conditional statements with their gap, smoothness and boundedness hypotheses, the explicit exclusions (equilibration and branch selection, unbounded and static-field perturbations, rectangular and coalescing turning-point configurations, detectors and measurements), and the absence of any empirical record on this page.

Remarks

5 · Examples, experiments and counterexamples

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Sources